Kenneth D. Karlin – författare

The cutting edge of scientific reporting . . .

PROGRESS in Inorganic Chemistry

Nowhere is creative scientific talent busier than in the world of inorganic chemistry experimentation. Progress in Inorganic Chemistry continues in its tradition of being the most respected avenue for exchanging innovative research. This series provides inorganic chemists and materials scientists with a forum for critical, authoritative evaluations of advances in every area of the discipline. With contributions from internationally renowned chemists, this latest volume offers an in-depth, far-ranging examination of the changing face of the field, providing a tantalizing glimpse of the emerging state of the science.

"This series is distinguished not only by its scope and breadth, but also by the depth and quality of the reviews."—Journal of the American Chemical Society

"[This series] has won a deservedly honored place on the bookshelf of the chemist attempting to keep afloat in the torrent of original papers on inorganic chemistry."—Chemistry in Britain

CONTENTS OF VOLUME 54:

Atomlike Building Units of Adjustable Character: Solid-State and Solution Routes to Manipulating Hexanuclear Transition Metal Chalcohalide Clusters (Eric J. Welch and Jeffrey R. Long) Doped Semiconductor Nanocrystals: Synthesis, Characterization, Physical Properties, and Applications (J. Daniel Bryan and Daniel R. Gamelin) Stereochemical Aspects of Metal Xanthane Complexes: Molecular Structures and Supramolecular Self-Assembly (Edward R. T. Tiekink and Ionel Haiduc) Trivalent Uranium: A Versatile Species for Molecular Activation (Ilia Korobkov and Sandro Gambarotta) Comparison of the Chemical Biology of NO and HNO: An Inorganic Perspective (Katrina M. Miranda and David A. Wink) Alterations of Nucleobase pKa Values upon Metal Coordination: Origins and Consequences (Bernhard Lippert) Functionalization of Myoglobin (Yoshihito Watanabe and Takashi Hayashi)

This comprehensive series of volumes on inorganic chemistry provides inorganic chemists with a forum for critical, authoritative evaluations of advances in every area of the discipline. Every volume reports recent progress with a significant, up-to-date selection of papers by internationally recognized researchers, complemented by detailed discussions and complete documentation. Each volume features a complete subject index and the series includes a cumulative index as well.

Cutting-edge research and innovative science PROGRESS in Inorganic Chemistry Hailed by professional chemists as an index of the most influentialand current research being done in inorganic chemistry, Progress inInorganic Chemistry has also enjoyed the reputation as anindispensable working reference. Featuring the work ofinternationally renowned chemists, this newest volume provides aclear, authoritative examination of each critically new advance andinnovative tremor in inorganic chemistry today. "This series is a valuable addition to the library of thepracticing research chemist, and is a good starting point forstudents wishing to understand modern inorganic chemistry."--Canadian Chemical News "[This series] has won a deservedly honored place on the bookshelfof the chemist attempting to keep afloat in the torrent of originalpapers on inorganic chemistry." --Chemistry in Britain CONTENTS OF VOLUME 42 * Slow Proton-Transfer Reactions in Organometallic and BioinorganicChemistry (K. W. Kramarz and J. R. Norton, Colorado StateUniversity) * Higher Oligopyridines as a Structural Motif inMetallosupramolecular Chemistry (Edwin C. Constable, UniversitatBasel) * Ternary Transition Metal Sulfides (Bryan W. Eichhorn, Universityof Maryland) * Organoimido Complexes of the Transition Metals (David E. Wigley,University of Arizona) * Palladium Complex Catalyzed Oxidation Reactions (Andreas Heumann,Klaus-Joachim Jens, and Marius Reglier, Universite d''Aix-Marseille)

Cutting-edge research and innovative science... PROGRESS in Inorganic Chemistry Hailed by professional chemists as an index of the most influentialand current research being done in inorganic chemistry, Progress inInorganic Chemistry has also enjoyed the reputation as anindispensable working reference. Featuring the work ofinternationally renowned chemists, this newest volume provides aclear, authoritative examination of each critical new advance andinnovative development in inorganic chemistry today. "This series is distinguished not only by its scope and breadth,but also by the depth and quality of the reviews."--Journal of theAmerican Chemical Society "This series is a valuable addition to the library of thepracticing research chemist, and is a good starting point forstudents wishing to understand modern inorganicchemistry."--Canadian Chemical News "[This series] has won a deservedly honored place on the bookshelfof the chemist attempting to keep afloat in the torrent of originalpapers on inorganic chemistry."--Chemistry in Britain CONTENTS OF VOLUME 43 * Oxovanadium and Oxomolybdenum Clusters and Solids IncorporatingOxygen-Donor Ligands (M. Ishaque Kahn, Illinois Institute ofTechnology, and Jon Zubieta, Syracuse University) * The Application of Polychalcogenide Salts to the ExploratorySynthesis of Solid State Multinary Chalcogenides at IntermediateTemperatures (Mercouri G. Kanatzidis and Anthony C. Sutorik,Michigan State University) * Mechanistic and Kinetic Aspects of Transition Metal OxygenChemistry (Andreja Bakac, Iowa State University) * The Chemistry of Metal Complexes with Selenolate and TellurolateLigands (John Arnold, University of California, Berkeley) * Coordination Chemistry with Sterically Hindered Hydrotris(pyrazolyl) borate Ligands: Organometallic and BioinorganicPerspectives (Nobumasa Kitajima, Tokyo Institute of Technology, andWilliam B. Tolman, University of Minnesota) * Metal Complexes of Calixarenes (D. Max Roundhill, TulaneUniversity)

Innovation today . . . Practice tomorrow. PROGRESS in Inorganic Chemistry Today''s cutting-edge chemical experimentation is a foretaste of thetechnical arsenal of tomorrow''s chemist. Progress in InorganicChemistry affords instant and convenient access to every area ofinnovative chemical research and has long served as theprofessional chemist''s index to the newest and influential turns ininorganic chemistry. Featuring the work of internationally renownedchemists, Volume 45 discusses: * Selective Recognition of Organic Molecules by Metallohosts (JamesW. Canary and Bruce C. Gibb, New York University) * Metallacrowns: A New Class of Molecular Recognition Agents(Vincent L. Pecoraro, Ann J. Stemmler, Brian R. Gibney, Jeffrey J.Bodwin, Hsin Wang, Jeff W. Kampf, and Almut Barwinski, Universityof Michigan) * The Interpretation of Ligand Field Parameters (Adam J. Bridgemanand Malcolm Gerloch, University Chemical Laboratories) * Chemistry of Transition Metal Cyanide Compounds: ModernPerspectives (Kim R. Dunbar and Robert A. Heintz, Michigan StateUniversity) * Assembling Sugars and Metals: Novel Architectures andReactivities in Transition Metal Chemistry (Umberto Piarulli andCarlo Floriani, University of Lausanne) * Oxygen Activation Mechanism at the Binuclear Site of Heme-CopperOxidase Superfamily as Revealed by Time-Resolved Resonance RamanSpectroscopy (Teizo Kitagawa and Takashi Ogura, Institute forMolecular Science) "This series is distinguished not only by its scope and breadth,but also by the depth and quality of the reviews." --Journal of theAmerican Chemical Society "This series is a valuable addition to the library of thepracticing research chemist, and is a good starting point forstudents wishing to understand modern inorganic chemistry."--Canadian Chemical News "[This series] has won a deservedly honored place on the bookshelfof the chemist attempting to keep afloat in the torrent of originalpapers on inorganic chemistry." --Chemistry in Britain

Capturing today''s scientific imagination...PROGRESS in InorganicChemistry Nowhere is creative scientific talent busier than in the world ofinorganic chemistry experimentation. And the traditional forum forexchanging innovative research has been the respected Progress inInorganic Chemistry series. With contributions from internationallyrenowned chemists, this latest volume offers an in-depth,far-ranging examination of the changing face of the field,providing a tantalizing glimpse of the emerging state of thescience. CONTENTS OF VOLUME 46 * Anion Binding and Recognition by Inorganic Based Receptors (PaulD. Beer and David K. Smith) * Copper (I), Lithium and Magnesium Thiolate Complexes: An Overviewwith Due Mention of Selenolate and Tellurolate Analogues andRelated Silver (I) and Gold (I) Species (Maurits D. Janssen, DavidM. Grove, and Gerard van Koten) * The Role of the Pyrazolate Ligand in Building PolynuclearTransition Metal Systems (Girolamo La Monica and G. AttilloArdizzoia) * Recent Trends in Metal Alkoxide Chemistry (Ram C. Mehrotra andAnirudh Singh). "This series is distinguished not only by its scope and breadth,but also by the depth and quality of the reviews." --Journal of theAmerican Chemical Society. "This series is a valuable addition to the library of thepracticing research chemist, and is a good starting point forstudents wishing to understand modern inorganic chemistry."--Canadian Chemical News. "[This series] has won a deservedly honored place on the bookshelfof the chemist attempting to keep afloat in the torrent of originalpapers on inorganic chemistry." --Chemistry in Britain.

Straight from the frontier of scientific investigation . . . PROGRESS in Inorganic Chemistry Nowhere is creative scientific talent busier than in the world of inorganic chemistry. And the respected Progress in Inorganic Chemistry series has long served as an exciting showcase for new research in this area. With contributions from internationally renowned chemists, this latest volume reports the most recent advances in the field, providing a fascinating window on the emerging state of the science. "This series is distinguished not only by its scope and breadth, but also by the depth and quality of the reviews." --Journal of the American Chemical Society. "[This series] has won a deservedly honored place on the bookshelf of the chemist attempting to keep afloat in the torrent of original papers on inorganic chemistry." --Chemistry in Britain. CONTENTS OF VOLUME 47 Terminal Chalcogenido Complexes of the Transition Metals (Gerard Parkin, Columbia University) * Coordination Chemistry of Azacryptands (Jane Nelson, Vickie McKee, and Grace Morgan, The Queen''s University, Northern Ireland) * Polyoxometallate Complexes in Organic Oxidation Chemistry (Ronny Neumann, Hebrew University of Jerusalem, Israel) * Metal-Phosphonate Chemistry (Abraham Clearfield, Texas A&M University) * Oxidation of Hydrazine in Aqueous Solution (David M. Stanbury, Auburn University) * Metal Ion Reconstituted Hybrid Hemoglobins (B. Venkatesh, J. M. Rifkind, and P. T. Manoharan, Sophisticated Instrumentation Centre, IIT, Madras, India) * Three-Coordinate Complexes of "Hard" Ligands: Advances in Synthesis, Structure, and Reactivity (Christopher C. Cummins, Massachusetts Institute of Technology) * Metal-Carbohydrate Complexes in Solution (Jean-Francois Verchere and Stella Chapelle, Universite de Rouen, France; Feibo Xin and Debbie C. Crans, Colorado State University).

Straight from the frontier of scientific investigation . . .

Nowhere is creative scientific talent busier than in the world of inorganic chemistry. And the respected Progress in Inorganic Chemistry series has long served as an exciting showcase for new research in this area. With contributions from internationally renowned chemists, this latest volume reports the most recent advances in the field, providing a fascinating window on the emerging state of the science.

"This series is distinguished not only by its scope and breadth, but also by the depth and quality of the reviews."—Journal of the American Chemical Society

"[This series] has won a deservedly honored place on the bookshelf of the chemist attempting to keep afloat in the torrent of original papers on inorganic chemistry."—Chemistry in Britain

CONTENTS OF VOLUME 48:

Synthesis, Structure, and Properties of Organic-Inorganic Perovskites and Related Materials (David B. Mitzi, IBM T. J. Watson Research Center, Yorktown Heights, New York). Transition Metals in Polymeric 1 - Conjugated Organic Frameworks (Richard P. Kingsborough and Timothy M. Swager, Massachusetts Institute of Technology, Cambridge, Massachusetts). The Transition Metal Coordination Chemistry of Hemilabile Ligands (Caroline S. Slone, Dana A. Weinberger, and Chad A. Mirkin, Northwestern University, Evanston, Illinois). Organometallic Fluorides of the Main Group Metals Containing the C-M-F Fragment (Balaji R. Jagirdar, Eamonn F. Murphy, and Herbert W. Roesky, Universität Göttingen, Germany). Coordination Complex Impregnated Molecular Sieves-Synthesis, Characterization, Reactivity, and Catalysis (Partha P. Paul, Southwest Research Institute, San Antonio, Texas). Advances in Metal Boryl and Metal-Mediated B-X Activation Chemistry (Milton R. Smith III, Michigan State University, East Lansing, Michigan).

Breakthrough research and innovative science . . . PROGRESS in Inorganic Chemistry Nowhere is creative scientific talent busier than in the world of inorganic chemistry. This fascinating series provides the field of inorganic chemistry with a forum for critical and authoritative evaluations of advances in every area of the discipline. With contributions from internationally renowned chemists, this latest volume of Progress in Inorganic Chemistry continues to report the most recent advances with an innovative, cutting-edge style. "This series is distinguished not only by its scope and breadth, but also by the depth and quality of the reviews." -Journal of the American Chemical Society "[This series] has won a deservedly honored place on the bookshelf of the chemist attempting to keep afloat in the torrent of original papers on inorganic chemistry." -Chemistry in Britain CONTENTS OF VOLUME 49 * Nonclassical Metal Carbonyls (Anthony J. Lupinetti and Steven H. Strauss, Colorado State University, Fort Collins, Colorado, and Gernot Frenking, Philipps-Universitat Marburg, Germany) * The Influence of Ligands on Dirhodium(II) on Reactivity and Selectivity in Metal Carbene Reactions (Michael P. Doyle, University of Arizona, Tucson, Arizona, and Tong Ren, University of Miami, Coral Gables, Florida) * Coordination Chemistry of Transition Metals with Hydrogen Chalcogenide and Hydrochalcogenido Ligands (Maurizio Peruzzini and Isaac De Los Rios, Instituto per lo Studio della Stereochimica ed Energetica dei Composti de Coordinazione, CNR, Firenze, Italy, and Antonio Romerosa, Universidad de Almeria, Spain) * The Coordination Chemistry of Phosphinines, Their Polydentate and Macrocyclic Derivatives (Nicolas Mezailles, Francois Mathey, and Pascal le Floch, Ecole Polytechnique, Palaiseau Cedex, France) * Texaphyrins: Synthesis and Development of a Novel Class of Therapeutic Agents (Tarak D. Mody and Lei Fu, Pharmacyclics, Inc., Sunnyvale, California, and Jonathan L. Sessler, University of Texas at Austin, Texas) * The Chemistry of Synthetic Fe-Mo-S Clusters and Their Relevance to the Structure and Function of the Fe-Mo-S Center in Nitrogenase (Steve M. Malinak, Albion College, Michigan, and Dimitri Coucouvanis, University of Michigan, Ann Arbor, Michigan)

This series provides inorganic chemists and materials scientists with a forum for critical, authoritative evaluations of advances in every area of the discipline. Volume 56 continues to report recent advances with a significant, up-to-date selection of contributions by internationally-recognized researchers.

This series provides inorganic chemists and materials scientists with a forum for critical, authoritative evaluations of advances in every area of the discipline. Volume 56 continues to report recent advances with a significant, up-to-date selection of contributions by internationally-recognized researchers.

Covers the vastly expanding subject of oxidative processes mediated by copper ions within biological systems Copper-mediated biological oxidations offer a broad range of fundamentally important and potentially practical chemical processes that cross many chemical and pharmaceutical disciplines. This newest volume in the Wiley Series on Reactive Intermediates in Chemistry and Biology is divided into three logical areas within the topic of copper/oxygen chemistry— biological systems, theory, and bioinorganic models and applications—to explore the biosphere for its highly evolved and thus efficient oxidative transformations in the discovery of new types of interactions between molecular oxygen and copper ion. Featuring a diverse collection of subject matter unified in one complete and comprehensive resource, Copper-Oxygen Chemistry probes the fundamental aspects of copper coordination chemistry, synthetic organic chemistry, and biological chemistry to reveal both the biological and chemical aspects driving the current exciting research efforts behind copper-oxygen chemistry. In addition, Copper-Oxygen Chemistry: Addresses the significantly increasing literature on oxygen-atom insertion and carbon-carbon bond-forming reactions as well as enantioselective oxidation chemistries Progresses from biological systems to spectroscopy and theory, and onward to bioinorganic models and applications Covers a wide array of reaction types such as insertion and dehydrogenation reactions that utilize the cheap, abundant, and energy-containing O2 molecule With thorough coverage by prominent authors and researchers shaping innovations in this growing field, this valuable reference is essential reading for bioinorganic chemists, as well as organic, synthetic, and pharmaceutical chemists in academia and industry.

Cutting-edge research and innovative science PROGRESS in Inorganic Chemistry Hailed by professional chemists as an index of the most influentialand current research being done in inorganic chemistry, Progress inInorganic Chemistry has also enjoyed the reputation as anindispensable working reference. Featuring the work ofinternationally renowned chemists, this newest volume provides aclear, authoritative examination of each critically new advance andinnovative tremor in inorganic chemistry today. "This series is a valuable addition to the library of thepracticing research chemist, and is a good starting point forstudents wishing to understand modern inorganic chemistry."--Canadian Chemical News "[This series] has won a deservedly honored place on the bookshelfof the chemist attempting to keep afloat in the torrent of originalpapers on inorganic chemistry." --Chemistry in Britain CONTENTS OF VOLUME 42* Slow Proton-Transfer Reactions in Organometallic and BioinorganicChemistry (K. W. Kramarz and J. R. Norton, Colorado StateUniversity)* Higher Oligopyridines as a Structural Motif inMetallosupramolecular Chemistry (Edwin C. Constable, UniversitatBasel)* Ternary Transition Metal Sulfides (Bryan W. Eichhorn, Universityof Maryland)* Organoimido Complexes of the Transition Metals (David E. Wigley,University of Arizona)* Palladium Complex Catalyzed Oxidation Reactions (Andreas Heumann,Klaus-Joachim Jens, and Marius Reglier, Universite d'Aix-Marseille)

Cutting-edge research and innovative science... PROGRESS in Inorganic Chemistry Hailed by professional chemists as an index of the most influentialand current research being done in inorganic chemistry, Progress inInorganic Chemistry has also enjoyed the reputation as anindispensable working reference. Featuring the work ofinternationally renowned chemists, this newest volume provides aclear, authoritative examination of each critical new advance andinnovative development in inorganic chemistry today. "This series is distinguished not only by its scope and breadth,but also by the depth and quality of the reviews."--Journal of theAmerican Chemical Society "This series is a valuable addition to the library of thepracticing research chemist, and is a good starting point forstudents wishing to understand modern inorganicchemistry."--Canadian Chemical News "[This series] has won a deservedly honored place on the bookshelfof the chemist attempting to keep afloat in the torrent of originalpapers on inorganic chemistry."--Chemistry in Britain CONTENTS OF VOLUME 43* Oxovanadium and Oxomolybdenum Clusters and Solids IncorporatingOxygen-Donor Ligands (M. Ishaque Kahn, Illinois Institute ofTechnology, and Jon Zubieta, Syracuse University)* The Application of Polychalcogenide Salts to the ExploratorySynthesis of Solid State Multinary Chalcogenides at IntermediateTemperatures (Mercouri G. Kanatzidis and Anthony C. Sutorik,Michigan State University)* Mechanistic and Kinetic Aspects of Transition Metal OxygenChemistry (Andreja Bakac, Iowa State University)* The Chemistry of Metal Complexes with Selenolate and TellurolateLigands (John Arnold, University of California, Berkeley)* Coordination Chemistry with Sterically Hindered Hydrotris(pyrazolyl) borate Ligands: Organometallic and BioinorganicPerspectives (Nobumasa Kitajima, Tokyo Institute of Technology, andWilliam B. Tolman, University of Minnesota)* Metal Complexes of Calixarenes (D. Max Roundhill, TulaneUniversity)

Innovation today . . . Practice tomorrow. PROGRESS in Inorganic Chemistry Today's cutting-edge chemical experimentation is a foretaste of thetechnical arsenal of tomorrow's chemist. Progress in InorganicChemistry affords instant and convenient access to every area ofinnovative chemical research and has long served as theprofessional chemist's index to the newest and influential turns ininorganic chemistry. Featuring the work of internationally renownedchemists, Volume 45 discusses:* Selective Recognition of Organic Molecules by Metallohosts (JamesW. Canary and Bruce C. Gibb, New York University)* Metallacrowns: A New Class of Molecular Recognition Agents(Vincent L. Pecoraro, Ann J. Stemmler, Brian R. Gibney, Jeffrey J.Bodwin, Hsin Wang, Jeff W. Kampf, and Almut Barwinski, Universityof Michigan)* The Interpretation of Ligand Field Parameters (Adam J. Bridgemanand Malcolm Gerloch, University Chemical Laboratories)* Chemistry of Transition Metal Cyanide Compounds: ModernPerspectives (Kim R. Dunbar and Robert A. Heintz, Michigan StateUniversity)* Assembling Sugars and Metals: Novel Architectures andReactivities in Transition Metal Chemistry (Umberto Piarulli andCarlo Floriani, University of Lausanne)* Oxygen Activation Mechanism at the Binuclear Site of Heme-CopperOxidase Superfamily as Revealed by Time-Resolved Resonance RamanSpectroscopy (Teizo Kitagawa and Takashi Ogura, Institute forMolecular Science) "This series is distinguished not only by its scope and breadth,but also by the depth and quality of the reviews." --Journal of theAmerican Chemical Society "This series is a valuable addition to the library of thepracticing research chemist, and is a good starting point forstudents wishing to understand modern inorganic chemistry."--Canadian Chemical News "[This series] has won a deservedly honored place on the bookshelfof the chemist attempting to keep afloat in the torrent of originalpapers on inorganic chemistry." --Chemistry in Britain

Capturing today's scientific imagination...PROGRESS in InorganicChemistry Nowhere is creative scientific talent busier than in the world ofinorganic chemistry experimentation. And the traditional forum forexchanging innovative research has been the respected Progress inInorganic Chemistry series. With contributions from internationallyrenowned chemists, this latest volume offers an in-depth,far-ranging examination of the changing face of the field,providing a tantalizing glimpse of the emerging state of thescience. CONTENTS OF VOLUME 46* Anion Binding and Recognition by Inorganic Based Receptors (PaulD. Beer and David K. Smith)* Copper (I), Lithium and Magnesium Thiolate Complexes: An Overviewwith Due Mention of Selenolate and Tellurolate Analogues andRelated Silver (I) and Gold (I) Species (Maurits D. Janssen, DavidM. Grove, and Gerard van Koten)* The Role of the Pyrazolate Ligand in Building PolynuclearTransition Metal Systems (Girolamo La Monica and G. AttilloArdizzoia)* Recent Trends in Metal Alkoxide Chemistry (Ram C. Mehrotra andAnirudh Singh). "This series is distinguished not only by its scope and breadth,but also by the depth and quality of the reviews." --Journal of theAmerican Chemical Society. "This series is a valuable addition to the library of thepracticing research chemist, and is a good starting point forstudents wishing to understand modern inorganic chemistry."--Canadian Chemical News. "[This series] has won a deservedly honored place on the bookshelfof the chemist attempting to keep afloat in the torrent of originalpapers on inorganic chemistry." --Chemistry in Britain.

Straight from the frontier of scientific investigation . . . PROGRESS in Inorganic Chemistry Nowhere is creative scientific talent busier than in the world of inorganic chemistry. And the respected Progress in Inorganic Chemistry series has long served as an exciting showcase for new research in this area. With contributions from internationally renowned chemists, this latest volume reports the most recent advances in the field, providing a fascinating window on the emerging state of the science. "This series is distinguished not only by its scope and breadth, but also by the depth and quality of the reviews." --Journal of the American Chemical Society. "[This series] has won a deservedly honored place on the bookshelf of the chemist attempting to keep afloat in the torrent of original papers on inorganic chemistry." --Chemistry in Britain. CONTENTS OF VOLUME 47 Terminal Chalcogenido Complexes of the Transition Metals (Gerard Parkin, Columbia University)* Coordination Chemistry of Azacryptands (Jane Nelson, Vickie McKee, and Grace Morgan, The Queen's University, Northern Ireland)* Polyoxometallate Complexes in Organic Oxidation Chemistry (Ronny Neumann, Hebrew University of Jerusalem, Israel)* Metal-Phosphonate Chemistry (Abraham Clearfield, Texas A&M University)* Oxidation of Hydrazine in Aqueous Solution (David M. Stanbury, Auburn University)* Metal Ion Reconstituted Hybrid Hemoglobins (B. Venkatesh, J. M. Rifkind, and P. T. Manoharan, Sophisticated Instrumentation Centre, IIT, Madras, India)* Three-Coordinate Complexes of "Hard" Ligands: Advances in Synthesis, Structure, and Reactivity (Christopher C. Cummins, Massachusetts Institute of Technology)* Metal-Carbohydrate Complexes in Solution (Jean-Francois Verchere and Stella Chapelle, Universite de Rouen, France; Feibo Xin and Debbie C. Crans, Colorado State University).

Breakthrough research and innovative science . . . PROGRESS in Inorganic Chemistry Nowhere is creative scientific talent busier than in the world of inorganic chemistry. This fascinating series provides the field of inorganic chemistry with a forum for critical and authoritative evaluations of advances in every area of the discipline. With contributions from internationally renowned chemists, this latest volume of Progress in Inorganic Chemistry continues to report the most recent advances with an innovative, cutting-edge style. "This series is distinguished not only by its scope and breadth, but also by the depth and quality of the reviews."-Journal of the American Chemical Society "[This series] has won a deservedly honored place on the bookshelf of the chemist attempting to keep afloat in the torrent of original papers on inorganic chemistry."-Chemistry in Britain CONTENTS OF VOLUME 49* Nonclassical Metal Carbonyls(Anthony J. Lupinetti and Steven H. Strauss, Colorado State University, Fort Collins, Colorado, and Gernot Frenking, Philipps-Universitat Marburg, Germany)* The Influence of Ligands on Dirhodium(II) on Reactivity and Selectivity in Metal Carbene Reactions(Michael P. Doyle, University of Arizona, Tucson, Arizona, and Tong Ren, University of Miami, Coral Gables, Florida)* Coordination Chemistry of Transition Metals with Hydrogen Chalcogenide and Hydrochalcogenido Ligands(Maurizio Peruzzini and Isaac De Los Rios, Instituto per lo Studio della Stereochimica ed Energetica dei Composti de Coordinazione, CNR, Firenze, Italy, and Antonio Romerosa, Universidad de Almeria, Spain)* The Coordination Chemistry of Phosphinines, Their Polydentate and Macrocyclic Derivatives(Nicolas Mezailles, Francois Mathey, and Pascal le Floch, Ecole Polytechnique, Palaiseau Cedex, France)* Texaphyrins: Synthesis and Development of a Novel Class of Therapeutic Agents(Tarak D. Mody and Lei Fu, Pharmacyclics, Inc., Sunnyvale, California, and Jonathan L. Sessler, University of Texas at Austin, Texas)* The Chemistry of Synthetic Fe-Mo-S Clusters and Their Relevance to the Structure and Function of the Fe-Mo-S Center in Nitrogenase(Steve M. Malinak, Albion College, Michigan, and Dimitri Coucouvanis, University of Michigan, Ann Arbor, Michigan)

This series provides inorganic chemists and materials scientists with a forum for critical, authoritative evaluations of advances in every area of the discipline. Volume 50 continues to report recent advances with a significant, up-to-date selection of contributions on topics such as the following: Structural and mechanistic investigations in asymmetric copper;Catalyzed reactions;Phenoxyl radical complexes;Synthesis of large pore zeolites and molecular sieves;Inorganic nanoclusters with fullerene-like structure and nanotubes

This series provides inorganic chemists and materials scientists with a forum for critical, authoritative evaluations of advances in every area of the discipline. Volume 50 continues to report recent advances with a significant, up-to-date selection of contributions on topics such as the following: Structural and mechanistic investigations in asymmetric copper; Catalyzed reactions; Phenoxyl radical complexes; Synthesis of large pore zeolites and molecular sieves; Inorganic nanoclusters with fullerene-like structure and nanotubes

Progress in Inorganic Chemistry continues in its tradition of being the most respected forum for exchanging innovative research. This series provides inorganic chemists and materials scientists with a community where critical, authoritative evaluations of advances in every area of the discipline are exchanged. With contributions from internationally renowned chemists, this latest volume offers an in-depth, far-ranging examination of the changing face of the field, providing a tantalizing glimpse of the emerging state of the science.

The cutting edge of scientific reporting . . .PROGRESS in Inorganic ChemistryNowhere is creative scientific talent busier than in the world of inorganic chemistry experimentation. Progress in Inorganic Chemistry continues in its tradition of being the most respected avenue for exchanging innovative research. This series provides inorganic chemists and materials scientists with a forum for critical, authoritative evaluations of advances in every area of the discipline. With contributions from internationally renowned chemists, this latest volume offers an in-depth, far-ranging examination of the changing face of the field, providing a tantalizing glimpse of the emerging state of the science."This series is distinguished not only by its scope and breadth, but also by the depth and quality of the reviews."-Journal of the American Chemical Society"[This series] has won a deservedly honored place on the bookshelf of the chemist attempting to keep afloat in the torrent of original papers on inorganic chemistry."-Chemistry in BritainCONTENTS OF VOLUME 53* Main Group Dithiocarbamate Complex (Peter J. Heard)* Transition Metal Dithiocarbamates-1978-2003 (Graeme Hogarth)

This comprehensive series of volumes on inorganic chemistry provides inorganic chemists with a forum for critical, authoritative evaluations of advances in every area of the discipline. Every volume reports recent progress with a significant, up-to-date selection of papers by internationally recognized researchers, complemented by detailed discussions and complete documentation. Each volume features a complete subject index and the series includes a cumulative index as well.

The cutting edge of scientific reporting . . .PROGRESS in Inorganic ChemistryNowhere is creative scientific talent busier than in the world of inorganic chemistry experimentation. Progress in Inorganic Chemistry continues in its tradition of being the most respected avenue for exchanging innovative research. This series provides inorganic chemists and materials scientists with a forum for critical, authoritative evaluations of advances in every area of the discipline. With contributions from internationally renowned chemists, this latest volume offers an in-depth, far-ranging examination of the changing face of the field, providing a tantalizing glimpse of the emerging state of the science."This series is distinguished not only by its scope and breadth, but also by the depth and quality of the reviews."—Journal of the American Chemical Society"[This series] has won a deservedly honored place on the bookshelf of the chemist attempting to keep afloat in the torrent of original papers on inorganic chemistry."—Chemistry in BritainCONTENTS OF VOLUME 54: Atomlike Building Units of Adjustable Character: Solid-State and Solution Routes to Manipulating Hexanuclear Transition Metal Chalcohalide Clusters (Eric J. Welch and Jeffrey R. Long)Doped Semiconductor Nanocrystals: Synthesis, Characterization, Physical Properties, and Applications (J. Daniel Bryan and Daniel R. Gamelin)Stereochemical Aspects of Metal Xanthane Complexes: Molecular Structures and Supramolecular Self-Assembly (Edward R. T. Tiekink and Ionel Haiduc)Trivalent Uranium: A Versatile Species for Molecular Activation (Ilia Korobkov and Sandro Gambarotta)Comparison of the Chemical Biology of NO and HNO: An Inorganic Perspective (Katrina M. Miranda and David A. Wink)Alterations of Nucleobase pKa Values upon Metal Coordination: Origins and Consequences (Bernhard Lippert)Functionalization of Myoglobin (Yoshihito Watanabe and Takashi Hayashi)

The cutting edge of scientific reporting . . .PROGRESS in Inorganic ChemistryNowhere is creative scientific talent busier than in the world of inorganic chemistry experimentation. Progress in Inorganic Chemistry continues in its tradition of being the most respected avenue for exchanging innovative research. This series provides inorganic chemists and materials scientists with a forum for critical, authoritative evaluations of advances in every area of the discipline. With contributions from internationally renowned chemists, this latest volume offers an in-depth, far-ranging examination of the changing face of the field, providing a tantalizing glimpse of the emerging state of the science."This series is distinguished not only by its scope and breadth, but also by the depth and quality of the reviews."-Journal of the American Chemical Society"[This series] has won a deservedly honored place on the bookshelf of the chemist attempting to keep afloat in the torrent of original papers on inorganic chemistry."-Chemistry in BritainCONTENTS OF VOLUME 54* Atomlike Building Units of Adjustable Character: Solid-State and Solution Routes to Manipulating Hexanuclear Transition Metal Chalcohalide Clusters (Eric J. Welch and Jeffrey R. Long)* Doped Semiconductor Nanocrystals: Synthesis, Characterization, Physical Properties, and Applications (J. Daniel Bryan and Daniel R. Gamelin)* Stereochemical Aspects of Metal Xanthane Complexes: Molecular Structures and Supramolecular Self-Assembly (Edward R. T. Tiekink and Ionel Haiduc)* Trivalent Uranium: A Versatile Species for Molecular Activation (Ilia Korobkov and Sandro Gambarotta)* Comparison of the Chemical Biology of NO and HNO: An Inorganic Perspective (Katrina M. Miranda and David A. Wink)* Alterations of Nucleobase pKa Values upon Metal Coordination: Origins and Consequences (Bernhard Lippert)* Functionalization of Myoglobin (Yoshihito Watanabe and Takashi Hayashi)

The cutting edge of scientific reporting . . . PROGRESS in Inorganic Chemistry Nowhere is creative scientific talent busier than in the world of inorganic chemistry experimentation. Progress in Inorganic Chemistry continues in its tradition of being the most respected avenue for exchanging innovative research. This series provides inorganic chemists and materials scientists with a forum for critical, authoritative evaluations of advances in every area of the discipline. With contributions from internationally renowned chemists, this latest volume offers an in-depth, far-ranging examination of the changing face of the field, providing a tantalizing glimpse of the emerging state of the science. "This series is distinguished not only by its scope and breadth, but also by the depth and quality of the reviews." -Journal of the American Chemical Society "[This series] has won a deservedly honored place on the bookshelf of the chemist attempting to keep afloat in the torrent of original papers on inorganic chemistry." -Chemistry in Britain CONTENTS OF VOLUME 54 * Atomlike Building Units of Adjustable Character: Solid-State and Solution Routes to Manipulating Hexanuclear Transition Metal Chalcohalide Clusters (Eric J. Welch and Jeffrey R. Long) * Doped Semiconductor Nanocrystals: Synthesis, Characterization, Physical Properties, and Applications (J. Daniel Bryan and Daniel R. Gamelin) * Stereochemical Aspects of Metal Xanthane Complexes: Molecular Structures and Supramolecular Self-Assembly (Edward R. T. Tiekink and Ionel Haiduc) * Trivalent Uranium: A Versatile Species for Molecular Activation (Ilia Korobkov and Sandro Gambarotta) * Comparison of the Chemical Biology of NO and HNO: An Inorganic Perspective (Katrina M. Miranda and David A. Wink) * Alterations of Nucleobase pKa Values upon Metal Coordination: Origins and Consequences (Bernhard Lippert) * Functionalization of Myoglobin (Yoshihito Watanabe and Takashi Hayashi)

The cutting edge of scientific reporting . . . PROGRESS in Inorganic Chemistry Nowhere is creative scientific talent busier than in the world of inorganic chemistry experimentation. Progress in Inorganic Chemistry continues in its tradition of being the most respected avenue for exchanging innovative research. This series provides inorganic chemists and materials scientists with a forum for critical, authoritative evaluations of advances in every area of the discipline. With contributions from internationally renowned chemists, this latest volume offers an in-depth, far-ranging examination of the changing face of the field, providing a tantalizing glimpse of the emerging state of the science. "This series is distinguished not only by its scope and breadth, but also by the depth and quality of the reviews." -Journal of the American Chemical Society "[This series] has won a deservedly honored place on the bookshelf of the chemist attempting to keep afloat in the torrent of original papers on inorganic chemistry." -Chemistry in Britain CONTENTS OF VOLUME 53 * Main Group Dithiocarbamate Complex (Peter J. Heard) * Transition Metal Dithiocarbamates-1978-2003 (Graeme Hogarth)

Covers the vastly expanding subject of oxidative processes mediated by copper ions within biological systems

Copper-mediated biological oxidations offer a broad range of fundamentally important and potentially practical chemical processes that cross many chemical and pharmaceutical disciplines. This newest volume in the Wiley Series on Reactive Intermediates in Chemistry and Biology is divided into three logical areas within the topic of copper/oxygen chemistry— biological systems, theory, and bioinorganic models and applications—to explore the biosphere for its highly evolved and thus efficient oxidative transformations in the discovery of new types of interactions between molecular oxygen and copper ion. Featuring a diverse collection of subject matter unified in one complete and comprehensive resource, Copper-Oxygen Chemistry probes the fundamental aspects of copper coordination chemistry, synthetic organic chemistry, and biological chemistry to reveal both the biological and chemical aspects driving the current exciting research efforts behind copper-oxygen chemistry. In addition, Copper-Oxygen Chemistry:

Addresses the significantly increasing literature on oxygen-atom insertion and carbon-carbon bond-forming reactions as well as enantioselective oxidation chemistries

Progresses from biological systems to spectroscopy and theory, and onward to bioinorganic models and applications

Covers a wide array of reaction types such as insertion and dehydrogenation reactions that utilize the cheap, abundant, and energy-containing O2 molecule

With thorough coverage by prominent authors and researchers shaping innovations in this growing field, this valuable reference is essential reading for bioinorganic chemists, as well as organic, synthetic, and pharmaceutical chemists in academia and industry.

Covers the vastly expanding subject of oxidative processes mediated by copper ions within biological systems

Copper-mediated biological oxidations offer a broad range of fundamentally important and potentially practical chemical processes that cross many chemical and pharmaceutical disciplines. This newest volume in the Wiley Series on Reactive Intermediates in Chemistry and Biology is divided into three logical areas within the topic of copper/oxygen chemistry— biological systems, theory, and bioinorganic models and applications—to explore the biosphere for its highly evolved and thus efficient oxidative transformations in the discovery of new types of interactions between molecular oxygen and copper ion. Featuring a diverse collection of subject matter unified in one complete and comprehensive resource, Copper-Oxygen Chemistry probes the fundamental aspects of copper coordination chemistry, synthetic organic chemistry, and biological chemistry to reveal both the biological and chemical aspects driving the current exciting research efforts behind copper-oxygen chemistry. In addition, Copper-Oxygen Chemistry:

Addresses the significantly increasing literature on oxygen-atom insertion and carbon-carbon bond-forming reactions as well as enantioselective oxidation chemistries

Progresses from biological systems to spectroscopy and theory, and onward to bioinorganic models and applications

Covers a wide array of reaction types such as insertion and dehydrogenation reactions that utilize the cheap, abundant, and energy-containing O2 molecule

With thorough coverage by prominent authors and researchers shaping innovations in this growing field, this valuable reference is essential reading for bioinorganic chemists, as well as organic, synthetic, and pharmaceutical chemists in academia and industry.