Mechanochemistry: From Functional Solids to Single Molecules

Faraday Discussion 170

Inbunden, Engelska, 2014

2 443 kr

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Beskrivning

Mechanochemical reactions utilise mechanical force to achieve chemical transformation. Because they can be both solvent-free and less energy consuming than standard solution reactions, mechanochemical transformations are rapidly becoming popular as a sustainable alternative to conventional solution-based and solvothermal chemical processes which are inherently wasteful of solvent and energy in both the laboratory and industry.The growing interest in mechanochemical processes has in the past decade provided exciting developments in the areas of supramolecular, pharmaceutical, materials and organic chemistry and catalysis. These developments indicate that mechanochemistry will play a key role in future clean and sustainable technologies, ranging from "green" synthesis to mineral manufacturing and nanoparticle synthesis.However, such development requires improving the understanding of the underlying principles of mechanochemistry and extensive communication between researchers in its different areas. The 170th Faraday Discussion will facilitate further development of mechanochemistry in terms of applications, definitions and mechanistic understanding, and explore how its innovative, clean and energy-efficient applications could form the basis of new paradigm for academic and industrial chemistry.In this volume the topics covered include:the mechanochemistry of organic molecules and soft organic moleculesthe mechanochemistry of inorganic compounds and coordination-based materialssonication and macromolecular mechanochemistrythe mechanistic understanding, catalysis and scaling up of mechanochemistry

Produktinformation

Utgivningsdatum:2014-11-25
Mått:156 x 234 x 22 mm
Vikt:786 g
Format:Inbunden
Språk:Engelska
Serie:Faraday Discussions
Antal sidor:432
Förlag:Royal Society of Chemistry
ISBN:9781782621706

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Faraday Discussions documents a long-established series of Faraday Discussion meetings which provide a unique international forum for the exchange of views and newly acquired results in developing areas of physical chemistry, biophysical chemistry and chemical physics. The papers presented are published in the Faraday Discussion volume together with a record of the discussion contributions made at the meeting. Faraday Discussions therefore provide an important record of current international knowledge and views in the field concerned. The latest (2012) impact factor of Faraday Discussions is 3.82.

Innehållsförteckning

Introductory Lecture: Mechanochemistry, a versatile synthesis strategy for new materialsLiquid-assisted vortex grinding supports the single-step solid-state construction of a [2.2]paracyclophaneIs the equilibrium composition of mechanochemical reactions predictable using computational chemistry?The two-step mechanochemical synthesis of porphyrinsMechanochemistry of organic molecules, soft materials and pharmaceuticals: General discussionMechanochemical synthesis of an organometallic compound: a high volume manufacturing methodMechanochemical preparation of copper iodide clusters of interest for luminescent devicesMechanochemical synthesis and characterisation of cocrystals and metal organic compoundsThe mechanically induced structural disorder in barium hexaferrite, BaFe12O19, and its impact on magnetismDry mechanochemical synthesis of alane from LiH and AlCl3Mechanochemical synthesis of Au, Pd, Ru and Re nanoparticles with lignin as a biobased reducing agent and stabilizing matrixThe dual role of sulfur-containing amino acids in the synthesis of IV–VI semiconductor nanocrystals: a mechanochemical approachMechanochemistry of inorganic compounds and coordination-based materials: General discussionQuantitative in situ and real-time monitoring of mechanochemical reactionsThe scalability in the mechanochemical syntheses of edge functionalized graphene materials and biomass-derived chemicalsApplication of twin screw extrusion to the manufacture of cocrystals: scale-up of AMG 517–sorbic acid cocrystal productionSelf-sustaining reactions as a tool to study mechanochemical activationScale-up of organic reactions in ball mills: process intensification with regard to energy efficiency and economy of scaleMechanistic understanding, catalysis and scaling up of mechanochemistry: General discussionAdvances in elucidating mechanochemical complexities via implementation of a simple organic systemEnhancing covalent mechanochemistry in bulk polymers using electrospun ABA triblock copolymersIncreasing the energy yield of mechanochemical transformations: selected case studiesMechanically induced silyl ester cleavage under acidic conditions investigated by AFM-based single-molecule force spectroscopy in the force-ramp modeTriboelectricity in insulating polymers: evidence for a mechanochemical mechanismThe mechanochemical production of phenyl cations through heterolytic bond scissionSonication and macromolecular mechanochemistry: General discussionMechanochemistry and sonochemistry: concluding remarks