H. Magdi Selim - Böcker

Understanding the mechanisms associated with metal complexes and the sequestering metal contaminants in the environment is essential for effective remediation. Heavy Metal Release in Soils describes and quantifies desorption/release kinetics and dissolution reactions in the release of heavy metals from soil.The book focuses on:New techniques - microscopic surface techniques, NMR and electrophoresis, XAFS, SFM, and time-resolved ATR-FTIRTheoretical analysis and kinetic approaches - adsorption/desorption hysteresis, competitive sorption and transport, multi-component models, speciation kinetics, isotherms and soil and metal parameters, and the role of soil properties on transportApplications - arsenic speciation and mobility in contaminated soils, modeling activity of CD, Zn, and Cu in contaminated soils, and in situ chemical immobilizationA timely addition to the literature, this book highlights the desorption/release mechanisms for the purpose of resolving remediation dilemmas in contaminated environments. It gives you the added advantage of case studies at both the microscopic and macroscopic scales, and provides both experimental and numerical investigations. With contributions from an international panel of authors, Heavy Metals Release in Soils fills a gap in the current literature concerned with subsurface contaminant fate and transport processes.

Physical Nonequilibrium in Soils provides cutting-edge knowledge on physical nonequilibrium phenomena in soils, offering unique insight into the complexity of our physical world. With 18 chapters comprising the book, topics coversoil properties fluid properties mechanistic models transfer function geostatistics fractal analysis cellular-automation fluids coupling of physical and chemical nonequilibrium models confirming and quantifying physical nonequilibrium in soils analytical solutions field-scale research environmental impacts.

The scaling issue remains one of the largest problems in soil science and hydrology. This book is a unique compendium of ideas, conceptual approaches, techniques, and methodologies for scaling soil physical properties. Scaling Methods in Soil Physics covers many methods of scaling that will be useful in helping scientists across a range of soil-related disciplines. The first single-source reference in this developing field, the text will help readers develop a greater understanding of how to interpret remote sensing data, delineate management zones in agricultural fields, and estimate water yield and geochemical fluxes in watersheds, among other applications.The authors present the state-of-the-art in addressing the fundamental scale-bridging problem and provide case studies crossing several levels of scale hierarchy. Scaling Methods in Soil Physics offers novel approaches based on geostatistics, artificial intelligence, wavelet transforms, fractal theory, soil-landscape relationships, computer simulations, and advances in theories of scale developed and tested to facilitate the use of soil physics data in a wide variety of soil/land/earth-related applications.

The fate of heavy metal particles in the environment is important because they tend to be reactive, mobile, and highly toxic. Reactivity and Transport of Heavy Metals in Soils examines the sometimes complex interactions that occur between metals and the soil they occupy. It discusses basic kinetic concepts and covers the predictability and consequences of metal-soil interactions.This practical guide presents and explains heavy metal issues crucial to hazardous waste site cleanup, including:

Most reported incidents of soil contamination include an array of heavy metals species rather than a single ion. The various interactions in these multicomponent or multiple-ion systems significantly impact the fate and transport of heavy metals, and competition for sorption sites on soil matrix surfaces is a common phenomenon. Because of this, considering competitive sorption is an important part of predicting contaminant transport. Competitive Sorption and Transport of Heavy Metals in Soils and Geological Media gives you the information needed to understand heavy metals’ sorption and transport in the vadose zone and aquifers.The book brings together state-of-the art research on the competitive sorption and mobility of single versus multiple heavy metal species. It also relates the transport mechanisms to the processes that govern sorption mechanisms. The work offers new experimental evidence on the fate of multiple heavy metals in soil columns and new field results on how multiple ions influence the mobility of metals in the soil profile under water-unsaturated flow.Emphasizing modeling approaches, the book begins with an overview of the competitive behavior of heavy metals. It then takes a closer look at various heavy metals, discussing their behavior in tropical soils, speciation and fractionation, accumulation, migration, competitive retention, and the contamination of water resources at the watershed scale. The book also presents extensive data on phosphate, a commonly used fertilizer, and its role in facilitating the release of trace elements. The final chapter looks at the effect of waterlogged conditions on arsenic and cadmium solubilization.Edited by an internationally recognized researcher and featuring expert contributors, this comprehensive work addresses the complex physical and chemical phenomena of sorption mechanisms. Presenting the latest research, it helps you to better predict the potential mobility of multiple heavy metals in soils.

Concerns regarding heavy metal contamination in terrestrial ecosystems have prompted increasing efforts on limiting their bioavailability in the root zone. The complexity of the hydrologic system gives rise to the need for understanding the fate and transport of trace elements in the soil-water-plant environment. Dynamics and Bioavailability of Heavy Metals in the Rootzone provides a multidisciplinary approach with emphasis on geohydrology, plant and soil science, and environmental chemistry. The primary focus of this book is on different approaches that describe the dynamics of heavy metals in the soil system. These approaches are key to providing direct information on the concentration of heavy metals and hence on their transport, toxicity, and bioavailability.The book includes chapters covering equilibrium and kinetic models of heavy metal interactions as well as non-equilibrium transport models. It also discusses chemical processes controlling soil solution concentrations and modeling of heavy metals adsorption. Addressing the biological component of heavy metal dynamics, this work examines rhizosphere microorganisms and phytoremediation. Colloid-associated transport, which can result in groundwater contamination, is discussed in relation to reclaimed mine sites. The authors also present an overview of recent advancements in the biogeochemistry of trace elements and their environmental implications. Additional chapters include examination of various natural environments including runoff waters at the watershed scale, heavy metal transformation in wetlands, dynamics of trace metals in frequently flooded soils, and effects on crops in biosolid-amended soils.Reliable assessment of potential risks resulting from the transport of trace elements in the soil environment requires the examination of complex chemical and biological interactions due to the heterogeneous nature of soils. This text describes the current state of the art in this field and explores innovative experimental and theoretical/modeling approaches that will enhance this knowledge. The book provides a coherent presentation of recent advances in techniques, modeling, and dynamics and bioavailability of heavy metals in the root zone.

During the last four decades, tremendous advances have been made towards the understanding of transport characteristics of contaminants in soils, solutes, and tracers in geological media. Transport & Fate of Chemicals in Soils: Principles & Applications offers a comprehensive treatment of the subject complete with supporting examples of mathematical models that describe contaminants reactivity and transport in soils and aquifers. This approach makes it a practical guide for designing experiments and collecting data that focus on characterizing retention as well as release kinetic reactions in soils and contaminant transport experiments in the laboratory, greenhouse), and in the field.The book provides the basic framework of the principals governing the sorption and transport of chemicalsin soils. It focuses on physical processes such as fractured media, multiregion, multiple porosities, and heterogeneity and effect of scale as well as chemical processes such as nonlinear kinetics, release and desorption hysteresis, multisite and multireaction reactions, and competitive-type reactions. The coverage also includes details of sorption behavior of chemicals with soil matrix surfaces as well the integration of sorption characteristics with mechanisms that govern solute transport in soils. The discussions of applications of the principles of sorption and transport are not restricted to contaminants, but also include nitrogen, phosphorus, and trace elements including essential micronutrients, heavy metals, military explosives, pesticides, and radionuclides.Written in a very clear and easy-to-follow language by a pioneer in soil science, this book details the basic framework of the physical and chemical processes governing the transport of contaminants, trace elements, and heavy metals in soils. Highly practical, it includes laboratory methods, examples, and empirical formulations. The approach taken by the author gives you not only the fundamentals of understanding of reactive chemicals retention and their transport in soils and aquifers, but practical guidance you can put to immediate use in designing experiments and collecting data.

Edited by One of the Best Specialists in Soil ScienceRecent studies reveal that Phosphorus (P) in the form of phosphate, a macronutrient essential for plant growth, and crop yields can influence the bioavailability, retention, and mobility of trace elements, metal(loid)s, and radio nuclides in soils. When this occurs, phosphates can affect the dynamics of heavy metals and influence soil characteristics, impacting soil mobility and toxicity. Phosphate in Soils: Interaction with Micronutrients, Radionuclides and Heavy Metalsutilizes the latest research to emphasize the role that phosphate plays in enhancing or reducing the mobility of heavy metals in soil, and the soil-water-plant environment. It provides an in-depth understanding of each heavy metal species, and expands on phosphate interactions in geological material.Composed of 12 chapters, this text: Provides an overview of the reactions of metal(loid)s and common P compounds that are used as fertilizer in soilsEmphasizes the effect of phosphorus on copper and zinc adsorption in acid soilsDiscusses findings on the influence of phosphate compounds on speciation, mobility, and bioavailability of heavy metals in soils as well as the role of phosphates on in situ and phytoremediation of heavy metals for contaminated soils Places emphasis on the influence of phosphate on various heavy metals species in soils, and their solubility/mobility and availabilityProvides extensive information on testing various high phosphate materials for remediation of heavy metal, micronutrients, and radionuclides contaminated sitesExplores the reactivity of heavy metals, micronutrients and radionuclides elements in several soilsPresents a case study illustrating various remediation efforts of acidic soils and remediation of Cu, Zn, and lead (Pb) contaminated soils around nonferrous industrial plantsEmphasizes the significance of common ions (cations and anions) on phosphate mobility and sorption in soils, and moreThe author includes analytical and numerical solutions along with hands-on applications, and addresses other topics that include the transport and sorption modeling of heavy metals in the presence of phosphate at different scales in the vadose zone.

Concerns regarding heavy metal contamination in terrestrial ecosystems have prompted increasing efforts on limiting their bioavailability in the root zone. The complexity of the hydrologic system gives rise to the need for understanding the fate and transport of trace elements in the soil-water-plant environment. Dynamics and Bioavailability of Heavy Metals in the Rootzone provides a multidisciplinary approach with emphasis on geohydrology, plant and soil science, and environmental chemistry. The primary focus of this book is on different approaches that describe the dynamics of heavy metals in the soil system. These approaches are key to providing direct information on the concentration of heavy metals and hence on their transport, toxicity, and bioavailability.The book includes chapters covering equilibrium and kinetic models of heavy metal interactions as well as non-equilibrium transport models. It also discusses chemical processes controlling soil solution concentrations and modeling of heavy metals adsorption. Addressing the biological component of heavy metal dynamics, this work examines rhizosphere microorganisms and phytoremediation. Colloid-associated transport, which can result in groundwater contamination, is discussed in relation to reclaimed mine sites. The authors also present an overview of recent advancements in the biogeochemistry of trace elements and their environmental implications. Additional chapters include examination of various natural environments including runoff waters at the watershed scale, heavy metal transformation in wetlands, dynamics of trace metals in frequently flooded soils, and effects on crops in biosolid-amended soils.Reliable assessment of potential risks resulting from the transport of trace elements in the soil environment requires the examination of complex chemical and biological interactions due to the heterogeneous nature of soils. This text describes the current state of the art in this field and explores innovative experimental and theoretical/modeling approaches that will enhance this knowledge. The book provides a coherent presentation of recent advances in techniques, modeling, and dynamics and bioavailability of heavy metals in the root zone.

Most reported incidents of soil contamination include an array of heavy metals species rather than a single ion. The various interactions in these multicomponent or multiple-ion systems significantly impact the fate and transport of heavy metals, and competition for sorption sites on soil matrix surfaces is a common phenomenon. Because of this, considering competitive sorption is an important part of predicting contaminant transport. Competitive Sorption and Transport of Heavy Metals in Soils and Geological Media gives you the information needed to understand heavy metals’ sorption and transport in the vadose zone and aquifers.The book brings together state-of-the art research on the competitive sorption and mobility of single versus multiple heavy metal species. It also relates the transport mechanisms to the processes that govern sorption mechanisms. The work offers new experimental evidence on the fate of multiple heavy metals in soil columns and new field results on how multiple ions influence the mobility of metals in the soil profile under water-unsaturated flow.Emphasizing modeling approaches, the book begins with an overview of the competitive behavior of heavy metals. It then takes a closer look at various heavy metals, discussing their behavior in tropical soils, speciation and fractionation, accumulation, migration, competitive retention, and the contamination of water resources at the watershed scale. The book also presents extensive data on phosphate, a commonly used fertilizer, and its role in facilitating the release of trace elements. The final chapter looks at the effect of waterlogged conditions on arsenic and cadmium solubilization.Edited by an internationally recognized researcher and featuring expert contributors, this comprehensive work addresses the complex physical and chemical phenomena of sorption mechanisms. Presenting the latest research, it helps you to better predict the potential mobility of multiple heavy metals in soils.

During the last four decades, tremendous advances have been made towards the understanding of transport characteristics of contaminants in soils, solutes, and tracers in geological media. Transport & Fate of Chemicals in Soils: Principles & Applications offers a comprehensive treatment of the subject complete with supporting examples of mathematical models that describe contaminants reactivity and transport in soils and aquifers. This approach makes it a practical guide for designing experiments and collecting data that focus on characterizing retention as well as release kinetic reactions in soils and contaminant transport experiments in the laboratory, greenhouse), and in the field.The book provides the basic framework of the principals governing the sorption and transport of chemicalsin soils. It focuses on physical processes such as fractured media, multiregion, multiple porosities, and heterogeneity and effect of scale as well as chemical processes such as nonlinear kinetics, release and desorption hysteresis, multisite and multireaction reactions, and competitive-type reactions. The coverage also includes details of sorption behavior of chemicals with soil matrix surfaces as well the integration of sorption characteristics with mechanisms that govern solute transport in soils. The discussions of applications of the principles of sorption and transport are not restricted to contaminants, but also include nitrogen, phosphorus, and trace elements including essential micronutrients, heavy metals, military explosives, pesticides, and radionuclides.Written in a very clear and easy-to-follow language by a pioneer in soil science, this book details the basic framework of the physical and chemical processes governing the transport of contaminants, trace elements, and heavy metals in soils. Highly practical, it includes laboratory methods, examples, and empirical formulations. The approach taken by the author gives you not only the fundamentals of understanding of reactive chemicals retention and their transport in soils and aquifers, but practical guidance you can put to immediate use in designing experiments and collecting data.

Edited by One of the Best Specialists in Soil ScienceRecent studies reveal that Phosphorus (P) in the form of phosphate, a macronutrient essential for plant growth, and crop yields can influence the bioavailability, retention, and mobility of trace elements, metal(loid)s, and radio nuclides in soils. When this occurs, phosphates can affect the dynamics of heavy metals and influence soil characteristics, impacting soil mobility and toxicity. Phosphate in Soils: Interaction with Micronutrients, Radionuclides and Heavy Metalsutilizes the latest research to emphasize the role that phosphate plays in enhancing or reducing the mobility of heavy metals in soil, and the soil-water-plant environment. It provides an in-depth understanding of each heavy metal species, and expands on phosphate interactions in geological material.Composed of 12 chapters, this text: Provides an overview of the reactions of metal(loid)s and common P compounds that are used as fertilizer in soilsEmphasizes the effect of phosphorus on copper and zinc adsorption in acid soilsDiscusses findings on the influence of phosphate compounds on speciation, mobility, and bioavailability of heavy metals in soils as well as the role of phosphates on in situ and phytoremediation of heavy metals for contaminated soils Places emphasis on the influence of phosphate on various heavy metals species in soils, and their solubility/mobility and availabilityProvides extensive information on testing various high phosphate materials for remediation of heavy metal, micronutrients, and radionuclides contaminated sitesExplores the reactivity of heavy metals, micronutrients and radionuclides elements in several soilsPresents a case study illustrating various remediation efforts of acidic soils and remediation of Cu, Zn, and lead (Pb) contaminated soils around nonferrous industrial plantsEmphasizes the significance of common ions (cations and anions) on phosphate mobility and sorption in soils, and moreThe author includes analytical and numerical solutions along with hands-on applications, and addresses other topics that include the transport and sorption modeling of heavy metals in the presence of phosphate at different scales in the vadose zone.

Understanding the mechanisms associated with metal complexes and the sequestering metal contaminants in the environment is essential for effective remediation. Heavy Metal Release in Soils describes and quantifies desorption/release kinetics and dissolution reactions in the release of heavy metals from soil.The book focuses on:New techniques - microscopic surface techniques, NMR and electrophoresis, XAFS, SFM, and time-resolved ATR-FTIRTheoretical analysis and kinetic approaches - adsorption/desorption hysteresis, competitive sorption and transport, multi-component models, speciation kinetics, isotherms and soil and metal parameters, and the role of soil properties on transportApplications - arsenic speciation and mobility in contaminated soils, modeling activity of CD, Zn, and Cu in contaminated soils, and in situ chemical immobilizationA timely addition to the literature, this book highlights the desorption/release mechanisms for the purpose of resolving remediation dilemmas in contaminated environments. It gives you the added advantage of case studies at both the microscopic and macroscopic scales, and provides both experimental and numerical investigations. With contributions from an international panel of authors, Heavy Metals Release in Soils fills a gap in the current literature concerned with subsurface contaminant fate and transport processes.

The hydrological and geochemical interactions between clay minerals and organic matter in soils directly influence the reaction, behavior, and mobility of heavy metals in soils. Geochemical and Hydrological Reactivity of Heavy Metals in Soils is one of few books that comprehensively illustrates this cause-and-effect relationship. It highlights analytical techniques such as nuclear magnetic resonance spectroscopy and environmental electron microscopy and reveals how molecular-level modeling is used to remove metal contaminants from the environment. It is thus a practical guide for soil and groundwater scientists, ecologists, and government regulators.