Electron Transfer

Shunichi Fukuzumi, PhD, is a Distinguished Professor of Ewha Womans University, South Korea, Designated Professor of Meijo University, Japan, and Professor Emeritus of Osaka University, Japan and authored over 1000 scientific publications. He is the director of the SORST (Solution Oriented Research for Science and Technology) project, and is also the leader of a Global COE (Centers of Excellence) program.

• Acknowledgments vii1 Introduction 12 Marcus Theory of Electron Transfer 53 Photosynthetic Reaction Center Models 74 Electron Donor–Acceptor Dyads 115 Supramolecular Electron Transfer 255.1 Cation–Anion Binding 255.2 π-Complexes 355.3 Electron-Transfer Switching 465.4 Dendrimers 535.5 Supramolecular Solar Cells 556 Effects of Metal Ions on Photoinduced Electron Transfer 657 Photoredox Catalysis 697.1 Photocatalytic Oxygenation 697.2 Photocatalytic Oxibromination 777.3 Carbon—Carbon Bond Formation 777.4 DNA Cleavage 817.5 Anti-Markovnikov Hydroetherification 817.6 Photocatalytic Cycloaddition 837.7 Photocatalytic Hydrotrifluoromethylation 857.8 Photocatalytic Hydrogen Evolution 868 Hydrogen Storage 938.1 Interconversion Between Hydrogen and Formic Acid 958.2 Interconversion Between Hydrogen and NADH 1018.3 Hydrogen Evolution from Alcohols 1048.4 Hydrogen Evolution from Paraformaldehyde 1079 Metal Ion-Coupled Electron Transfer (MCET) 1099.1 MCET of O2 1099.2 Binding Modes of Metal Ions 1149.3 Self-Organized MCET 1249.4 Accelerating and Decelerating Effects of Metal Ions 1329.5 Driving Force Dependence of MCET Rate Constants 1379.6 MCET Coupled with Hydrogen Bonding 1439.7 MCET Catalysis 1489.7.1 Hydride Transfer vs. Cycloaddition 1489.7.2 Suproxode Disumutase (SOD) Models 1529.8 MCET of Metal-Oxo Complexes 1579.9 PCET of Metal-Oxo Complexes 1629.10 Unified Mechanism of MCET and PCET of Metal-Oxo Complexes 1659.11 MCET of Metal-Peroxo Complexes 16910 Catalytic Reduction of O2 17311 Catalytic Oxidation of H2O 18112 Production of Hydrogen Peroxide from Water and Oxygen as a Solar Fuel 18713 Production and Usage of Hydrogen Peroxide as a Solar Fuel in Seawater 19314 Photosystem II Mimic 19715 Conclusion and Perspective 201References 203Index 225