Water Chemistry

Vernon L. Snoeyink and David Jenkins are the authors of Water Chemistry, published by Wiley.

• Chapter 1 Introduction 11.1 Properties of Water 11.2 Composition of Several Types of Water 31.3 Methods of Expressing Concentration 141.4 Additional Reading 23Chapter 2 Chemical Kinetics 242.1 Introduction 242.2 Collisions of Reacting Species 242.3 Orientations of Reactants 262.4 The Rate Law 272.5 Reaction Mechanisms 362.6 Effect of Temperature on Reaction Rate 402.7 Catalysis 442.8 Empirical Rate Laws 482.9 Problems 552.10 Additional Reading 57Chapter 3 Chemical Equilibrium 583.1 Introduction 583.2 The Dynamic Nature of Chemical Equilibrium 583.3 The Thermodynamic Basis of Chemical Equilibrium 603.4 Enthalpy and the Temperature Dependence of the Equilibrium Constant 713.5 Nonideal Behavior of Ions and Molecules in Solution 743.6 Problems 823.7 Additional Reading 85Chapter 4 Acid-Base Chemistry 864.1 Introduction 864.2 Definition of Terms 864.3 Rate of Reaction 934.4 Equilibrium Calculations – A General Approach 954.5 Strong Acid-Strong Base Calculations 1024.6 Weak Acid-Weak Base Calculations 1084.7 Graphical Procedure for Equilibrium Calculations – pC-pH Diagrams 1144.8 Determination of Temperature and Ionic Strength Effects on Equilibria Using pC-pH diagrams 1224.9 Multiprotic Acid-Conjugate Base Equilibrium Calculations 1254.10 Ionization Fractions and Distribution diagrams 1344.11 Mixtures of Acids and Bases – pH Calculation 1364.12 pH Buffers and Buffer Intensity 1464.13 The Carbonate System 1564.14 Problems 1924.15 Additional Reading 195Chapter 5 Coordination Chemistry 1975.1 Introduction 1975.2 Nomenclature and Definitions of Terms 1975.3 Reaction Rate 2005.4 Complex Stability and Equilibrium Calculations 2015.5 Metal Ion Hydrolysis – H2O and OH as Ligands 2175.6 Complexes with Other Inorganic Ligands 2175.7 Complexes with Organic Ligands 2235.8 Problems 2415.9 Additional Reading 242Chapter 6 Precipitation and Dissolution 2436.1 Introduction 2436.2 Precipitation and Dissolution Kinetics 2446.3 Equilibrium Calculations 2476.4 Solubility of Salts of Weak Acids and Bases 2586.5 Effect of Complexation on Solubility 262   6.6 Competitive Effects of Several Ligands 2706.7 Calcium Carbonate Solubility and Water Stability 2826.8 Phosphate Chemistry 2986.9 Problems 3136.10 Additional Reading 315Chapter 7 Oxidation – Reduction Reactions 3167.1 Introduction 3167.2  Redox Stoichiometry 3167.3 Redox Equilibria 3227.4 Electron Activity and pϵ 3387.5 Graphical Representation of Redox Equilibria 3437.6 Corrosion 3637.7 Iron Chemistry 3787.8 Chlorine Chemistry 3867.9 Biologically Important Redox Reactions 4047.10 Electrochemical Measurements 4147.11 Problems 4267.12 Additional Reading 430Appendix 1 Ionization Fractions 431Appendix 2 Answers to Problems 435Appendix 3 Useful Data 442Index 453