Allen J. Bard is Norman Hackerman-Welch Regents Chair in Chemistry at the University of Texas at Austin, where he has been a faculty member since 1958. Professor Bard is the recipient of more than twenty academic awards, most recently the Luigi Galvani Medal of the Societa Chimica Italiana, 1992; the G. M. Kosolapoff Award of the American Chemical Society, 1992; and the Award for Outstanding Achievement in the Fields of Analytical Chemistry of the Eastern Analytical Symposium, 1990. A frequent lecturer at major universities throughout the United States and Canada, and a member of numerous professional and academic organizations, Professor Bard is Editor in Chief of the Journal of the American Chemical Society and served as president of the International Union of Pure and Applied Chemistry from 1991 to 1993. He received his PhD in electroanalytical chemistry from Harvard University in 1958.

• 1 Introduction and Overview Electrode Processes 12 Potentials and Thermodynamics of Cells 73 Kinetics of Electrode Reactions 154 Mass Transfer by Migration and Diffusion 215 Basic Potential Step methods 256 Potential Sweep Methods 477 Polarography and Pulse Voltammetry 558 Controlled-Curreny Techniques 619 Methods Involving Forced Convection-Hydrodynamic Methods 6510 Techniques Based on Concepts of Impedance 7111 Bulk Electrolysis Methods 8312 Electrode Reactions With Coupled Homogeneous Chemical Reactions 9513 Double-Layer Structure and Adsorption 10314 Electroactive Layers and Modified Electrodes 11115 Electrochemical Instrumentation 11516 Scanning Probe Techniques 12117 Spectroelectrochemistry and other Coupled Characterization Methods 12318 Photoelectrochemistry and Electrogenerated Chemiluminescence 131AppendicesA Mathematical Methods 135B Digital Simulations of Electrochemical Problems 143

Allen J. Bard is Norman Hackerman-Welch Regents Chair in Chemistry at the University of Texas at Austin, where he has been a faculty member since 1958. Professor Bard is the recipient of more than twenty academic awards, most recently the Luigi Galvani Medal of the Societa Chimica Italiana, 1992; the G. M. Kosolapoff Award of the American Chemical Society, 1992; and the Award for Outstanding Achievement in the Fields of Analytical Chemistry of the Eastern Analytical Symposium, 1990. A frequent lecturer at major universities throughout the United States and Canada, and a member of numerous professional and academic organizations, Professor Bard is Editor in Chief of the Journal of the American Chemical Society and served as president of the International Union of Pure and Applied Chemistry from 1991 to 1993. He received his PhD in electroanalytical chemistry from Harvard University in 1958.

• 1 Introduction and Overview Electrode Processes 12 Potentials and Thermodynamics of Cells 73 Kinetics of Electrode Reactions 154 Mass Transfer by Migration and Diffusion 215 Basic Potential Step methods 256 Potential Sweep Methods 477 Polarography and Pulse Voltammetry 558 Controlled-Curreny Techniques 619 Methods Involving Forced Convection-Hydrodynamic Methods 6510 Techniques Based on Concepts of Impedance 7111 Bulk Electrolysis Methods 8312 Electrode Reactions With Coupled Homogeneous Chemical Reactions 9513 Double-Layer Structure and Adsorption 10314 Electroactive Layers and Modified Electrodes 11115 Electrochemical Instrumentation 11516 Scanning Probe Techniques 12117 Spectroelectrochemistry and other Coupled Characterization Methods 12318 Photoelectrochemistry and Electrogenerated Chemiluminescence 131AppendicesA Mathematical Methods 135B Digital Simulations of Electrochemical Problems 143

Allen J. Bard is Norman Hackerman-Welch Regents Chair in Chemistry at the University of Texas at Austin, where he has been a faculty member since 1958. Professor Bard is the recipient of more than twenty academic awards, most recently the Luigi Galvani Medal of the Societa Chimica Italiana, 1992; the G. M. Kosolapoff Award of the American Chemical Society, 1992; and the Award for Outstanding Achievement in the Fields of Analytical Chemistry of the Eastern Analytical Symposium, 1990. A frequent lecturer at major universities throughout the United States and Canada, and a member of numerous professional and academic organizations, Professor Bard is Editor in Chief of the Journal of the American Chemical Society and served as president of the International Union of Pure and Applied Chemistry from 1991 to 1993. He received his PhD in electroanalytical chemistry from Harvard University in 1958.

• 1 Introduction and Overview Electrode Processes 12 Potentials and Thermodynamics of Cells 73 Kinetics of Electrode Reactions 154 Mass Transfer by Migration and Diffusion 215 Basic Potential Step methods 256 Potential Sweep Methods 477 Polarography and Pulse Voltammetry 558 Controlled-Curreny Techniques 619 Methods Involving Forced Convection-Hydrodynamic Methods 6510 Techniques Based on Concepts of Impedance 7111 Bulk Electrolysis Methods 8312 Electrode Reactions With Coupled Homogeneous Chemical Reactions 9513 Double-Layer Structure and Adsorption 10314 Electroactive Layers and Modified Electrodes 11115 Electrochemical Instrumentation 11516 Scanning Probe Techniques 12117 Spectroelectrochemistry and other Coupled Characterization Methods 12318 Photoelectrochemistry and Electrogenerated Chemiluminescence 131AppendicesA Mathematical Methods 135B Digital Simulations of Electrochemical Problems 143