Chemistry of Heterocyclic Compounds
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Köp båda 2 för 9044 kr"This book updates Volumes 5 and 35 of this series on quinoxalines and covers the literature on quinoxalines from approximately 1976-2002." (Journal of the American Chemical Society, June 9, 2004)
Desmond J. Brown is Professor of Chemistry at The Australian National University.
Chapter 1 Primary Syntheses 1 1.1 From a Single Benzene Substrate 1 1.1.1 By Formation of the N1,C8a Bond 1 1.1.2 By Formation of the N1,C2 Bond 4 1.1.2.1 Cyclization of o-(Ethylamino)aniline Derivatives 4 1.1.2.2 Direct Cyclization of o-(Ethylamino)nitrobenzene Derivatives 6 1.1.2.3 Reductive Cyclization of o-(Ethylamino)nitrobenzene Derivatives 8 1.1.3 By Formation of the C2,C3 Bond 12 1.2 From a Benzene Substrate with an Ancillary Synthon 13 1.2.1 When the Synthon Supplies N1 of the Quinoxaline 13 1.2.2 When the Synthon Supplies C2 of the Quinoxaline 14 1.2.3 When the Synthon Supplies C2 + C3 of the Quinoxaline 16 1.2.3.1 Using a Dialdehyde (Glyoxal) or Related Synthon 16 1.2.3.2 Using an Aldehydo Ketone or Related Synthon 18 1.2.3.3 Using an Aldehydo Acid or Related Synthon 22 1.2.3.4 Using an Aldehydo Ester or Related Synthon 23 1.2.3.5 Using an Aldehydo Amide, Nitrile, Acyl Halide, or Related Synthon 24 1.2.3.6 Using a Diketone or Related Synthon 24 1.2.3.7 Using a Keto Acid or Related Synthon 30 1.2.3.8 Using a Keto Ester or Related Synthon 31 1.2.3.9 Using a Keto Amide, Nitrile, Acyl Halide, or Related Synthon 34 1.2.3.10 Using a Diacid (Oxalic Acid) as Synthon 35 1.2.3.11 Using a Diester (a Dialkyl Oxalate) or Related Synthon 36 1.2.3.12 Using an Estero Amide, Nitrile, Acyl Halide, or Related Synthon 38 1.2.3.13 Using a Diamide (Oxamide), Amido Nitrile, or Related Synthon 40 1.2.3.14 Using a Diacyl Dihalide (Oxalyl Halide) or Related Synthon 40 1.2.4 When the Synthon Supplies N1 + C2 + C3 of the Quinoxaline 42 1.2.5 When the Synthon Supplies N1 + C2 + C3 + N4 of the Quinoxaline 42 1.3 From a Benzene Substrate with Two or More Synthons 44 1.4 From a Pyrazine Substrate with or without Synthon(s) 45 1.5 From Other Heteromonocyclic Substrates/Synthons 46 1.5.1 Azirines as Substrates/Synthons 47 1.5.2 1,2,3-Dithiazol-1-iums as Substrates/Synthons 47 1.5.3 Furans as Substrates/Synthons 48 1.5.4 Isothiazoles as Substrates/Synthons 49 1.5.5 Isoxazoles as Substrates/Synthons 50 1.5.6 Oxazoles as Substrates/Synthons 51 1.5.7 Oxirenes as Substrates/Synthons 51 1.5.8 Pyrans as Substrates/Synthons 53 1.5.9 Pyridazines as Substrates/Synthons 53 1.5.10 Pyridines as Substrates/Synthons 54 1.5.11 Pyrimidines as Substrates/Synthons 54 1.5.12 Pyrroles as Substrates/Synthons 55 1.5.13 Thiophenes as Substrates/Synthons 55 1.5.14 1,2,4-Triazines as Substrates/Synthons 56 1.5.15 1,2,3-Triazoles as Substrates/Synthons 56 1.6 From Heterobicyclic Substrates/Synthons 57 1.6.1 7-Azabicyclo[4.1.0]heptanes as Substrates/Synthons 57 1.6.2 Benzimidazoles as Substrates/Synthons 57 1.6.3 1,4-Benzodiazepines as Substrates/Synthons 59 1.6.4 1,5-Benzodiazepines as Substrates/Synthons 59 1.6.5 1-Benzopyrans (Chromenes) as Substrates/Synthons 61 1.6.6 2,1,3-Benzoselena(or thia)diazoles as Substrates/Synthons 61 1.6.7 2,1,3-Benzoxadiazoles as Substrates/Synthons 62 1.6.8 Cycloheptapyrazines as Substrates/Synthons 68 1.6.9 Indoles as Substrates/Synthons 68 1.6.10 Pyrrolo[3,4-b]pyrazines as Substrates/Synthons 69 1.7 From Heteropolycyclic Substrates/Synthons 70 1.7.1 Azeto- or Azirino[1,2-a]quinoxalines as Substrates/Synthons 70 1.7.2 Benz[g]indoles as Substrates/Synthons 71 1.7.3 Benzo[3,4]cyclobuta[1,2-b]quinoxalines as Substrates/Synthons 71 1.7.4 Benzo[g]pteridines as Substrates/Synthons 71 1.7.5 [1]Benzopyrano[2,3-b]quinoxalines as Substrates/Synthons 73 1.7.6 [1]Benzothiopyrano[4,3-b]pyrroles as Substrates/Synthons 73 1.7.7 Cyclobuta[b]quinoxalines as Substrates/Synthons 73 1.7.8 1,3-Dithiolo[4,5-b]quinoxalines as Substrates/Synthons 74 1.7.9 1,4-Ethanoquinoxalines as Substrates/Synthons 74 1.7.10 Furo[2,3-b]quinoxalines as Substrates/Synthons 75 1.7.11 Furo[3,4-b]quinoxalines as Substrates/Synthons 76 1.7.12 Indeno[1,2-b]pyrroles as Substrates/Synthons 76 1.7.13 Isoxazolo[2,3-d][1,4]benzodiazepines as Sub