Superacid Chemistry

Inbunden, Engelska, 2009

2 409 kr

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Beskrivning

The chemistry of superacids deals with acid systems stronger than conventional strong mineral Bronsted acids such as sulfuric acid and Lewis acids such as aluminum trichloride.The first edition of Superacid Chemistry, published in 1985, quickly became the definitive work in the field. Since that time, however, the field has grown exponentially, with the development of new superacid systems and innovative superacid applications. This Second Edition of Superacid Chemistry has been published to bring this acclaimed book fully up to date with all these new developments.Superacid Chemistry features a team of pioneering authors in the field headed by George Olah, the 1994 Nobel Laureate in Chemistry. The book covers: General aspects of superacid chemistry, including types of superacids and experimental techniques for acidity measurementsSuperacids systems, including primary, ternary, and solid superacidsCarbocations in superacids, including methods of generating carbocations in superacids and methods and techniques in the study of carbocationsHeterocations in superacids, including onium ions, enium ions, homo-, and heteropolyatomic cations, and cations of group 6-12 elementsSuperacids catalyzed reactions, including conversion of saturated hydrocarbons and alkylation of aromatic hydrocarbonsExtensive references are provided throughout the book to guide readers to the primary literature for further in-depth investigations. In short, this Second Edition meets the growing need for current information on superacid chemistry among researchers in inorganic, organic, and physical chemistry in order to support and advance their research.

Produktinformation

Utgivningsdatum:2009-03-10
Mått:163 x 236 x 46 mm
Vikt:1 247 g
Format:Inbunden
Språk:Engelska
Antal sidor:880
Upplaga:2
Förlag:John Wiley & Sons Inc
ISBN:9780471596684

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Mer om författaren

Ronald M. Heck, PHD, is President of RMH Consulting, where he specializes in consultation on environmental catalysis for auto, diesel, and stationary sources; general catalysis; fuel cells; reaction engineering: combustion technology; and chemical engineering. Previously, Dr. Heck was a Research Manager responsible for developing new catalyst technology for Engelhard Corporation's worldwide customers in environmental catalysis. Robert J. Farrauto, PHD, is a research Fellow at BASF Catalysts and Adjunct Professor in the Earth and Environmental engineering Department of Columbia University in the City of New York where he teaches courses in catalysis and supervises graduate student research, His responsibilities at BASF catalysts include the development of advanced catalysts for hydrogen economy. He has worked extensively i9n the development of catalysts for the environmental, petroleum, and chemical industries. Suresh T. Gulati, PHD, is a Consultant to the Science and Technology Division of Corning. He has also been a research fellow with Corning, specializing in the behavior of brittle materials. Dr. Galati has many years of experience working with automotive substrates, with an emphasis on their design and durability for diesel and passenger car applications.

Recensioner i media

"Superacid Chemistry is a tightly worded description of the present state of the field, and as an inclusive reference book for this area of chemistry, I believe most active researchers will want access to it." (JACS , August 2009)

Innehållsförteckning

Preface to the Second Edition xviiPreface to the First Edition xix1.General Aspects 11.1. Defining Acidity 11.2. Definition of Superacids 61.3. Types of Superacids 91.4. Experimental Techniques for Acidity Measurements (Protic Acids) 112. Superacid Systems 352.1. Primary Superacids 352.2. Binary Superacids 472.3. Ternary Superacids 622.4. Solid Superacids 633. Carbocations in Superacid Systems 833.1. Introduction 833.2. Methods of Generating Carbocations in Superacids Systems 873.3. Methods and Techniques in the Study of Carbocations 883.4. Trivalent Carbocations 933.5. Equilibrating (Degenerate) and Higher (Five or Six) Coordinate (Nonclassical) Carbocations 2064.Heterocations in Superacid Systems 3114.1. Introduction 3114.2. Onium Ions 3114.3. Enium Ions 3974.4. Homo-and Heteropolyatomic Cations 4264.5. Cations of Group 6–12 Elements 4535. Superacid-Catalyzed Reactions 5015.1. Conversion of Saturated Hydrocarbons 5015.2. Alkylation of Aromatic Hydrocarbons 5545.3. Acylation of Aromatics 6085.4. Carboxylation 6185.5. Formylation 6275.6. Thio- and Dithiocarboxylation 6325.7. Sulfonation and Sulfonylation 6335.8. Nitration 6365.9. Nitrosonium Ion (NOþ)-Induced Reactions 6435.10. Halogenation 6475.11. Amination 6595.12. Oxyfunctionalization 6605.13. Superacids in Protection Group Chemistry 6765.14. Superacids in Heterocyclic Chemistry 6805.15. Dehydration 6985.16. Superacidsin Carbohydrate Chemistry 7005.17. Rearrangements and Cyclizations 7065.18. Ionic Hydrogenation 7275.19. Esterification and Ester Cleavage 7345.20. Additions 7355.21. Ritter Reactions 7425.22. Polymerization 7445.23. Miscellaneous Reactions 750References 756Outlook 789Index 791