Studies in Interface Science – serie

This book covers major areas of modern Colloid and Surface Science (in some countries also referred to as Colloid Chemistry) which is a broad area at the intersection of Chemistry, Physics, Biology and Material Science investigating the disperse state of matter and surface phenomena in disperse systems. The book arises of and summarizes the progress made at the Colloid Chemistry Division of the Chemistry Department of Lomonosov Moscow State University (MSU) over many years of scientific, pedagogical and methodological work. Throughout the book the presentation of fundamental theoretical and experimental approaches and results is combined with discussion of general scientific basis of their role in nature and applications in various technological processes.

In the small world of micrometer to nanometer scale many natural and industrial processes include attachment of colloid particles (solid spheres, liquid droplets, gas bubbles or protein macromolecules) to fluid interfaces and their confinement in liquid films. This may lead to the appearance of lateral interactions between particles at interfaces, or between inclusions in phospholipid membranes, followed eventually by the formation of two-dimensional ordered arrays. The book is devoted to the description of such processes, their consecutive stages, and to the investigation of the underlying physico-chemical mechanisms. The first six chapters give a concise but informative introduction to the basic knowledge in surface and colloid science, which includes both traditional concepts and some recent results. Chapters 1 and 2 are devoted to the basic theory of capillarity, kinetics of surfactant adsorption, shapes of axisymmetric fluid interfaces, contact angles and line tension. Chapters 3 and 4 present a generalization of the theory of capillarity to the case, in which the variation of the interfacial (membrane) curvature contributes to the total energy of the system. The generalized Laplace equation is applied to determine the configurations of free and adherent biological cells. Chapters 5 and 6 are focused on the role of thin liquid films and hydrodynamic factors in the attachment of solid and fluid particles to an interface. Surface forces of various physical nature are presented and their relative importance is discussed. Hydrodynamic interactions of a colloidal particle with an interface (or another particle) are also considered.Chapters 7 to 10 are devoted to the theoretical foundation of various kinds of capillary forces. When two particles are attached to the same interface (membrane), capillary interactions, mediated by the interface or membrane, appear between them. Two major kinds of capillary interactions are described: (i) capillary immersion force related to the surface wettability (Chapter 7), (ii) capillary flotation force originating from interfacial deformations due to particle weight (Chapter 8). Special attention is paid to the theory of capillary immersion forces between particles entrapped in spherical liquid films (Chapter 9). A generalization of the theory of immersion forces allows one to describe membrane-mediated interactions between protein inclusions into a lipid bilayer (Chapter 10).Chapter 11 is devoted to the theory of the capillary bridges and the capillary-bridge forces, whose importance has been recognized in phenomena like consolidation of granules and soils, wetting of powders, capillary condensation, long-range hydrophobic attraction, etc. The nucleation of capillary bridges is also examined.Chapter 12 considers solid particles, which have an irregular wetting perimeter upon attachment to a fluid interface. The undulated contact line induces interfacial deformations, which engender a special lateral capillary force between the particles. The latter contributes to the dilatational and shear elastic moduli of particulate adsorption monolayers.Chapter 13 describes how lateral capillary forces, facilitated by convective flows and some specific and non-specific interactions, can lead to the aggregation and ordering of various particles at fluid interfaces or in thin liquid films. Recent results on fabricating two-dimensional (2D) arrays from micrometer and sub-micrometer latex particles, as well as 2D crystals from proteins and protein complexes, are reviewed. Chapter 14 presents applied aspects of the particle-surface interaction in antifoaming and defoaming. The mechanisms of antifoaming action involve as a necessary step the entering of an antifoam particle at the air-water interface. The considered mechanisms indicate the factors for control of foaminess.

This book considers the different concepts of hydrophile-lipophile balance (HLB) of surfactants and solid particles and the main physicochemical properties of surfactant and solid interfaces which are used to definite the hydrophile-lipophile balance. The book comprehensively analyses all interfacial and bulk properties of surfactants used for the determination of HLB (such as interfacial tension, distribution coefficient, adsorption, surface pressure, surfactants solubility, structure characteristics, distribution between heteropolar phases, micellar formation, chromatographic characteristics, phase separation in emulsions, phase inversion temperature, formation of three phase systems).The central point of the book is the energetic interpretation of the balance, i.e. the hydrophile-lipophile ratio. At the same time the HLB-number systems of Griffin and Davies and other independant methods of the hydrophile-lipophile balance definitions are discussed: PIT, polarity indexes, surfactant affinity difference etc. The possibility of application of the different characteristics of the hydrophile-lipophile balance as a criterion of phase inversion in emulsions and microemulsion systems water-oil-surfactant are considered.For the first time the different methods of the hydrophile-lilophile balance definition for solid particles in compact and dispersed form are suggested by the author. The use of hydrophile-lipophile characteristics of solid particles as a criterion of phase inversion in emulsion stabilisation and for other applications is discussed.

This book presents a number of selected papers given at the LB9 conference, held in Potsdam, Germany, in August 2000. It is dedicated to new techniques and methodologies for studying interfacial layers. One group of manuscripts deals with the application of surface plasmons at solid interfaces, used for example in resonance spectroscopy and light scattering. New applications of various types of Atomic Force Microscopy are reported making use of various modifications of tips. A number of chapters are dedicated to light emitting diodes built with the help of LB layers. The aim of these studies is the improvement of efficiency. Electrochemical methods were described as tools for developing sensors, in particular miniaturised pH or gas sensors.The application of synchrotron X-ray and NMR techniques have been described in detail in two extended chapters. It is demonstrated how molecular information can be detected by these methods for various types of interfacial layers.This monograph, along with 130 papers that have been submitted for publication in the special issues of relevant journals, represent the proceedings of the LBP conference.

Wave evolution on a falling film is a classical hydrodynamic instability whose rich wave dynamics have been carefully recorded in the last fifty years. Such waves are known to profoundly affect the mass and heat transfer of multi-phase industrial units.

This book describes the collective effort of both authors and their students in constructing a comprehensive theory to describe the complex wave evolution from nearly harmonic waves at the inlet to complex spatio-temporal patterns involving solitary waves downstream. The mathematical theory represents a significant breakthrough from classical linear stability theories, which can only describe the inlet harmonic waves and also extends classical soliton theory for integrable systems to real solitrary wave dynamics with dissipation. One unique feature of falling-film solitary wave dynamics, which drives much of the spatio-temporal wave evolution, is the irreversible coalescence of such localized wave structures. It represents the first full description of a hydrodynamic instability from inception to developed chaos. This approach should prove useful for other complex hydrodynamic instabilities and would allow industrial engineers to better design their multi-phase apparati by exploiting the deciphered wave dynamics. This publication gives a comprehensive review of all experimental records and existing theories and significantly advances state of the art on the subject and are complimented by complex and attractive graphics from computational fluid mechanics.

This title presents the state-of-the-art in molecular engineering and new developments in the fields of materials science, membrane biophysics, interfaces, sensing, and intermolecular interactions including molecular recognition.Topics covered are: the organization (orientation and association) of molecules in ultrathin films (monolayers) at the air/water interface; long range order in these films and in assemblies of such films on solid substrates; the interactions with solutes in the aqueous phase (including tensides, enzymes and analytes); and the potential applications of ultrathin films as nanometric modules in devices.�Contributions are from leading scientists in their fields�The book presents the most recent developments in molecular engineering�Aims to stimulate new developments in the field of materials science

Introduction to Molecular-Microsimulation for Colloidal Dispersions provides an introduction to molecular-microsimulation methods for colloidal dispersions and is suitable for both self-study and reference. It provides the reader with a systematic understanding of the theoretical background to simulation methods, together with a wide range of practical skills for developing computational programs. Exercises are included at the end of each chapter to further assist the understanding of the subjects addressed. Provides the reader with the theoretical background to molecular-microsimulation methods Suitable for both self-study and reference Aids the reader in developing programs to meet their own requirements

Transport Mediated by Electrified Interfaces provides an overview of the innovative use of electro-kinetic phenomena in experimentally exploring non-equilibrium regions of chemically non-reacting systems. Transport phenomena mediated by charged liquid-liquid interfaces and solid-liquid interfaces are also covered. Transport phenomena mediated by electrified interfaces are discussed in the context of a number of important areas, including, soil/water systems, phase transfer catalysis, animal/plant physiology and mimicking taste/smell sensing mechanisms. Provides an overview of the innovative use of electro-kinetic phenomena Discusses conventional electro-kinetics and other transport phenomena mediated by charged interfaces Of special interest to those working in the area of interface science

Interfacial Separation of Particles is concerned with the processing and separation of fine solid particles in liquid solutions using interfacial technology.Interfacial separation has been finding wide application in many industrial fields, such as pigment and filler production, mineral processing, environmental protection, hydrometallurgy, bioengineering, food and beverage industry and chemical industry. This book describes all interfacial separation techniques and discusses the general and specific fundamentals of the techniques. The book intends to promote theoretical understanding and the more promising developments of interfacial separation technology whilst broadening the reader's background knowledge of industrial suspensions.* Is clearly written based on strong systematic science fundamentals* Provides comprehensive coverage on particle technology, mineral processing and water treatment* Includes practical examples from the different industrial fields

Surface activity is present in living systems; for example in body fluid or cell soup and molecules of surface-active nature are crucial to living matter and its organization. Surface Activity in Drug Action proposes "a liquid membrane hypothesis of drug action" for surface-active drugs. Chapters 1-7 contains an account of the hypothesis and chapter 8 contains a general account of the application of surface activity in therapeutics. The methodology and presentation of the information makes Surface Activity in Drug Action valuable reading for students and researchers interested in surface activity.* Is clearly written * Includes contributions from prominent names in the field, such as Bhise and Subrahmanyam* Contains a general account of the application of surface activity in therapeutics

An electrorheological (ER) suspension is made from an insulating liquid medium embodying either a semi-conductive particulate material or a semi-conductive liquid material (usually a liquid crystal material). Since its mechanical properties can be easily controlled over a wide range (almost from a pure liquid to a solid), the ER fluid can be used as an electric and mechanical interface in various industrial areas, for example, in the automotive industrial for clutch, brake and damping systems and in robotic arm joints and hands. In addition, the ER technique can be used to fabricate advanced functional materials such as photonic crystals, smart inks, and heterogeneous polymer composites. The major objective of Electrorheological Fluids is to present a comprehensive survey on the ER suspensions in term of screening high performance ER materials, physical mechanisms of the ER effect, and the applications of ER technology.* Applications of ER suspensions are of wide interest both in academia and industry* Surveys a large body of literature on the mechanism of the ER effect and the design of industrially applicable ER devices* Discusses technological problems affiliated with industrial applications

Two key words define the scope of this book: 'ultrasound' and 'colloids'. Historically, there has been little real communication between practitioners in these two fields. Although there is a large body of literature devoted to ultrasound phenomenon in colloids, there is little recognition that such phenomena may be of real importance for both the development and applications of colloid science.�On the other side, colloid scientists have not embraced acoustics as an important tool for characterizing colloids. The lack of any serious dialogue between these scientific fields is the biggest motivation behind this book. Covers in detail�this multidisciplinary field�combining acoustics, electroacoustics, colloid science, analytical chemistry and rheology Provides a bibliography with more than 1,000 references Presents theories and their experimental verification, as well as�analysis of the methods and hardware pertaining to applications such as pharmaceuticals, ceramics, and polymers

This title is a greatly expanded and updated second edition of the original volume published by Elsevier in 1986. New material has been integrated with the original content in an organized and comprehensive manner.

Five new chapters have been included, which review over one and a half decades of research into lipid-coated microbubbles (LCM) and their medical applications. The new chapters contain much experimental data, which is examined in detail, along with relevant current literature.

This current edition builds on the original work in effectively filling the gap in the market for a comprehensive account of the surfactant stabilization of coated microbubbles.

Presents updated results from extensive multidisciplinary research on coated microbubbles Greatly expanded and updated 2nd edition, with five new chapters Fills the gap for a comprehensive and up-to-date account of subject matter

The main physicochemical aspects of foam and foam films such as preparation, structure, properties, are considered, giving a special emphasis on foam stability. It is shown that the foam and foam films are an efficient object in the study of various surface phenomena and in establishing regularities common for different interfaces, in particular, water/oil interface. The techniques and results on foam films have an independent meaning and involve the latest achievement in this field, with a focus on authors' results.

The book has an expressed monographic character. It reveals joint ideas, i.e. the quantitative approach in treating foams is based on foam film behaviour and the techniques for controlling the foam liquid content, developed by the authors. A major contribution represents the independent consideration of formation and stability of foam films in theoretical and experimental aspects. No monograph published so far reveals these topics in the mentioned manner. Data and information about foams, physicochemical characterization of surfactants, phospholipids and polymers can also be found. Furthermore, the book provides information about: techniques involved in the study of foam films and foam structure and properties; foam drainage; processes of destruction in gravitational and centrifugal fields; reasons for stability of films and their role in the processes running in the foam; mechanical, rheological, optical, thermophysical, electrical properties; foam destruction upon addition of antifoams (mechanism of destruction, techniques, application); scientific principles of controlling foam properties and their application in foam separation and concentration; enhanced oil recovery; thermodynamic and non-equilibrium properties of foam films, stabilized by surfactants, phospholipids and polymers; techniques for the study of surface forces; formation and stability of foam films; black films, including bilayers; new theories of stability of amphiphile bilayer; experiments involved in this stability; application in biology and medicine.

One of the few textbooks in the field, this volume deals with several aspects of the dynamics of colloids. A self-contained treatise, it fills the gap between research literature and existing books for graduate students and researchers. For readers with a background in chemistry, the first chapter contains a section on frequently used mathematical techniques, as well as statistical mechanics.

Some of the topics covered include:

. diffusion of free particles on the basis of the Langevin equation

.the separation of time, length and angular scales;

. the fundamental Fokker-Planck and Smoluchowski equations derived for interacting particles

. friction of spheres and rods, and hydrodynamic interaction of spheres (including three body interactions)

. diffusion, sedimentation, critical phenomena and phase separation kinetics

. experimental light scattering results.

For universities and research departments in industry this textbook makes vital reading.

The shape of drops and bubbles is the centre of interest for many interfacial scientists. This book describes the most recent accomplishments to make use of drops and bubbles in fundamental research and application.

After a general introduction into the mechanics of liquid menisci, chapters are dedicated to methods based on drops or bubbles. The chapters about the three main drop experiments provide the theoretical basis, a description of experimental set-ups, specific advantages and disadvantages, correction and calibration problems, experimental examples and their interpretation: pendent and sessile drop, drop volume, and spinning drop technique. The chapter about capillary pressure methods summarises different techniques and gives examples of applications, for instance measurements under microgravity.

The maximum bubble pressure technique as a particular capillary pressure method is described, with emphasis on the most recent developments which made this technique applicable to extremely short adsorption times, down to the range of milliseconds and less. Problems connected with aerodynamics and hydrodynamics are discussed and used to show the limits of this widely used standard method.

The oscillating bubble technique provides information not available by other techniques, for example about the dilational rheology of adsorption layers and relaxation processes at the interface.

The description of rising bubbles in surfactant solutions will contain the hydrodynamic basis as well as the theoretical description of the effect of interfacial layers on the movement of bubbles. Besides the theoretical basis experimental data, such as water purification, flotation processes etc. and the relevance for practical applications will be presented. The chapter about lung alveols demonstrates how important bubbles built by biological membranes are in everyday life. The relevance for medicine and biology as well as model studies is discussed.

An important example for the application of drops is metallurgy, where the surface tension of metals and alloys is an important parameter for many applications. The chapters on drop shape analysis by using fibre technique and on force measurements between emulsion droplets are of much practical relevance.

Lists of references and symbols are given separately at the end of each chapter while a common subject index is given at the end of the book.

The interfacial behaviour of surfactants and proteins, and their mixtures, is of importance in a wide range of areas such as food technology, detergency, cosmetics, coating processes, biomedicine, pharmacy and biotechnology. Methods such as surface and interfacial tension measurements and interfacial dilation and shear rheology characterise the relationships between these interfacial properties and the complex behaviour of foams and emulsions is established. Recently-developed experimental techniques, such as FRAP which enable the measurement of molecular mobility in adsorption layers, are covered in this volume. The development of theories to describe the thermodynamic surface state or the exchange of matter for proteins and protein/surfactant mixtures is also described.

Features of this book:

. Reflects the state-of-the-art research and application of protein interfacial layers rather than a snapshot of only some recent developments.

. Emphasis is placed on experimental details as well as recent theoretical developments.

. New experimental techniques applied to protein interfacial layers are described, such as FRAP or ADSA, or rheological methods to determine the mechanical behaviour of protein-modified interfaces.

. A large number of practical applications, ranging from emulsions relevant in food technology for medical problems such as lung surfactants, to the characterisation of foams intrinsic to beer and champagne production.

The book will be of interest to research and university institutes dedicated to interfacial studies in chemistry, biology, pharmacy, medicine and food engineering. Industrial departments for research and technology in food industry, pharmacy, medicine and brewery research will also find this volume of value.