Silanes and Other Coupling Agents – serie
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The topic of silanes and other coupling agents/adhesion promoters is of tremendous contemporary interest because of their application in many and varied technologically important areas ranging from coatings to reinforced composites to dentistry to biomedical (e.g., for bonding nucleotides to the so-called ‘gene chips’). In addition to their traditional use for bonding different materials, silanes have been shown to be highly effective in corrosion protection of metallic materials. This book is divided into three parts as follows: Part 1: Silane Coupling Agents/Adhesion Promoters; Part 2: Silanes for Corrosion Inhibition/Protection; Parts 3: General papers. The topics covered include: various ways to deposit silanes and factors affecting silane deposition and silane deposit characteristics; structure of silane deposits; silane deposition on glass and other surfaces; hydrophobic silane films; water absorption and transport in silane films; application of silanes in fiber-reinforced composites for dental use in cathodic delamination of elastomer-metal adhesive joints, and to impart anti-mold and anti fungal characteristics to wood; use of silanes in providing corrosion protection to metallic materials and in enhancing corrosion performance of coatings; plasma polymer coatings in corrosion protection of metallic materials; chromata-free silane-containing primer technology; silane coupling agents for surface-initiated living polymerization; nanosols to improve functional properties of fabrics; photocatalytic titania for textile application; solid-state NMR studies of surface treatments; surface free energy of silicon-based plasma polymer films. In essence this book reflects the latest R&D activity in this arena and should be of interest and value to anyone with a desire or need to learn about this fascinating and technologically highly significant class of materials.
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This book embodies the proceedings of the Second International Symposium on Silanes and other Adhesion Promoters held in Newark, New Jersey, October 21--23, 1998. Silanes are the most popular and widely used coupling agents (or adhesion promoters) to promote adhesion between dissimilar materials in a variety of situations, e.g. coating technology, adhesive bonding, reinforced composites, etc. Since the first symposium on this topic in 1991, there had been a tremendous R&D activity in developing new and more effective adhesion promoters and in understanding and optimising the performance of available coupling agents. The technical program for the symposium contained 36 papers and reflected both overviews and original research contributors and the presenters hailed from academia, industry and other research laboratories. Many different aspects of coupling agents were discussed, and both fundamental and applied aspects were accorded due coverage. In addition to formal presentations, there were brisk and lively discussions throughout the symposium, and this event provided an opportunity for cross-pollination of ideas in the broad arena of adhesion promoters. This present volume contains 18 papers by experts from academia, industry and other research laboratories. All manuscripts were subjected to rigorous peer review and were suitably revised before inclusion in this volume. The book is divided into two parts as follows: Part 1. Silane Coupling Agents; and Part 2: Non-silane Coupling Agents/Adhesion Promotors. The topics covered include: silane adhesion prompters for hydrosilylation cure systems; sterically hindered silanes; study of silanes hydrolysis; adsorption of silanes on different substrates; interaction of water with silane films studied by neutron reflection; characterization of glass fiber sizings; silanes as dispersion promoters; corrosion protection of metals by silanes; surface 'Intelligraft' as a new class of adhesion promoters; hydroxymethylated resorcinol, sol-gels, and -diketone functionalised polymers as adhesion promoters; and plasma deposition of silanes.