- Inbunden (Hardback)
- Antal sidor
- OUP USA
- Derwent, Richard G / Orlando, John J / Tyndall, Geoffrey S / Wallington, Timothy J
- 18 halftones, 328 black and white line illustrations, and 229 colour halftones
- 234 x 165 x 50 mm
- Antal komponenter
- 1496 g
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Mechanisms of Atmospheric Oxidation of the Alkanes
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various approaches now used to model the alkane atmospheric chemistry. Comprehensive coverage is given of both the unsubstituted alkanes and the many haloalkanes. All the existing quality measurements of the rate coefficients for the reactions of OH, Cl, O(3P), NO3, and O3 with the alkanes, the haloalkanes,
and their major oxidation products have been reviewed and evaluated. The expert authors then give recommendations of the most reliable kinetic data. They also review the extensive literature on the mechanisms and rates and modes of photodecomposition of the haloalkanes and the products of atmospheric oxidation of the alkanes and the haloalkanes, and make recommendations for future use by atmospheric scientists. The evaluations presented allow an extrapolation of the existing kinetic and
photochemical data to those alkanes and haloalkanes that are as yet unstudied.
The current book should be of special interest and value to the modelers of atmospheric chemistry as a useful input for development of realistic modules designed to simulate the atmospheric chemistry of the alkanes, their major oxidation products, and their influence on ozone and other trace gases within the troposphere.
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<br>Jack G. Calvert, Emeriturs Senior Scientist at National Center for Atmospheric Reseach<br>Richard G. Derwent, Independent consultant, OBE, past scientist with UK Meterological Office<br>John J. Orlando, Scientist III at National Center for Atmospheric Research<br>Geoffrey S. Tyndall, NCAR, Leader of Laboratory Kinetics Group<br>Timothy J. Wallington, Technical Leader in Physical and Environmental Sciences at Ford Motor Company<br>
I. Importance of Alkanes in Atmospheric Chemistry of the Urban, Regional, and Global Scales; II. Reactions of Alkanes with the Hydroxy Radical (OH); III. Kinetics and Mechanisms of Reactions of Cl, O(3P), NO3, and O3 with Alkanes; IV. Mechanisms and End-Products of the Atmospheric Oxidation of Alkanes; V. Reactions of Products of Alkane Reactions; VI. Atmospheric Chemistry of the Haloalkanes; VII. The Primary Photochemical Processes in the Alkanes, Haloalkanes, and Some of Their Oxidation Products; VIII. Representation of the Atmospheric Chemistry of Alkanes in Models References