Supramolecular Chemistry (inbunden)
Fler böcker inom
Inbunden (Hardback)
Antal sidor
8 Volume Set
Steed, Jonathan W. (ed.-in-chief)/Gale, Philip A. (ed.-in-chief)/Steed, Jonathan W. (ed.-in-chief)/Gale, Philip A. (ed.-in-chief)
Illustrations (some col.)
304 x 317 x 266 mm
14968 g
Antal komponenter
8 Hardbacks

Supramolecular Chemistry

From Molecules to Nanomaterials

Inbunden, Engelska, 2012-02-09
19576 kr
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Supramolecular Chemistry: From Molecules to Nanomaterials is a new major reference work which links supramolecular chemistry and nanomaterials. Presenting over 150 tutorial articles and spanning over 10 comprehensive sections, this new resource covers: * Concepts * Techniques * Molecular recognition * Supramolecular reactivity * Supramolecular aspects of chemical biology * Self processes * Supramolecular devices * Supramolecular materials chemistry * Soft matter * Nanotechnology Supramolecular chemistry is 'chemistry beyond the molecule'. While traditional chemistry focuses on the bonds that hold atoms together in a molecule, supramolecular chemistry examines the weaker interactions that hold groups of molecules together. Important concepts that have been demonstrated by supramolecular chemistry include molecular self-assembly, folding, molecular recognition, host-guest chemistry, mechanically-interlocked molecular architectures, and dynamic covalent chemistry. The importance of supramolecular chemistry was established by the 1987 Nobel Prize for Chemistry, which was awarded to Donald J. Cram, Jean-Marie Lehn, and Charles J. Pedersen in recognition of their work in the field. The past decade has seen dramatic developments in the field, with supramolecular chemistry leaving its roots in classical host guest chemistry and expanding into exciting areas of materials chemistry and nanoscience with many real and potential applications. Supramolecular findings are evolving our understanding of the way chemical concepts at the molecular level build up into materials and systems with fascinating, emergent properties on the nanoscale. Supramolecular chemistry: the biggest challenge yet! "Creating that link between the chemist's understanding of the way in which molecules interact with one another, and the understanding a materials scientist, engineer or biologist has of the resulting properties of a material or system comprised of those molecules is one of the huge grand challenges facing modern molecular science." Philip A. Gale and Jonathan W. Steed, Editors-in-Chief Linking supramolecular chemistry and nanotechnology to define the field in the 21st Century Supramolecular Chemistry: From Molecules to Nanomaterials is the first major reference to link supramolecular chemistry and nanotechnology. A global team of experts present an overview of the concepts and techniques of modern supramolecular chemistry, demonstrating how these paradigms evolve into nanoscale systems chemistry, nanotechnology, materials science and beyond. Breaking down the barriers between synthetic chemistry and materials science, the authors demonstrate how modern techniques allow access increasingly far along the 'synthesising-up' pathway. Supramolecular Chemistry: From Molecules to Nanomaterials explains the fundamental concepts and provides invaluable practical guidance on the applications and limitations of modern instrumental techniques for addressing molecular and materials-based problems. The printed edition of Supramolecular Chemistry: From Molecules to Nanomaterials is available as an eight-volume set. Publishing in full colour to enhance the interpretation of complex supramolecular structures the printed edition * is highly illustrated with an average of three images per page * features fully indexed articles with cross-references integrated into the text * includes a glossary of key terms Online Edition Supramolecular Chemistry: From Molecules to Nanomaterials is now available online. For further information visit
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Editors-in-Chief Professor Philip Gale, School of Chemistry, University of Southampton,UK Professor Gale is currently Head of the School of Chemistry at Southampton University. He is the author or co-author of over 160 publications including two books and a series of highly cited review articles on anion complexation. Professor Gale has won a number of research prizes and is the co-editor of the journal Supramolecular Chemistry, a commissioning editor for Chemical Society Reviews and a member of the international editorial advisory boards of Coordination Chemistry Reviews, the Encyclopaedia of Supramolecular Chemistry, The Open Inorganic Chemistry Journal and Chemical Communications. Professor Gale is also a member of RSC Science Policy Board. Professor Jonathan Steed, Professor of Inorganic Chemistry, Department of Chemistry, Durham University,UK Jonathan Steed is Professor of Inorganic Chemistry at Durham University. He is co-author of the textbooks Supramolecular Chemistry (2000 & 2009), Core Concepts in Supramolecular Chemistry and Nanochemistry (2007) and around 250 research papers. He has edited the Encyclopaedia of Supramolecular Chemistry (2004) and Organic Nanostructures (2008). International Advisory Board Jerry Atwood - University of Missouri-Columbia Paul D. Beer - University of Oxford Makoto Fujita - The University of Tokyo Tom Fyles - University of Victoria Andrew D. Hamilton - Yale University Michaele Hardie - University of Leeds Ivan Huc - Institut Europeen de Chimie et Biologie (IECB) Yun-Bao Jiang - Xiamen University Kate Jolliffe - The University of Sydney Kimoon Kim - Pohang University of Science and Technology (POSTECH) David A. Leigh - University of Edinburgh Jonathan L. Sessler - Institute for Cellular and Molecular Biology George Shimizu - University of Calgary Section Editors Philip Gale, University of Southampton, UK Eric Anslyn, University of Texas, USA Bradley Smith, University of Notre Dame, USA Edwin Constable, University of Basel, Switzerland Enrique Garcia-Espana, Universidad de Valencia, Spain Douglas Philp, University of St Andrews, UK Marcey Waters, University of North Carolina, USA David Amabilino, Institut de Ciencia de Materials de Barcelona (CSIC), Spain Pavel Anzenbacher, Bowling Green State University, USA Len Barbour, University of Stellenbosch, South Africa David K Smith, University of York, UK Paula Mendes & Jonathan Preece, University of Birmingham, UK Co


VOLUME 1: CONCEPTS Contributors to Volume 1 xiii Foreword xv Preface xvii Abbreviations and Acronyms xix Concepts 1 Definition and Emergence of Supramolecular Chemistry 3 Jonathan W. Steed/Jerry L. Atwood/Philip A. Gale Supramolecular Interactions 9 Dushyant B. Varshey/John R. G. Sander/Tomislav Friscic/ Leonard R. MacGillivray Complementarity and Preorganization 25 James B. Wittenberg/Lyle Isaacs The Thermodynamics of Molecular Recognition 45 Corinne L. D. Gibb/Bruce C. Gibb Cooperativity and the Chelate, Macrocyclic and Cryptate Effects 67 Richard W. Taylor/Rowshan Ara Begum/Victor W. Day/Kristin Bowman-James Multivalency 95 Mary J. Cloninger/Ba,sar Bilgi,cer/Lingyin Li/Shane L. Mangold/Scott T. Phillips/Mark L. Wolfenden Solvation Effects in Supramolecular Recognition 117 Mikhail Rekharsky/Yoshihisa Inoue Competition Experiments 135 Lei You/Eric V. Anslyn Supramolecular Information/Programming from a Boolean Perspective 161 A. Prasanna de Silva Self-Assembly and Self-Organization 167 Michael F. Geer/Linda S. Shimizu Introduction to Surfactant Self-Assembly 181 Laurence S. Romsted Reversible Covalent Bond Toolbox 205 Yunfeng Cheng/Hanjing Peng/Binghe Wang Chirality 217 F. Richard Keene VOLUME 2: TECHNIQUES Contributors to Volume 2 xiii Foreword xvii Preface xix Abbreviations and Acronyms xxi Techniques 237 Binding Constants and Their Measurement 239 Pall Thordarson Isothermal Titration Calorimetry in Supramolecular Chemistry 275 Franz P. Schmidtchen NMR Spectroscopy in Solution 297 Jesus Garc a/Lucas G. Martins/Miquel Pons Diffusion Ordered NMR Spectroscopy (DOSY) 319 Alceo Macchioni/Gianluca Ciancaleoni/Cristiano Zuccaccia/Daniele Zuccaccia Solid-State NMR Studies on Supramolecular Chemistry 331 Michele R. Chierotti/Roberto Gobetto Mass Spectrometry and Gas-Phase Chemistry of Supermolecules: A Primer 347 Egor V. Dzyuba/Johannes Poppenberg/Sebastian Richter/Ralf W. Troff/Christoph A. Schalley Luminescent Spectroscopy in Supramolecular Chemistry 379 Sundus Erbas-Cakmak/Ruslan Guliyev/Engin U. Akkaya Circular Dichroism Spectroscopy 393 Tohru Taniguchi/Toyonobu Usuki Dynamic Light Scattering in Supramolecular Materials Chemistry 411 Jorg Braun/Kasper Renggli/Julia Razumovitch/Corinne Vebert X-Ray Diffraction: Addressing Structural Complexity in Supramolecular Chemistry 425 Gary D. Enright/Satoshi Takeya/John A. Ripmeester Small-Angle X-ray Scattering (SAXS) and Wide-Angle X-ray Scattering (WAXS) of Supramolecular Assemblies 437 Adriana C. Toma/Thomas Pfohl Supramolecular Electrochemistry 451 Amar H. Flood/Angel E. Kaifer Transport Experiments in Membranes 473 Stefan Matile/Naomi Sakai/Andreas Hennig Vesicles in Supramolecular Chemistry 501 Bart Jan Ravoo Rheology 517 Christophe Chassenieux/Laurent Bouteiller Langmuir Blodgett Films 529 Jeremy J. Ramsden Affinity Capillary Electrophoresis as a Tool to Characterize Intermolecular Interactions 543 Steffen Kiessig/Alexandra Stettler/Samuel Fuhrimann/Maria Anna Schwarz Ion Chromatography and Membrane Separations Using Macrocyclic Ligands 563 John D. Lamb/Na Li Brewster Angle Microscopy 589 Keith J. Stine Scanning Electron Microscopy 619 Zhan-Ting Li/Xin Zhao Transmission Electron Microscopy (TEM) 633 Jun-ichi Kikuchi/Kazuma Yasuhara Scanning Tunneling Microscopy (STM) 647 Meike Stohr Atomic Force Microscopy (AFM) 659 Janne T. Hyotyla/Roderick Y. H. Lim Scanning Near-Field Optical Microscopy (SNOM) 669 Gerd Kaupp Computational Techniques (DFT, MM, TD-DFT, PCM) 689 Rosemary Sheehan/Peter J. Cragg Uses of Differential Sensing and Arrays in Chemical Analysis 709 Michelle M. Adams/Leo A. Joyce/Eric V. Anslyn VOLUME 3: MOLECULAR RECOGNITION Contributors to Volume 3 xiii Foreword xv Preface xvii Abbreviations and Acronyms xix Mol