Clusters of Atoms and Molecules II (häftad)
Format
Häftad (Paperback / softback)
Språk
Engelska
Antal sidor
414
Utgivningsdatum
2011-12-21
Upplaga
Softcover reprint of the original 1st ed. 1994
Förlag
Springer-Verlag Berlin and Heidelberg GmbH & Co. K
Medarbetare
Haberland, Hellmut (ed.)
Illustrationer
XVIII, 414 p.
Volymtitel
II
Dimensioner
234 x 156 x 23 mm
Vikt
608 g
Antal komponenter
1
Komponenter
1 Paperback / softback
ISBN
9783642849879

Clusters of Atoms and Molecules II

Solvation and Chemistry of Free Clusters, and Embedded, Supported and Compressed Clusters

Häftad,  Engelska, 2011-12-21
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Cluster science studies the transition from atomic, and molecular physics or chemistry to the science and technology of condensed matter. Two main topics from this large field will be emphasized in this second volume of Atomic and Molecular Clusters. After an Introduction, Chap. 2 deals mainly with molecular clusters, how they react to positive or negative charges (Sect. 2.1 to 2.5), how they decompose and how they can be charged (Sect. 2.6 and 2.7), and how one can do chemistry with them (2.8 and 2.9). Clusters in contact with a macroscopic medium are treated in Chap. 3. It is from this domain that one can expect possible new applications of cluster science. The optical spectra of silver clusters in a dielectric medium are discussed in Sect. 3.1. Their properties have since long been used unknowingly to stain glass windows. Large clusters floating in an ambient pressure gas are called aerosols (Sect. 3.2). Their properties can be used to monitor air pollution. Development of a photographic film is due to supported silver clusters in a liquid environment (Sect. 3.3). Large semiconductor clusters, also called "quantum dots", have novel optical and electronic properties (Sect. 3.4). The optical properties of large clusters, in general, are reviewed in Sect. 3.5, and properties of clusters supported on clean surfaces are discussed in Sect. 3.6.
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Innehållsförteckning

1 Introduction.- 1.1 Historical Application of Metal Clusters.- 1.2 Outlook.- Reference.- 2 Solvation, Chemistry, and Charging of Free Clusters.- 2.1 Solvated Atoms in Polar Solvents.- 2.2 IR Spectroscopy of Solvated Molecules.- 2.3 IR Spectroscopy of Hydrogen Bonded Charged Clusters.- 2.4 Solvated Cluster Ions.- 2.5 Solvated Electron Clusters.- 2.6 Internal Reactions and Metastable Dissociations after Ionization of van der Waals Clusters.- 2.7 Multiply Charged Clusters.- 2.8 Chemistry with Neutral Metal Clusters.- 2.9 Chemistry with Cluster Ions.- 3 Embedded, Supported, and Compressed Clusters.- 3.1 Optical Properties of Silver Clusters in Dielectric Matrices.- 3.2 Aerosols, Large Clusters in Gas Suspensions.- 3.3 Metal Clusters in a Liquid Environment Photographic Development.- 3.4 Larger Semiconductor Clusters (Quantum Dots).- 3.5 Electromagnetic Excitations of Large Clusters.- 3.6 Supported Clusters.- 3.7 Nanocrystalline Materials.- Subject Index of Volume 52.