Stefan M. Sarge studied chemistry at the Braunschweig University of Technology. Since 1990 he has worked for the Physikalisch-Technische Bundesanstalt (PTB) in Braunschweig, which is the National Metrology Institute of Germany providing scientific and technical services at the highest level of accuracy and reliability for the benefit of society as a whole, trade and industry, and science.He is the Head of the Working Group on Caloric Quantities and the author of several publications in the fields of thermal analysis, calorimetry and legal metrology. In 1990 and 2004 he received the Netzsch-GEFTA award. Günther W. H. Höhne studied chemistry, physics and mathematics at the Technical University of Berlin. In 1997 he was appointed Privatdozent (Adj. Professor) after his habilitation in experimental physics. From 1970 until his retirement in 1999 he was Head of the Section for Calorimetry of the University of Ulm, with duties including academic teaching in physics. From 1999 to 2008 he was a visiting professor at the Eindhoven University of Technology. He has published numerous articles and two monographs on calorimetry and its applications. In 2002 he received the science award of the German Society of Thermal Analysis (GEFTA). Wolfgang Hemminger studied physics at the University of Stuttgart and worked for a couple of years at the Braunschweig University in the field of materials science using calorimetry as one tool of research. In 1981 he joined the PTB and worked in the fields of thermal conductivity and various thermoanalytical methods. In 1989 he was appointed Head of the PTB Division "Thermodynamics and Explosion Protection". He was co-editor of the journal Thermochimica Acta and is the author of numerous journal articles and books. In 1981 he received the Netzsch-GEFTA award and in 2006 the GEFTA science award.

• INTRODUCTION: Calorimetry: Definition, Application Fields and Units Definition of CalorimetryApplication Fields for CalorimetryFirst Example from Life SciencesSecond Example from Material ScienceThird Example from Legal MetrologyUnits PART I: Fundamentals of Calorimetry METHODS OF CALORIMETRYCompensation of the Thermal EffectMeasurement of Temperature DifferencesSummary of Measuring Principles MEASURING INSTRUMENTSMeasurement of Amount of SubstanceMeasurement of Electric QuantitiesMeasurement of TemperaturesChemical Composition FUNDAMENTALS OF THERMODYNAMICSStates and ProcessesPhases and Phase Transitions HEAT TRANSPORT PHENOMENAHeat ConductionConvectionHeat RadiationHeat TransferEntropy Increase during Heat ExchangeConclusions Concerning Calorimetry SURROUNDINGS AND OPERATION CONDITIONSThe Isothermal ConditionThe Isoperibol ConditionThe Adiabatic ConditionThe Scanning Condition MEASUREMENT AND EVALUATIONConsequences of Temperature Relaxation within the SampleTypical Results from Different CalorimetersReconstruction of the True Sample Heat Flow Rate from the Measured FunctionSpecial EvaluationsDetermination of the Measurement Uncertainty PART II: Practice of Calorimetry CALORIMETERSFunctional Components and AccessoriesHeating MethodsCooling MethodsComments on Control SystemsThermostatsOn the Classification of CalorimetersOn the Characterization of CalorimetersIsothermal CalorimetersCalorimeters with Heat Exchange between Sample and SurroundingsAdiabatic CalorimetersOther Calorimeters RECENT DEVELOPMENTSMicrochip CalorimetryMicrochip CalorimetryExtreme Ranges of StateCalorimetry as an Analytical and Diagnostic Tool CALORIMETRIC MEASUREMENTS: GUIDELINES AND APPLICATIONSGeneral ConsiderationsGuidelines to Calorimetric MeasurementsCalorimetric Applications Index

Stefan M. Sarge studied chemistry at the Braunschweig University of Technology. Since 1990 he has worked for the Physikalisch-Technische Bundesanstalt (PTB) in Braunschweig, which is the National Metrology Institute of Germany providing scientific and technical services at the highest level of accuracy and reliability for the benefit of society as a whole, trade and industry, and science.He is the Head of the Working Group on Caloric Quantities and the author of several publications in the fields of thermal analysis, calorimetry and legal metrology. In 1990 and 2004 he received the Netzsch-GEFTA award. Günther W. H. Höhne studied chemistry, physics and mathematics at the Technical University of Berlin. In 1997 he was appointed Privatdozent (Adj. Professor) after his habilitation in experimental physics. From 1970 until his retirement in 1999 he was Head of the Section for Calorimetry of the University of Ulm, with duties including academic teaching in physics. From 1999 to 2008 he was a visiting professor at the Eindhoven University of Technology. He has published numerous articles and two monographs on calorimetry and its applications. In 2002 he received the science award of the German Society of Thermal Analysis (GEFTA). Wolfgang Hemminger studied physics at the University of Stuttgart and worked for a couple of years at the Braunschweig University in the field of materials science using calorimetry as one tool of research. In 1981 he joined the PTB and worked in the fields of thermal conductivity and various thermoanalytical methods. In 1989 he was appointed Head of the PTB Division "Thermodynamics and Explosion Protection". He was co-editor of the journal Thermochimica Acta and is the author of numerous journal articles and books. In 1981 he received the Netzsch-GEFTA award and in 2006 the GEFTA science award.

• INTRODUCTION: Calorimetry: Definition, Application Fields and Units Definition of CalorimetryApplication Fields for CalorimetryFirst Example from Life SciencesSecond Example from Material ScienceThird Example from Legal MetrologyUnits PART I: Fundamentals of Calorimetry METHODS OF CALORIMETRYCompensation of the Thermal EffectMeasurement of Temperature DifferencesSummary of Measuring Principles MEASURING INSTRUMENTSMeasurement of Amount of SubstanceMeasurement of Electric QuantitiesMeasurement of TemperaturesChemical Composition FUNDAMENTALS OF THERMODYNAMICSStates and ProcessesPhases and Phase Transitions HEAT TRANSPORT PHENOMENAHeat ConductionConvectionHeat RadiationHeat TransferEntropy Increase during Heat ExchangeConclusions Concerning Calorimetry SURROUNDINGS AND OPERATION CONDITIONSThe Isothermal ConditionThe Isoperibol ConditionThe Adiabatic ConditionThe Scanning Condition MEASUREMENT AND EVALUATIONConsequences of Temperature Relaxation within the SampleTypical Results from Different CalorimetersReconstruction of the True Sample Heat Flow Rate from the Measured FunctionSpecial EvaluationsDetermination of the Measurement Uncertainty PART II: Practice of Calorimetry CALORIMETERSFunctional Components and AccessoriesHeating MethodsCooling MethodsComments on Control SystemsThermostatsOn the Classification of CalorimetersOn the Characterization of CalorimetersIsothermal CalorimetersCalorimeters with Heat Exchange between Sample and SurroundingsAdiabatic CalorimetersOther Calorimeters RECENT DEVELOPMENTSMicrochip CalorimetryMicrochip CalorimetryExtreme Ranges of StateCalorimetry as an Analytical and Diagnostic Tool CALORIMETRIC MEASUREMENTS: GUIDELINES AND APPLICATIONSGeneral ConsiderationsGuidelines to Calorimetric MeasurementsCalorimetric Applications Index

Stefan M. Sarge studied chemistry at the Braunschweig University of Technology. Since 1990 he has worked for the Physikalisch-Technische Bundesanstalt (PTB) in Braunschweig, which is the National Metrology Institute of Germany providing scientific and technical services at the highest level of accuracy and reliability for the benefit of society as a whole, trade and industry, and science.He is the Head of the Working Group on Caloric Quantities and the author of several publications in the fields of thermal analysis, calorimetry and legal metrology. In 1990 and 2004 he received the Netzsch-GEFTA award. Günther W. H. Höhne studied chemistry, physics and mathematics at the Technical University of Berlin. In 1997 he was appointed Privatdozent (Adj. Professor) after his habilitation in experimental physics. From 1970 until his retirement in 1999 he was Head of the Section for Calorimetry of the University of Ulm, with duties including academic teaching in physics. From 1999 to 2008 he was a visiting professor at the Eindhoven University of Technology. He has published numerous articles and two monographs on calorimetry and its applications. In 2002 he received the science award of the German Society of Thermal Analysis (GEFTA). Wolfgang Hemminger studied physics at the University of Stuttgart and worked for a couple of years at the Braunschweig University in the field of materials science using calorimetry as one tool of research. In 1981 he joined the PTB and worked in the fields of thermal conductivity and various thermoanalytical methods. In 1989 he was appointed Head of the PTB Division "Thermodynamics and Explosion Protection". He was co-editor of the journal Thermochimica Acta and is the author of numerous journal articles and books. In 1981 he received the Netzsch-GEFTA award and in 2006 the GEFTA science award.

• INTRODUCTION: Calorimetry: Definition, Application Fields and Units Definition of CalorimetryApplication Fields for CalorimetryFirst Example from Life SciencesSecond Example from Material ScienceThird Example from Legal MetrologyUnits PART I: Fundamentals of Calorimetry METHODS OF CALORIMETRYCompensation of the Thermal EffectMeasurement of Temperature DifferencesSummary of Measuring Principles MEASURING INSTRUMENTSMeasurement of Amount of SubstanceMeasurement of Electric QuantitiesMeasurement of TemperaturesChemical Composition FUNDAMENTALS OF THERMODYNAMICSStates and ProcessesPhases and Phase Transitions HEAT TRANSPORT PHENOMENAHeat ConductionConvectionHeat RadiationHeat TransferEntropy Increase during Heat ExchangeConclusions Concerning Calorimetry SURROUNDINGS AND OPERATION CONDITIONSThe Isothermal ConditionThe Isoperibol ConditionThe Adiabatic ConditionThe Scanning Condition MEASUREMENT AND EVALUATIONConsequences of Temperature Relaxation within the SampleTypical Results from Different CalorimetersReconstruction of the True Sample Heat Flow Rate from the Measured FunctionSpecial EvaluationsDetermination of the Measurement Uncertainty PART II: Practice of Calorimetry CALORIMETERSFunctional Components and AccessoriesHeating MethodsCooling MethodsComments on Control SystemsThermostatsOn the Classification of CalorimetersOn the Characterization of CalorimetersIsothermal CalorimetersCalorimeters with Heat Exchange between Sample and SurroundingsAdiabatic CalorimetersOther Calorimeters RECENT DEVELOPMENTSMicrochip CalorimetryMicrochip CalorimetryExtreme Ranges of StateCalorimetry as an Analytical and Diagnostic Tool CALORIMETRIC MEASUREMENTS: GUIDELINES AND APPLICATIONSGeneral ConsiderationsGuidelines to Calorimetric MeasurementsCalorimetric Applications Index