• Fri frakt över 249 kr
  • •
  • Snabba leveranser
  • •
  • Billiga böcker
Kundservice

Du är på sajten för privatpersoner.

Företag, bibliotek eller offentlig verksamhet?

Du handlar på classic.bokus.com, där alla dina funktioner finns intakta.
Till classic.bokus.com
Bokus logotyp. Gå till startsidan.
  • Erbjudanden
  • Nyheter
  • Student
  • Topplistor
  • Barn & ungdom
  • Bokus Play
  • E-böcker
  • Pocketböcker
  • Spel & pussel

10% rabatt på allt med kod NYSTART10 →

Sidfot

Mina sidor

    Hjälp

    • Kundservice
    • Vanliga frågor och svar
    • Frakt och leverans
    • Retur vid ångerrätt
    • Reklamera vara
    • Betalning
    • Köpvillkor
    • Allmänna villkor
    • Information om webbplatsens tillgänglighet

    Om Bokus

    • Om oss
    • Pressrum
    • För studenter
    • För företag
    • För bibliotek och offentlig verksamhet
    • För leverantörer
    • Hållbarhet

    Populärt

    • Aktuella erbjudanden
    • Presentkort
    • Studentlitteratur
    • Nya böcker
    • Topplistor
    • Signerade böcker
    • Engelska böcker

    Inspiration

    • Boktips
    • BookTok
    • Populära bokserier
    • Barnbokskaraktärer
    • Populära författare
    Logotyp för Bokus
    Följ oss på Facebook (extern länk)Följ oss på Instagram (extern länk)Följ oss på YouTube (extern länk)Följ oss på TikTok (extern länk)
    bokus @ CookiesAnpassa cookiesIntegritetspolicyKöpvillkor
    Till Citymail hemsida (extern länk)Till Budbee hemsida (extern länk)Till Postnord hemsida (extern länk)Till Schenker hemsida (extern länk)Till Early Bird hemsida (extern länk)Till Walleys hemsida (extern länk)
    1. Naturvetenskap och teknik
    2. Matematik och naturvetenskap
    3. Kemi
    4. Organisk kemi

    Organo Main Group Chemistry

    AvKin-ya Akiba

    Häftad, Engelska, 2011

    1 088 kr

    Beställningsvara. Skickas inom 5-8 vardagar. Fri frakt över 249 kr.

    Fler format och utgåvor

    E-bok

    1 206 kr

    E-bok

    1 246 kr

    Beskrivning

    Forging a new association; main group elements and organic chemistryCovering the essentials of all main group elements in organic chemistry, along with the synthesis and reactions of their organic compounds in just one volume, Organo Main Group Chemistry breaks important new ground. While main group chemistry has traditionally been classified as part of inorganic chemistry, this book establishes the organic chemistry of main group elements for the first time.The organic compounds of elements in the second period of the periodic table, which are centered around carbon, are the major components of animals and plants, while those in the third period and below also play key roles worthy of discussion when studying main group element chemistry.The major chapters describe synthesis and reactivity of organic compounds in the third period and below and are arranged according to the order of the periodic table. Starting with the role of lithium and magnesium cations, the chapters reach fluorine and iodine compounds. The first two chapters summarize the unique and common characteristics of main group elements in relation to carbon. The latter chapters deal with modern topics that address the unique characteristics of organo main group compounds.Suitable for professional researchers, chemistry professors, and advanced students, Organo Main Group Chemistry presents a novel new approach to the way we view both main groups and organic chemistry itself.

    Produktinformation

    • Utgivningsdatum:2011-11-09
    • Mått:158 x 236 x 16 mm
    • Vikt:417 g
    • Format:Häftad
    • Språk:Engelska
    • Antal sidor:288
    • Förlag:John Wiley & Sons Inc
    • ISBN:9780470450338

    Utforska kategorier

    • Organisk kemi inom Naturvetenskap och teknik

    Mer om författaren

    KIN-YA AKIBA, PHD, is a Professor Emeritus in the Department of Chemistry at Hiroshima University and a visiting researcher at the Advanced Research Institute for Science and Engineering at Waseda University. Among his many honors are the 1996 Humboldt Research Award, the 1997 Award by the Chemical Society of Japan, and the 2000 Medal with Purple Ribbon by the Prime Minister of Japan.

    Recensioner i media

    “Summing Up: Highly recommended.  Chemistry libraries serving academic students at all levels, researchers/faculty, and professionals.”  (Choice, 1 March 2012)

    Innehållsförteckning

    • Preface ix 1 Main Group Elements and Heteroatoms: Scope and Characteristics 11.1 Aufbau Principle and Sign of Orbitals / 11.2 Electronic Configuration of an Atom: Main Group Elements and Heteroatoms / 31.3 Fundamental Properties of Main Group Elements / 51.4 Acidity of Carboxylic Acid and Substituent Effect / 71.5 Heteroatom Effect / 101.5.1 Stabilization of α-Carbocation by Resonance: Stereoelectronic Effect / 101.5.2 Coordination with Lewis Acids / 15References / 16Notes 1: Electronegativity 17Notes 2: Importance of Formal Logic-I: Oxidation Number and Formal Charge 19Notes 3: Importance of Formal Logic-II: Octet Rule, Eighteen-Electron Rule, Hypervalence 232 Main Group Element Effect 252.1 What Is Main Group Element Effect? / 252.2 Single Bond Energy and π –Bond Energy / 272.3 Hypervalent Compound / 312.4 Effect of Hypervalent Bond (1): 3c–4e Bond and Structure / 332.5 Effect of Hypervalent Bond (2): Apicophilicity and Pseudorotation / 412.6 Effect of Hypervalent Bond (3): Ligand Coupling Reaction (LCR) and Edge Inversion / 452.7 Effect of σX−C / 462.8 Effect of σ ∗ X−C / 48Notes 4: (σ, σ ∗) and (π, π ∗): HMO (Hueckel Molecular Orbital) and Electrocyclic Reaction 573 Lithium, Magnesium, and Copper Compounds 633.1 Synthesis / 643.2 Structure / 663.3 Reaction / 683.3.1 Deprotonation as Base / 693.3.2 Nucleophilic Reaction / 723.3.3 Conjugate Addition of Lithium Dimethylcuprate / 76References / 774 Boron and Aluminum Compounds 794.1 Synthesis / 804.2 Structure / 824.3 Reaction / 84References / 885 Silicon, Tin, and Lead Compounds 915.1 Synthesis / 925.2 Reaction / 945.3 Organotin and Lead Compounds / 100References / 104Notes 5: Stable Carbene and Its Complex 1056 Phosphorus, Antimony, and Bismuth Compounds 1116.1 Phosphorus Compounds / 1126.2 Synthesis of Organophosphorus Compounds / 1136.3 Tertiary Phosphine and Its Nucleophilic Reaction / 1156.4 Arbuzov Reaction / 1176.5 Perkow Reaction / 1186.6 Synthesis of Optically Active Phosphines / 1196.7 Ylide and Wittig Reaction and Related Ones / 1236.8 Reactions of Phosphonium Salts and Formation of Phosphoranes / 1316.9 Freezing BPR and Its Effect / 1386.10 Antimony and Bismuth Compounds / 143References / 146Notes 6: Dreams of Staudinger and Wittig 149Notes 7: Stereochemistry in Nucleophilic Substitution of MX4-type Compounds: Inversion or Retention 1557 Sulfur, Selenium, and Tellurium Compounds 1597.1 Sulfur Compounds / 1607.2 Synthesis of Organosulfur Compounds / 1607.3 Reactions of Organosulfur Compounds / 1667.4 Structure and Reaction of Hypervalent OrganosulfurCompounds / 1707.5 Selenium and Tellurium Compounds / 175References / 178Notes 8: Inversion Mechanism of NH3 and NF3: Vertex Inversion or Edge Inversion 1818 Organohalogen Compounds: Fluorine and Iodine Compounds 1878.1 Synthesis of Chlorine and Bromine Compounds / 1888.2 Fluorine Compounds / 1908.3 Iodine Compounds / 195References / 1999 Atrane and Transannular Interaction: Formation of Hypervalent Bond 2019.1 Introduction / 2019.2 Silatrane and Atrane / 2029.3 Transannular Interaction (1) / 2089.4 Transannular Interaction (2) / 210References / 21110 Unsaturated Compounds of Main Group Elements of Third Period and Heavier 21310.1 Introduction / 21310.2 Unsaturated Bonds of Group 15 Elements of Third Period and Heavier / 21510.3 Unsaturated Bonds of Group 14 Elements of Third Period and Heavier / 21910.4 Aromatic Compounds of Group 14 Elements / 222References / 22311 Ligand Coupling Reaction 22511.1 Introduction / 22511.2 Selectivity of Ligand Coupling Reaction: Theoretical Investigation / 22611.3 Ligand Coupling Reaction of Organic Compounds of Phosphorus, Antimony, and Bismuth / 22711.4 Ligand Coupling Reaction of Organic Compounds of Sulfur, Selenium, and Tellurium / 23711.5 Ligand Coupling Reaction of Organoiodine Compounds / 241References / 245Notes 9: Hexavalent Organotellurium Compounds 24712 Hypervalent Carbon Compounds: Can Hexavalent Carbon Exist? 25112.1 Introduction / 25112.2 Attempts for Pentacoordinate Hypervalent Carbon Species / 25312.3 Synthesis of Pentacoordinate Hypervalent Carbon Species (10-C-5) and Bond Switching at Carbon and Boron / 25412.4 Attempts to Hexacoordinate Hypervalent Carbon Species (12-C-6) / 259References / 262Notes 10: Main Group Element Porphyrins 265Index 269