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    Diarylethene Molecular Photoswitches

    Concepts and Functionalities

    AvMasahiro Irie

    Inbunden, Engelska, 2021

    1 731 kr

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    Beskrivning

    A comprehensive review to the synthesis, properties, and applications of diarylethene-based molecular photoswitches Diarylethene Molecular Photoswitches: Concept and Functionalities provides the fundamental concepts of molecular photoswitches and includes information on how the bistable photoswitches of diarylethenes modulate the functions of materials and biological activities. Written by Masahiro Irie (the inventor of photochromic diarylethene compound), the book explores the reaction mechanism, photoswitching performance, photoswitchable crystals, and the myriad applications of diarylethenes based photoswitches. This book offers academics, chemists, and engineers an essential resource for understanding the molecular photoswitches and provides a guide to the development of new photoresponsive materials. The author explores the applications based on diarylethene and its dirivatives to Field-Effect Transistors, Metal-Organic Frameworks including nanoparticles, super-resolution fluorescence microscopies, drug release, and self-healing materials. This important book: * Offers a guide to diarylethene derivatives, the most widely studied compounds worldwide among the photochromic compounds* Includes the basic concepts of molecular photoswitches* Explores the myraid applications grounded in diarylethene and its derivatives * Presents an authortative text from the inventor of the photochromic diarylethene compound Written for materials scientists, organic, polymer, and physical chemists, and electronics engineers, Diarylethene Molecular Photoswitches offers an introduction to the topic and includes recent developments in the field.

    Produktinformation

    • Utgivningsdatum:2021-05-05
    • Mått:175 x 249 x 18 mm
    • Vikt:612 g
    • Format:Inbunden
    • Språk:Engelska
    • Antal sidor:240
    • Förlag:Wiley-VCH Verlag GmbH
    • ISBN:9783527346400

    Utforska kategorier

    • Elektronik och kommunikationer inom Naturvetenskap och teknik
    • Övrig teknik och tillämpad vetenskap inom Naturvetenskap och teknik

    Mer om författaren

    Masahiro Irie is an emeritus professor of Kyushu University. He received his B.S. and M.S. from Kyoto University and his Ph.D. in radiation chemistry from Osaka University. In 1968 he joined the Faculty of Engineering, Hokkaido University, as a research associate and started his research in photochemistry. He was the faculty members of at Osaka University, Kyushu University and Rikkyo University. He has been conducting research on molecular photoswitch systems for more than 40 years. In the middle of the 1980s he discovered thermally irreversible and fatigue resistant photochromic diarylethenes. Prof. Irie has authored over 500 scientific publications and has received numerous scientific awards, including Porter Medal (European Photochemistry Association, The Inter-American Photochemistry Society and Asian and oseanian Photochemsitry association), Theodor-Foerster-Preis (GDCh and Deutsche Bunsen-Gesellschaft, Germany) and The Chemical Society of Japan Award.

    Innehållsförteckning

    • Preface ix1 Introduction 11.1 General Introduction 11.2 Discovery of Diarylethene Molecular Photoswitches 4References 122 Reaction Mechanism 152.1 Basic Concepts 152.2 Theoretical Study 202.3 Reaction Dynamics 222.3.1 Cyclization Reaction 222.3.2 Cycloreversion Reaction 27References 293 Photoswitching Performance 313.1 Quantum Yield 313.1.1 Photocyclization Quantum Yield 313.1.2 Solvent Effect on Cyclization Quantum Yield 423.1.3 Photocycloreversion Quantum Yield 443.2 Thermal Stability 493.3 Fatigue Resistance 533.4 Fluorescence Property 603.4.1 Turn-Off Mode Photoswitching 613.4.2 Turn-On Mode Photoswitching 763.5 Chiral Property 80References 864 Photoswitchable Crystals 934.1 Dichroism 934.2 X-Ray Crystallographic Analysis 974.3 Quantum Yield 1014.4 Multicolored Systems and Nano-Layered Periodic Structures 1064.5 Fluorescent Crystals 1084.6 Photomechanical Response 1104.6.1 Surface Morphology Change 1124.6.2 Reversible Shape Change 1134.6.3 Bending Response of Mixed Crystals 116References 1215 Memory 1255.1 Single-Molecule Memory 1255.2 Near-Field Optical Memory 1285.3 Three-Dimensional Optical Memory 1305.4 Readout Using Infrared Absorption, Raman Scattering, and Refractive Index Changes 132References 1346 Switches 1376.1 Single-Molecule Conductance Photoswitch 1376.2 Optical Switch Based on Refractive Index Change 1416.3 Magnetism 141References 1467 Surface Properties 1497.1 SurfaceWettability 1497.2 Selective Metal Deposition 1517.3 Subwavelength Nanopatterning 154References 1558 Polymers and Liquid Crystals 1578.1 Polymers 1578.2 Liquid Crystals 175References 1789 Applications 1839.1 Organic Field-Effect Transistors (OFETs) 1839.2 Metal Organic Frameworks (MOFs) 1859.3 Super-Resolution Fluorescence Microscopy 1889.3.1 Control of Cycloreversion Quantum Yield 1899.3.2 Fatigue Resistance 1919.3.3 Photoswitching with Single-Wavelength Visible Light 1929.3.4 Super-Resolution Bioimaging 1959.4 Chemical Reactivity Control 1979.5 Biological Activity 2019.6 Color Dosimeters 204References 209A Synthesis Procedures of Typical Diarylethenes 213A.1 1,2-Bis(2,4-dimethyl-5-phenyl-3-thienyl)perfluorocyclopentene 213A.2 1,2-Bis(2-ethyl-6-phenyl-1-benzothiophene-1,1-dioxide-3-yl)-perfluorocyclopenetene 215References 217Index 219