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    1. Naturvetenskap och teknik
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    4. Fysikalisk kemi

    Chemical Reactions and Their Control on the Femtosecond Time Scale

    20th Solvay Conference on Chemistry, Volume 101

    AvPierre Gaspard,Irene Burghardt

    Inbunden, Engelska, 1997

    Del 113 i serien Advances in Chemical Physics

    5 082 kr

    Beställningsvara. Skickas inom 5-8 vardagar. Fri frakt över 249 kr.

    Beskrivning

    Continuing the tradition of the Advances in Chemical Physics series, Volume 101: Chemical Reactions and Their Control on the Femtosecond Time Scale details the extraordinary findings reported at the XXth Solvay Conference on Chemistry, held at the Université Libre de Bruxelles, Belgium, from November 28 to December 2, 1995. This new volume discusses the remarkable opportunities afforded by the femtosecond laser, focusing on the host of phenomena this laser has made it possible to observe. Examining molecules on the intrinsic time scale of their vibrations as well as their dissociative motions and electronic excitations represents only part of a broadened scientific window made possible by the femtosecond laser.The assembled studies, with follow-up discussions, reflect the many specialties and perspectives of the Conference's 65 participants as well as their optimism concerning the breadth of scientific discovery now open to them. The studies shed light on the laser's enhanced technical reach in the area of coherent control of chemical reactions as well as of more general quantum systems. The theoretical fundamentals of femto-chemistry, the unique behavior of the femtosecond laser, and a view toward future technological applications were also discussed: Femtochemistry: chemical reaction dynamics and their controlCoherent control with femtosecond laser pulsesFemtosecond chemical dynamics in condensed phasesControl of quantum many-body dynamicsExperimental observation of laser controlSolvent dynamics and RRKM theory of clustersHigh-resolution spectroscopy and intramolecular dynamicsMolecular Rydberg states and ZEKE spectroscopyTransition-state spectroscopy and photodissociationQuantum and semiclassical theories of chemical reaction rates.A fascinating and informative status report on the cutting-edge chemical research made possible by the femtosecond laser, Chemical Reactions and Their Control on the Femtosecond Time Scale is an indispensable volume for professionals and students alike.The femtosecond laser and chemistry's extraordinary new frontier of molecular motions observed on the scale of a quadrillionth of a second.Research chemists have only tapped the surface of the spectacular reach and precision of the femtosecond laser, a technology that has allowed them to observe the dynamics of molecules on the intrinsic time scale of their vibrations, dissociative motions, and electronic excitations. Volume 101 in the Advances in Chemical Physics series, Chemical Reactions and Their Control on the Femtosecond Time Scale details their extraordinary findings, presented at the XXth Solvay Conference on Chemistry, in Brussels.The studies reflect the work, in part, of the Conference's 65 participants, including many prominent contributors. Together they shed light on the laser's enhanced technical range in the area of coherent control of chemical reactions as well as of more general quantum systems. The theoretical fundamentals of femtochemistry, the unique behavior of the femtosecond laser, and a view toward future technological applications were also discussed.An exceptionally up-to-date examination of the chemical analyses made possible by the femtosecond laser, Chemical Reactions and Their Control on the Femtosecond Time Scale is an important reference for professionals and students interested in enhancing their research capabilities with this remarkable tool.From 1993 to 1996, she worked with Dr. P. Gaspard at the Université Libre de Bruxelles, Belgium, on the application of new semiclassical techniques to elementary chemical reaction processes.

    Produktinformation

    • Utgivningsdatum:1997-08-15
    • Mått:159 x 238 x 55 mm
    • Vikt:1 402 g
    • Format:Inbunden
    • Språk:Engelska
    • Serie:Advances in Chemical Physics
    • Antal sidor:984
    • Förlag:John Wiley & Sons Inc
    • ISBN:9780471180487

    Utforska kategorier

    • Fysikalisk kemi inom Naturvetenskap och teknik

    Mer om författaren

    PIERRE GASPARD is a permanent scientific researcher at the National Fund for Scientific Research (FNRS Belgium) at the Center for Nonlinear Phenomena and Complex Systems of the Universite Libre de Bruxelles. A specialist in classical and quantum dynamical systems theory, he has made several contributions to the semiclassical theory of intramolecular and reaction dynamics as well as to the control of chemical reactions, in collaboration with Prof. S. A. Rice. IRENE BURGHARDT received her PhD. in Nuclear Magnetic Resonance spectroscopy in 1992 from the Universite de Lausanne, Switzerland, under the supervision of Prof. G. Bodenhausen.

    Innehållsförteckning

    • Partial table of contents: FEMTOCHEMISTRY: FROM ISOLATED MOLECULES TO CLUSTERS. Femtochemistry: Chemical Reaction Dynamics and Their Control (A.Zewail). FEMTOCHEMISTRY: FROM CLUSTERS TO SOLUTIONS. Size-Dependent Ultrafast Relaxation Phenomena in Metal Clusters.(R. Berry, et al.). LASER CONTROL OF CHEMICAL REACTIONS. Coherent Control of Biomolecular Scattering (P. Brumer & M.Shapiro). INTRAMOLECULAR DYNAMICS. Solvent Dynamics and RRKM Theory of Clusters (R. Marcus). MOLECULAR RYDBERG STATES AND ZEKE SPECTROSCOPY. ZEKE Spectroscopy (E. Schlag). REACTION RATE THEORIES. Quantum and Semiclassical Theories of Chemical Reaction Rates (W.Miller). Concluding Remarks (S. Rice & V. Letokhov). Indexes.