Joan E. Shields - Böcker

This is a reference manual of the heats of formation and conformation of polycyclic hydrocarbons. The book compiles information on the polycyclic hydrocarbons from C5 to C14, including the IUPAC, Chemical Abstracts and trivial names; the Chemical Abstracts registry numbers; and the structures and heats of formation calculated by force field molecular mechanics.The book is directed to research-level chemists who are interested in this group of compounds and to institutions and industrial companies who work with these compounds, i.e. basic chemical companies and petroleum companies.The author is a well-known chemist and former president of the American Chemical Society Board of Directors.

An increasing number of industries now deal with materials in powder form. The surface area and porosity of powders are characteristics of particular importance in their industrial use. The previous edition of "Powder Surface Area and Porosity" continues to provide an introduction to the experimental methods used to study these properties and a handbook for those needing practical guidance on measurement of surface area, density, particle size and pore size. Particular features in this edition include an extended discussion of micropore analysis and an introduction to methods of particle size measurement, including sedimentation techniques. Part I of the book covers the important theories associated with the measurement of surface area and porosity, discussing gas adsorption, Langmuir and Brunauer, Emmett and Teller theories, adsorbate cross-sectional areas, Harkins and Jura methods, pore analysis by adsorption, microporosity, mercury porosimetry and sedimentation techniques.Part II describes and compares various experimental methods, including vacuum volumetric measurements, dynamic gravimetric and adsorption methods, mercury porosimetry, density measurements and sedimentation techniques. This book should be of interest to powder technology specialists in industry and academia, and graduate students in chemical engineering.

The growth of interest in newly developed porous materials has prompted the writing of this book for those who have the need to make meaningful measurements without the benefit of years of experience. One might consider this new book as the 4th edition of "Powder Surface Area and Porosity" (Lowell & Shields), but for this new edition we set out to incorporate recent developments in the understanding of fluids in many types of porous materials, not just powders. Based on this, we felt that it would be prudent to change the title to "Characterization of Porous Solids and Powders: Surface Area, Porosity and Density". This book gives a unique overview of principles associated with the characterization of solids with regard to their surface area, pore size, pore volume and density. It covers methods based on gas adsorption (both physi­ and chemisorption), mercury porosimetry and pycnometry. Not only are the theoretical and experimental basics of these techniques presented in detail but also, in light of the tremendous progress made in recent years in materials science and nanotechnology, the most recent developments are described. In particular, the application of classical theories and methods for pore size analysis are contrasted with the most advanced microscopic theories based on statistical mechanics (e.g. Density Functional Theory and Molecular Simulation). The characterization of heterogeneous catalysts is more prominent than in earlier editions; the sections on mercury porosimetry and particularly chemisorption have been updated and greatly expanded.

The rapid growth of interest in powders and their surface properties in many diverse industries prompted the writing of this book for those who have the need to make meaningful measurements without the benefit of years of experience. It is intended as an introduction to some of the elementary theory and experimental methods used to study the surface area, porosity, density, and particle size of powders. It may be found useful by those with little or no training in solid surfaces who have the need to learn quickly the rudiments of surface area, density, pore size, and particle size measurements. S. Lowell J.E. Shields Symbols Use of symbols for purposes other than those indicated in the following table are so defined in the text. Some symbols not shown in the table are also defined in the text. d adsorbate cross-sectional area A area; condensation coefficient; collision frequency C BET constant c concentration D diameter; coefficient of thermal diffusion E adsorption potential permeability aspect factor f F flow rate; force; feed rate g gravitational constant G Gibbs free energy S G free surface energy h heat of immersion per unit area; height H enthalpy heat of immersion Hi heat of adsorption Hsv BET intercept; filament current k thermal conductivity; specific reaction rate K Harkins-Jura constant C length L heat of liquefaction M mass M molecular weight MPa megapascals number of moles n number of molecules; number of particles N N Avogadro's num'ber molecular collisions per square cm per second