Jorge Ancheyta - Böcker

Many oil refineries employ hydroprocessing for removing sulfur and other impurities from petroleum feedstocks. Capable of handling heavier feedstocks than other refining techniques, hydroprocessing enables refineries to produce higher quality products from unconventional — and formerly wasted — sources. Hydroprocessing of Heavy Oils and Residua illustrates how to obtain maximum yields of high-value products from heavy oils and residue using hydroprocessing technologies.While most resources on hydroprocessing concentrate ongas oil and lower boiling products, this book details the chemistry involved and the process modifications required for the hydroprocessing of heavy crude oils and residua. Emphasizing the use of effective catalysts to ensure cleaner and more efficient industrial fuel processes, the book presents key principles of heterogeneous catalyst preparation, catalyst loading, and reactor systems. It explains how to evaluate and account for catalysts, reactor type, process variables, feedstock type, and feedstock composition in the design of hydroprocessing operations. The text concludes with examples of commercial processes and discusses methods of hydrogen production. To meet the growing demand for transportation fuels and fuel oil, modern oil refineries must find ways to produce high quality fuel products from increasingly heavy feedstocks. Hydroprocessing of Heavy Oils and Residua contains the fundamental concepts, technologies, and process modifications refineries need to adapt current hydroprocessing technologies for processing heavier feedstocks.

Modeling and Simulation of Catalytic Reactors for Petroleum Refining deals with fundamental descriptions of the main conversion processes employed in the petroleum refining industry: catalytic hydrotreating, catalytic reforming, and fluid catalytic cracking. Common approaches for modeling of catalytic reactors for steady-state and dynamic simulations are also described and analyzed. Aspects such as thermodynamics, reaction kinetics, process variables, process scheme, and reactor design are discussed in detail from both research and commercial points of view. Results of simulation with the developed models are compared with those determined at pilot plant scale as well as commercial practice. Kinetics data used in the reactor model are either taken from the literature or obtained under controlled experiments at the laboratory.

Many oil refineries employ hydroprocessing for removing sulfur and other impurities from petroleum feedstocks. Capable of handling heavier feedstocks than other refining techniques, hydroprocessing enables refineries to produce higher quality products from unconventional — and formerly wasted — sources. Hydroprocessing of Heavy Oils and Residua illustrates how to obtain maximum yields of high-value products from heavy oils and residue using hydroprocessing technologies.While most resources on hydroprocessing concentrate ongas oil and lower boiling products, this book details the chemistry involved and the process modifications required for the hydroprocessing of heavy crude oils and residua. Emphasizing the use of effective catalysts to ensure cleaner and more efficient industrial fuel processes, the book presents key principles of heterogeneous catalyst preparation, catalyst loading, and reactor systems. It explains how to evaluate and account for catalysts, reactor type, process variables, feedstock type, and feedstock composition in the design of hydroprocessing operations. The text concludes with examples of commercial processes and discusses methods of hydrogen production. To meet the growing demand for transportation fuels and fuel oil, modern oil refineries must find ways to produce high quality fuel products from increasingly heavy feedstocks. Hydroprocessing of Heavy Oils and Residua contains the fundamental concepts, technologies, and process modifications refineries need to adapt current hydroprocessing technologies for processing heavier feedstocks.

This book explores the common approaches to upgrade heavy and extra-heavy crude oils by means of catalytic hydrotreating, emphasizing hydrogen addition technology as well as carbon rejection alternatives. Kinetic and reactor models are combined with experimental data to simulate and optimize commercial-scale reactor performance.Key Features• Focuses on fixed-bed catalytic hydrotreating and catalysts and process scheme characteristics for commercial application.• Guides readers on hydrotreating process technology development from batch reactor experiments to semi-commercial test.• Describes step-by-step methodologies for development of kinetic models based on experimental data generated at different reaction scales.• Provides detailed explanation on how to formulate a reactor model for the simulation of catalytic hydrotreating of heavy oils.A comprehensive guide to the upgrading of crude oils, this book has particular appeal for petroleum refining industry professionals, catalyst developers, workshop instructors, professors, and their graduate and postgraduate students.

Written by a scientist and researcher with more than 25 years of experience in the field, this serves as a complete guide to catalyst activity loss during the hydroprocessing of heavy oils. Explores the physical and chemical properties of heavy oils and hydroprocessing catalysts; the mechanisms of catalyst deactivation; catalyst characterization by a variety of techniques and reaction conditions; laboratory and commercial information for model validations; and moreDemonstrates how to develop correlations and models for a variety of reaction scales with step-by-step descriptions and detailed experimental dataContains important implications for increasing operational efficiencies within the petroleum industryAn essential reference for professionals and researchers working in the refining industry as well as students taking courses on chemical reaction engineering

A practical approach to chemical reaction kinetics—from basic concepts to laboratory methods—featuring numerous real-world examples and case studiesThis book focuses on fundamental aspects of reaction kinetics with an emphasis on mathematical methods for analyzing experimental data and interpreting results. It describes basic concepts of reaction kinetics, parameters for measuring the progress of chemical reactions, variables that affect reaction rates, and ideal reactor performance. Mathematical methods for determining reaction kinetic parameters are described in detail with the help of real-world examples and fully-worked step-by-step solutions. Both analytical and numerical solutions are exemplified.  The book begins with an introduction to the basic concepts of stoichiometry, thermodynamics, and chemical kinetics. This is followed by chapters featuring in-depth discussions of reaction kinetics; methods for studying irreversible reactions with one, two and three components; reversible reactions; and complex reactions. In the concluding chapters the author addresses reaction mechanisms, enzymatic reactions, data reconciliation, parameters, and examples of industrial reaction kinetics. Throughout the book industrial case studies are presented with step-by-step solutions, and further problems are provided at the end of each chapter. Takes a practical approach to chemical reaction kinetics basic concepts and methodsFeatures numerous illustrative case studies based on the author’s extensive experience in the industryProvides essential information for chemical and process engineers, catalysis researchers, and professionals involved in developing kinetic modelsFunctions as a student textbook on the basic principles of chemical kinetics for homogeneous catalysisDescribes mathematical methods to determine reaction kinetic parameters with the help of industrial case studies, examples, and step-by-step solutionsChemical Reaction Kinetics is a valuable working resource for academic researchers, scientists, engineers, and catalyst manufacturers interested in kinetic modeling, parameter estimation, catalyst evaluation, process development, reactor modeling, and process simulation. It is also an ideal textbook for undergraduate and graduate-level courses in chemical kinetics, homogeneous catalysis, chemical reaction engineering, and petrochemical engineering, biotechnology.

Presents detailed information and study cases on experiments on hydrotreating catalysts for the petroleum industryCatalytic hydrotreating (HDT) is a process used in the petroleum refining industry for upgrading hydrocarbon streams—removing impurities, eliminating metals, converting asphaltene molecules, and hydrocracking heavy fractions. The major applications of HDT in refinery operations include feed pretreatment for conversion processes, post-hydrotreating distillates, and upgrading heavy crude oils. Designing HDT processes and catalysts for successful commercial application requires experimental studies based on appropriate methodologies. Experimental Methods for Evaluation of Hydrotreating Catalysts provides detailed descriptions of experiments in different reaction scales for studying the hydrotreating of various petroleum distillates. Emphasizing step-by-step methodologies in each level of experimentation, this comprehensive volume presents numerous examples of evaluation methods, operating conditions, reactor and catalyst types, and process configurations. In-depth chapters describe experimental setup and procedure, analytical methods, calculations, testing and characterization of catalyst and liquid products, and interpretation of experiment data and results. The text describes experimental procedure at different levels of experimentation—glass reactor, batch reactor, continuous stirred tank reactor, and multiple scales of tubular reactors—using model compounds, middle distillates and heavy oil. This authoritative volume: Introduces experimental setups used for conducting research studies, such as type of operation, selection of reactor, and analysis of productsFeatures examples focused on the evaluation of different reaction parameters and catalysts with a variety of petroleum feedstocksProvides experimental data collected from different reaction scalesIncludes experiments for determining mass transfer limitations and deviation from ideality of flow patternPresents contributions from leading scientists and researchers in the field of petroleum refining Experimental Methods for Evaluation of Hydrotreating Catalysts is an indispensable reference for researchers and professionals working in the area of catalytic hydrotreating, as well as an ideal textbook for courses in fields such as chemical engineering, petrochemical engineering, and biotechnology.

Catalytic In-Situ Upgrading of Heavy and Extra-Heavy Crude Oils A comprehensive guide to a cutting-edge and cost-effective refinement process for heavy oil Oil sufficiently viscous that it cannot flow normally from production wells is called heavy oil and constitutes as much as 70% of global oil reserves. Extracting and refining this oil can pose significant challenges, including very high transportation costs. As a result, processes which produce and partially refine heavy oil in situ, known as catalytic upgrading, are an increasingly important part of the heavy oil extraction process, and the reduced carbon footprint associated with these methods promises to make them even more significant in the coming years. Catalytic In-Situ Upgrading of Heavy and Extra-Heavy Crude Oils provides a comprehensive introduction to these processes. It introduces the properties and characteristics of heavy and extra-heavy oil before discussing different catalysts and catalyzing processes, their mechanisms and underlying physics, and more. It offers the full sweep of description and analysis required for petroleum and chemical engineers to understand this vital aspect of the modern oil industry. Readers will also find: Detailed discussion of subjects including electron paramagnetic resonance spectroscopy, nuclear magnetic resonance spectroscopy, and moreAnalysis of both liquid catalysts and nanoparticle catalystsA numerical simulation of the catalytic in-situ oil upgrading processCatalytic In-Situ Upgrading of Heavy and Extra-Heavy Crude Oils is a valuable reference for petroleum and chemical engineers as well as advanced undergraduate and graduate students in related fields.

During the upgrading of heavy petroleum, asphaltene is the most problematic impurity since it is the main cause of catalyst deactivation and sediments formation. Exploring many aspects related to asphaltenes composition and conversion, Asphaltenes: Chemical Transformation during Hydroprocessing of Heavy Oils highlights the various changes that these heavy and complex molecules undergo during catalytic hydroprocessing. After defining and characterizing asphaltene structure, the book examines the composition of petroleum and the processes and catalysts for upgrading heavy oils. It then details the characterization of asphaltenes after hydroprocessing and the effect of reaction conditions on their structures. The authors also analyze the deactivation and characterization of spent hydroprocessing catalysts as well as the role played by asphaltenes. They cover sediments formation during hydroprocessing and the role of asphaltenes on it. The final chapters describe the hydrocracking and kinetics of asphaltenes and the fractionation of heavy crudes and asphaltenes.Due to the increasing production of heavy crude oils, asphaltene has become one of the most studied molecules. This book provides a deep understanding of how asphaltenes transform during hydroprocessing, offering insight on designing catalysts and processing for the upgrading of heavy oils.

Master the fundamentals of reaction systems modeling for the age of decarbonization Reactor design is one of the most important parts of the oil and gas industry, with reactor processes and the accompanying technologies constantly evolving to meet industry needs. A crucial component of effective reactor design is modelling complex reaction systems, which can help predict commercial performance, shape safety procedures, and more. At a time when decarbonization and clean energy transition are among the fundamental global technological challenges, it has never been more important for engineers to grasp the cutting edge of reaction system modelling. Mathematical Modeling of Complex Reaction Systems in the Oil and Gas Industry provides a systematic introduction to this timely subject. Each chapter provides a step-by-step description of the kinetic and reactor models for a particular kind of process and its accompanying systems. Backed by voluminous experimental data and incorporating extensive simulation results, the book constitutes an indispensable contribution to the global search for clean energy solutions. Mathematical Modeling of Complex Reaction Systems in the Oil and Gas Industry readers will also find: All the required tools for developing new reactor models for different reaction scales Detailed discussion of topics including hydrocracking of heavy oils, catalyst deactivation, oxidative regeneration of catalysts, and many more Extensive treatment of both steady-state and dynamic simulations Mathematical Modeling of Complex Reaction Systems in the Oil and Gas Industry is ideal for chemical and process engineers, computational chemists and modelers, catalysis researchers, and any other researchers or professionals in petrochemical engineering and the oil and gas industry.

During the upgrading of heavy petroleum, asphaltene is the most problematic impurity since it is the main cause of catalyst deactivation and sediments formation. Exploring many aspects related to asphaltenes composition and conversion, Asphaltenes: Chemical Transformation during Hydroprocessing of Heavy Oils highlights the various changes that these heavy and complex molecules undergo during catalytic hydroprocessing. After defining and characterizing asphaltene structure, the book examines the composition of petroleum and the processes and catalysts for upgrading heavy oils. It then details the characterization of asphaltenes after hydroprocessing and the effect of reaction conditions on their structures. The authors also analyze the deactivation and characterization of spent hydroprocessing catalysts as well as the role played by asphaltenes. They cover sediments formation during hydroprocessing and the role of asphaltenes on it. The final chapters describe the hydrocracking and kinetics of asphaltenes and the fractionation of heavy crudes and asphaltenes.Due to the increasing production of heavy crude oils, asphaltene has become one of the most studied molecules. This book provides a deep understanding of how asphaltenes transform during hydroprocessing, offering insight on designing catalysts and processing for the upgrading of heavy oils.