Modern Surface Organometallic Chemistry (inbunden)
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Inbunden (Hardback)
Antal sidor
2 Volume Set
Wiley-VCH Verlag GmbH
Basset, Jean -Marie (ed.), Psaro, Rinaldo (ed.), Roberto, Dominique (ed.), Ugo, Renato (ed.)
244 x 175 x 38 mm
1498 g
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2 Hardbacks
Modern Surface Organometallic Chemistry (inbunden)

Modern Surface Organometallic Chemistry

Inbunden Engelska, 2009-07-08
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Covering everything from the basics to recent applications, this monograph represents an advanced overview of the field. Edited by internationally acclaimed experts respected throughout the community, the book is clearly divided into sections on fundamental and applied surface organometallic chemistry. Backed by numerous examples from the recent literature, this is a key reference for all chemists.
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  • Surface Organometallic Chemistry: Molecular Approaches to Surface Catalysis

    Jean-Marie Basset, Bruce C Gates, Jean-Pierre Candy, Agnes Choplin, Michel Leconte

    Surface organometallic chemistry is a new field bringing together researchers from organometallic, inorganic, and surface chemistry and catalysis. Topics ranging from reaction mechanisms to catalyst preparation are considered from a molecular basi...

Recensioner i media

This comprehensive book is edited by four eminent scientists, two of whom have helped pioneer the research area. Fifty investigators have contributed to the impressive array of 16 chapters, the breadth and depth of which render an encyclopedic flavor to the volume. (JACS, January 2010)

Övrig information

Jean Marie Basset is Research Director at CNRS and Director of the Laboratory of Surface Organometallic Chemistry at CPE in Lyon. He received many awards including the grand prix (Prix Sue-1997) of the French Chemical society, the Max Planck Award in Germany, and the IFP Award of the French Academy of Sciences (1998). He is the author of 472 publications, 45 patents and is a member of the French Academy of Sciences and of the French Academy of Technologies as well of the Europan Academy of Sciences. His research interests are mostly centered in the field of Surface Organometallic Chemistry. Rinaldo Psaro is Director of the CNR Institute of Molecular Science and Technologies, Milano Italy. The general scientific interest is the development of new methods for the preparation of more efficient and eco-compatible catalytic systems for fine chemicals and commodities, to achieve higher performances, simpler preparation methods, conditions allowing for extended recycling. Author or co-author of 3 international patents and 162 papers on international journals on the field of surface organometallic chemistry, catalyst characterisation and heterogeneous catalysis. Dominique Roberto is Full Professor of ?General and Inorganic Chemistry at the Milan University. Author of 81 publications on highly qualified journals, her current research interests cover molecular engineering and nanoorganization of coordination and organometallic compounds with luminescent or non-linear optical properties, coordination complexes for solar cell application, and surface organometallic chemistry. For her research, she received the "Flavio Bonati" (1996) and the "Federchimica-per un futuro intelligente" (1998) awards. Renato Ugo is Full Professor of Inorganic Chemistry at Milan University. He received many awards including the Gold medal of the President of the Italian Republic for advancement in science (2000) and the Pino medal (2006). President of the Italian Association of Industrial Research, he is a member of the "Accademia Nazionale dei Lincei". He is author of ca 250 publications on highly qualified journals in the field of coordination chemistry, catalysis, surface organometallic chemistry, and recently nonlinear optics.


Preface ON THE ORIGINS AND DEVELOPMENT OF ?SURFACE ORGANOMETALLIC CHEMISTRY? The Basic Concept Use of Probe Molecules on Metallic Surfaces as Evidence of Coordination and Organometallic Chemistry at Metal Surfaces Chemical and Structural Analogy between Molecular Clusters and Small Metallic Particles Analogy between Supported Molecular Clusters and Small Supported Catalytic Particles Foundation of Surface Organometallic Chemistry From Organometallic Surface Chemistry to the Elementary Steps Occurring on Surfaces and Stabilization by the Surface of Rather Unstable Molecular Species From Surface Organometallic Chemistry on Oxides to Surface Organometallic Chemistry on Metals From Surface Organometallic Chemistry to Surface-Mediated Organometallic Synthesis Single Metal Site Heterogeneous Catalysts and the Design of New Catalysts PREPARATION OF SINGLE SITE CATALYSTS ON OXIDES AND METALS PREPARED VIA SURFACE ORGANOMETALLIC CHEMISTRY Introduction Surface Organometallic Chemistry on Oxides Reaction of Organometallic Compounds with Supported or Unsupported Group VIII Metals Particles Conclusion CATALYTIC PROPERTIES OF SINGLE SITE CATALYSTS PREPARED VIA SURFACE ORGANOMETALIC CHEMISTRY ON OXIDES AND ON METALS Introduction Stoichiometric Activation of Alkane C-H Bonds Alkane C-C Bond Activation by Tantalum Hydrides. Low Temperature Catalytic Hydrogenolysis of Alkanes Metathesis of Acyclic Alkanes Cross-Metathesis Reactions of Alkanes Homologation of Alkanes Polystyrene Modification and Hydrogenolysis of Linear Alkanes and Polyethylene by a Supported Zirconium Hydride Olefin Metathesis Olefin Epoxidation Deperoxidation of Cyclohexyl Hydroperoxide Some Applications of Supported Nanoparticles Modified by Organometallics Conclusion BUILDING BLOCK APPROACHES TO NANOSTRUCTURED, SINGLE SITE, HETEROGENEOUS CATALYSTS Introduction Current Challenges in Catalysis What is a Nanostructured Catalyst? Benefits of Nanostructuring Catalysts Current Approaches to Nanostructured Catalysts Building Block Approaches to Nanostructured Materials and Catalysis Nanostructured Catalysts via a Non-Aqueous Building Block Methodology A Model for the Growth of Building Block Matrices and a Nanostructuring Strategy A General Procedure for Preparing Nanostructured Catalysts in Silicate Matrices Atomically Dispersed Titanium and Vanadium, Single Site Catalysts Bridge between Nanostructuring and Catalysis Summary TRANSITION METAL SINGLE SITE CATALYSTS ? FROM HOMOGENEOUS TO IMMOBILIZED SYSTEMS Introduction Covalently Anchored Organometallic Complexes on Unmodified Silica Anchoring of Organometallic Complexes via the Metal Center Organometallic Complexes Anchored via a Covalent Linkage to a Ligand Noncovalently Anchored Organometallic Complexes Encapsulated Organometallic Complexes Conclusions CONTROLLED PREPARATION OF HETEROGENEOUS CATALYSTS FOR CHEMO- AND ENANTIOSELECTIVE HYDROGENATION REACTIONS Introduction Catalyst Preparation and Characterization Hydrogenation of Alpha,Beta-Unsaturated Aldehydes Hydrogenation of Aromatic Ketones Enantioselective Hydrogenation Reactions Conclusions WELL-DEFINED SURFACE RHODIUM SILOXIDE COMPLEXES AND THEIR APPLICATION TO CATALYSIS Molecular versus Immobilized Transition Metal Siloxide Complexes in Catalysis Synthesis, Characterization and Catalytic Activity of Well-Defined Surface Rhodium Siloxide Complexes Solid-State NMR Method in Catalysis by Surface Organometallics Mechanism of Hydrosilylation Catalyzed by Surface versus Soluble Rhodium Siloxide Complexes CARBONYL COMPOUNDS AS METALLIC PRECURSORS OF TAILORED SUPPORTED CATALYSTS Introduction Catalysts Prepared from Metal Carbonyls of Groups 6, 7, 10 and Gold Catalysts Prepared from Metal Carbonyls of Group 8: Iron, Ruthenium and Osmium Catalysts Prepared from Metal Carbonyls of Group 9: Cobalt, Rhodium and Iridium Concluding Remarks EXPLOITING SURFACE CHEMISTRY TO PREPARE METAL-SUPPORTED CATALYSTS BY ORGANOMETALLIC CHEMICAL VAPOR DEPOSITION Introduction Surface Organometallic Chemis