Introduction to the Properties of Fluids and Solids

Robert A. Heidemann is associated with the Department of Chemical and Petroleum Engineering at the University of Calgary. Ayodeji A. Jeje is associated with the Department of Chemical and Petroleum Engineering at the University of Calgary. Farhang Mohtadi is associated with the Department of Chemical and Petroleum Engineering at the University of Calgary.

• 1. Introduction1.1 The States of Matter1.2 Atoms and Molecules1.3 The Properties of Matter2. Basic Concepts and Principles2.1 Scales of Magnitude in Space and Time 2.2. Fundamental and Derived outcomes 2.3 The Conservation Principles 2.4 The Concepts of Temperature 2.5 Interconvertibility of Energy 3. Notations about the Nature of Matter 3.1 Early Notations about the Structure of Matter 3.1.1 Dalton's Postulates 3.1.2 Avogadro's Hypothesis 3.2 Contemporary Picture of the Atom 3.2.1 The Nucleus 3.2.2 The Electron 3.2.2 The Elementary Particles 3.3 Proof of the Particulate Nature of Matter 3.3.1 Brownian Motion 3.3.2 Field Emission Microscopy 3.3.3 Radioactivity 3.4 The Classification of Elements 3.4.1 The Periodic Table 3.4.2 Chemical Reactivity 3.5 The Size of Atoms and Molecules 3.5 The Nature of Bonds Between Atoms and Molecules 3.7 Potential Energy Functions 3.8 Structure of Solids 3.8.1 Crystals and non-Crystals 3.8.2 Bravais Lattices 3.8.3 Atomic Densities and Dimensions 3.9 The States of Matter and Their TransformationsEquilibrium Between Phases of Matter4.1 States of Equilibrium 4.2 Phases and Composition 4.3 The Phase Rule 4.3.1 The Number of Phases, P 4.3.2 The Number of Independent Components, C 4.3.3 The Degrees of Freedom, F 4.3.4 Phase Rule Examples 4.4 Phase Equilibria in Single Component Systems 4.4.1 Single Phase Systems 4.4.2 Two Phase Systems 4.4.3 Three Phase Systems 4.4.4 Systems with more than Three Phases 4.4.5 The Pressure-Temperature Diagram for a Pure Substance 4.4.6 The Pressure-Volume Diagram for a Pure Substance 4.4.7 The Critical Point 4.4.8 The Lever Rule 4.4.9 The P-V-T Surface 4.5 Systems with Two Independent Components4.5.1 Binary Phase Diagrams 4.6 Vapor-Liquid Systems 4.6.1 Two Completely Miscible Liquids 4.6.2 Two Completely Miscible Liquids with Azeotropic Point 4.6.3 Two Partially Miscible Liquids 4.7 Liquid-Solid Systems 4.7.1 Completely Miscible Solids 4.7.2 Immiscible Solids 4.7.3 Partially Miscible Solids 4.7.4 Invariant Reactions 4.7.5 Compound Phases 4.8 Phase Diagrams for Some Systems of Special Engineering Interest 4.8.1 The Iron-Carbon System 4.8.2 Steeles and Cast-Irons 4.8.3 Non-Equilibrium Steeles 4.8.4 Copper-Zinc Mixtures 4.8.5 Methan-n-Heptane Mixtures 5. Ideal Gasses 5.1 P-V-T Behavior of the Ideal Gas 5.2 The Equation of the State of an Ideal Gas 5.2.1 The Universal Gas Constant 5.3 Ideal Gas Mixtures 5.4 Elementary Kinetic Theory of Gasses 5.5 Deductions from the Kinetic Theory 5.5.1 Boyle's Law 5.5.2 Avogadro's Law 5.5.3 Temperature and Motion of Molecules 5.5.4 Distribution of Molecular Velocities in Gasses 5.5.5 The Relationship between the Gas Constant and Heat Capacities 5.5.6 Mean Free Path and Collision of Molecules 5.6 Transport Properties of Gasses 5.6.1 Transfer of Momentum; Viscosity 5.6.2 Conduction of Heat; Thermal Conductivity 5.6.3 Molecular Diffusion; Diffusivity 6. Real Gasses 6.1 Deviation from Ideal Gas Behavior 6.2 P-V-T Behavior of Real Gases 6.3 The van der Walls Equation of State 6.4 Applicability of the van der Waals Equation 6.5 The van der Waals Equation and the Critical Point 6.6. Other Equations of State 6.7 Compressibility Factor and Corresponding States 6.8 Real Gas Mixtures 6.8.1 The Pseudocritical Point Method 6.8.2 Application of Dalton's and Amagat's Laws 6.8.3 Mixing Rules Method 7. Liquids 7.1 The Liquid State 7.1.1 Models of the Liquid State 7.1.2 The Glassy State and Liquid Crystals 7.2 Volumetric Behaviour of Liquids 7.2.1 Thermal Expransion of Liquids 7.2.2 Compressibility; Tait's Equation 7.2.3 The van der Waals Equation 7.2.4 The Corresponding States 7.3 Energy Effects in Liquids 7.3.1 Heat Capacity 7.3.2 Latent Heat of Vaporization 7.3.3 The Clausis&Clapeyron Equation 7.3.4 Correlating Vapor Pressure Data 7.3.5 Equilibrium Pressure Above Liquid Mixtures 7.4 Cohesion and Surface Tension 7.4.1 Surface Tension; Pressure Inside Drops and Bubbles 7.4.2 The Contact Angle 7.4.3 Capillary Rise 7.4.4 Interfacial Tension 7.4.5 Variations in Surface Tension 7.5 Colligative Properties of Liquid Solutions 7.5.1 Elevation of Boiling Point 7.5.2 Depression of Freezing Point 7.5.3 Osmotic Pressure 7.6 Transport Properties of Liquids 7.6.1 Viscosity of Liquids 7.6.2 Thermal Conductivity of Liquids 7.6.3 Molecular Diffusion in Liquids 8. The Motion of Fluids 8.1 The Basic Concepts 8.1.1 Stress and Strain in Fluids 8.1.2 Ideal Fluids 8.1.3 Newtonian Fluids 8.1.4 The Effects of Temperature and Pressure on Viscosity 8.1.5 Non-Newtonian Fluids 8.1.6 The Measurement of Viscosity 8.2 Potential Flow 8.2.1 Bernoulli's Equation 8.3 Flow of Viscous Fluids 8.3.1 The Boundary Layer 8.4 Laminar Flow in Pipes; The Hagen-Poiseuille Equation 8.4.1 Velocity Distribution in a Pipe8.4.2 Power Consumption 8.4.3 Working Equations for Laminar Flow 8.5 Turbulent Flow in Piper 8.5.1 The Friction Factor 8.5.2 Power Consumption 8.5.3 Pressure Drop in Fittings, Bends and Valves 8.6 Drag on Submerged Bodies 8.6.1 Flow on a Flat Plate 8.6.2 Flow on a Curved Surface 8.6.3 Drag on a Two-dimensional Surface 9. The Structure and Transport of Properties of Solids 9.1 Macrostructure of Solids 9.1.1 Crystalline Solutions 9.1.2 Amorphous Solids 9.1.3 Polymeric Solids 9.2 Thermal Properties in Heat Conduction 9.1.1 Heat Capacity 9.1.2 Thermal Expansion 9.2.3 Thermal Conductivity 9.2.4 The Rate of Heat Conduction 9.3 Diffusion in Solids 9.3.1 Mechanisms of Diffusion in Solids 9.3.2 The Phenomenological Theory of Diffusion 9.3.3 Diffusion of Neutrons 9.3.4 Diffusion of Porous and Non-porous Solids 9.3.5 Solid Diffusivity Data 9.4 The Transport of Electrical Charge in Solids 9.4.1 Basic Conception and Terminologies 9.4.2 Electric Conduction in Metals 9.4.3 Superconductivity 9.4.4 Semiconductors 10. Stress-Strain Relationships for Solids 10.1 Stress and Strain in Solids 10.1.1 Normal and Shear Stresses 10.1.2 Normal and Shear Strains 10.2.3 Typical Stress-Strain Behaviors 10.2 Elastic Deformation of Solids 10.2.1 Young Modulus for Linear Deformation 10.2.2 Poisson's Ratio 10.2.3 The Bulk Modulus for Volume Change 10.2.4 Modulus of Rigidity for Shear Deformation 10.2.5 Effect of Anisotropy on Elasticity 10.2.6 Effects of Temperature on Elasticity 10.3 Plastic Deformation 10.3.1 Maximum Strength of Perfect Crystals 10.3.2 Dislocations and Slip 10.4 Linear Visco-Elastic Models 10.4.1 The Maxwell Models 10.4.2 The Temperature Effects on Visco-Elastic Models 10.5 Creep 10.5.1 Correlating Minimum Creep Rate 10.6 Brittle Failure 10.6.1 Effect of Cracks on Strength 10.6.2 Brittle-Ductile Transition Appendix 1 - Constants and Units Appendix B - Properties of Elements and Pure Substances Appendix C - Volumetric PropertiesSubject Index