Gas-Phase Combustion Chemistry

Inbunden, Engelska, 1999

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Beskrivning

This book supersedes Gardiner's 1984 "Combustion Chemistry. " It is an updated, comprehensive coverage of the aspects of combustion chemistry that are relevant to gas-phase combustion of hydrocarbons. It includes an extended discussion of air pollutant chemistry and aspects of combustion. The book newly reviews elementary reactions of nitrogen, sulfur and chlorine compounds that are relevant to combustion. Methods of combustion modeling and rate coefficient estimation which have been established during the recent years are presented, as well as access to databases for combustion thermochemistry and modeling.

Produktinformation

Utgivningsdatum:1999-12-10
Mått:155 x 235 x 35 mm
Vikt:1 004 g
Format:Inbunden
Språk:Engelska
Antal sidor:543
Upplaga:2
Förlag:Springer-Verlag New York Inc.
ISBN:9780387988610

Utforska kategorier

Fysikalisk kemi inom Naturvetenskap och teknik
Kemi inom Naturvetenskap och teknik
Miljöteknik inom Naturvetenskap och teknik

Innehållsförteckning

1. Combustion Chemistry Modeling.- 1.1. Introduction.- 1.2. Oxidation of hydrogen and carbon monoxide.- 1.3. Hydrocarbon combustion chemistry.- 1.4. Nitrogen, sulfur, and halogens in flames.- 1.5. Combustion of alternative fuels.- 1.6. Combustion inhibitors.- 1.7. Combustion promoters.- 1.8. Reduced chemistry models of combustion.- 1.9. Resources for combustion chemistry modeling.- 1.10. References.- 2. Combustion Chemistry of Nitrogen.- 2.1. Introduction.- 2.2. Overview of nitrogen chemistry.- 2.3. Unimolecular and chemically activated bimolecular reactions.- 2.4. Analysis of hydrogen atom abstraction reactions.- 2.5. Updated rate coefficients for the H/N/O system.- 2.6. QRRK treatments.- 2.7. Other reactions of interest.- 2.8. Illustrative modeling results.- 2.9. Summary.- 2.10. Acknowledgments.- 2.11. References.- 3. Kinetics and Mechanisms of the Oxidation of Gaseous Sulfur Compounds.- 3.1. Introduction.- 3.2. Sulfur emissions.- 3.3. Elementary reactions.- 3.4. Basic chemistry of sulfur in combustion environments.- 3.5. Thermochemistry of sulfur-containing compounds.- 3.6. Observations and conclusions.- 3.7. Acknowledgments.- 3.8. References.- 4. Survey of Rate Coefficients in the C-H-Cl-O System.- 4.1. Introduction.- 4.2. Electronic structure and thermochemistry.- 4.3. Characteristic features of elementary reactions of chlorine.- 4.4. Reaction mechanisms.- 4.5. Survey of elementary reactions.- 4.6. Data gaps and suggestions for future work.- 4.7. Acknowledgments.- 4.8. References.- 5. Ideal Gas Thermochemical Data for Combustion and Air Pollution Use.- 5.1. Introduction.- 5.2. Thermochemical database.- 5.3. Sources of thermochemical data.- 5.4. Thermochemical polynomials.- 5.5. Calculation procedures.- 5.6. Accuracy of the database.- 5.7. Accuracy of standard enthalpies of formation.- 5.8. Other sources of thermochemical data.- 5.9. Format of the database.- 5.10. Conversion factors.- 5.11. Internet transfer of the database.- 5.12. References.- 5.13. Table of standard enthalpies of formation.