Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition – serie
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Verbindungen des Mangans mit Schwefel, Selen und Tellur
Inbunden, Tyska, 1976
11 524 kr
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U Uranium
Supplement Volume C5 Uranium Dioxide, UO2, Physical Properties. Electrochemical Behavior
Inbunden, Engelska, 1985
7 856 kr
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The present volume Uranium C5 covers the physical properties of U0 - the production 2 and preparation of U0 were already treated in Uranium C4, whereas the chemical proper 2 ties will be the subject of the forthcoming part C6. U0 is the most important chemical compound in all aspects of nuclear technology. 2 It is and will be for the foreseeable future the fuel for all light and heavy water reactors as well as (in the mixed crystal with Pu0 ) for the fast breeder reactors. Therefore, the 2 nuclear engineer has to understand the behavior of U0 under all conditions existing during 2 operational (and possibly failure) states of a nuclear reactor, e. g. , not only in the solid state but also to some extent in the liquid and gaseous states. Besides high scientific interest in the sometimes unique or unusual properties, e. g. , at low temperatures, a lot of data and physical properties which are critical for its use as a nuclear fuel have been determined more or less accurately. Creep, swelling, irradiation densification, and fission gas behavior in the fuel are properties which have been evaluated up to the high temperatu res (near the melting point) which may exist in U0 fuel due to its low thermal conductivity. 2 Besides these more technical data there have been accumulated a lot of important physical data, e. g.
TYPIX — Standardized Data and Crystal Chemical Characterization of Inorganic Structure Types
Inbunden, Engelska, 1993
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The crystaLLographer usuaLLy needs, as a compLement to his experimentaL work, a smaLL structure data compiLation. My first, some 25 years ago, was a hand-written List of structure types containing space group, unit ceLL data and positionaL atom coordinates. Some 20 years ago, when computers had become a more easiLy accessibLe tooL, a smaLL computer test fiLe was created with the help of Dr. Jan Portheine, which was LabeLLed TYPIX. Assisted by Dr. KLaus Yvon I inserted in the fiLe the somewhat more than 200 inorganic crystaL structure types which were of interest for our research or with which I was famiLiar from my previous experimentaL crystaL structure studies on intermetalLics and tetrahedraL structure compounds. We soon stopped our work on TYPIX because we reaLized that simpLy storing structure data copied from the Literature did not serve our finaL objective. I had, for exampLe, Listed the structures of certain isotypic compounds as separate distinct structure types because, due to a different setting or description given in the originaL Literature, I missed their isotypism.In other cases, with good Luck, I found the isotypism and succeeded in correctLy transforming one description to the other but then did not know which of the different but equivaLent descriptions I shouLd retain in my data coLLection.
TYPIX Standardized Data and Crystal Chemical Characterization of Inorganic Structure Types
Inbunden, Engelska, 1993
7 919 kr
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TYPIX is a critical compilation of crystallographic data prepared by E. Parthé at the University of Geneva. It contains over 3200 compounds representative of the structure types found among inorganic compounds. This work contains condensed crystal chemical information about individual structure types as well as an extensive chapter on the crystal chemistry of particular structure families. The aim of the compilation is to clarify and classify published data for intermetallic and other inorganic structures (types found exclusively with halides or oxides are only included for a few special cases). It provides a tool for additional crystal chemical studies and the development of new materials.
TYPIX Standardized Data and Crystal Chemical Characterization of Inorganic Structure Types
Inbunden, Engelska, 1994
7 919 kr
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TYPIX is a critical compilation of crystallographic data prepared by E. Parthé at the University of Geneva. It contains over 3200 compounds representative of the structure types found among inorganic compounds. This work contains condensed crystal chemical information about individual structure types as well as an extensive chapter on the crystal chemistry of particular structure families. The aim of the compilation is to clarify and classify published data for intermetallic and other inorganic structures (types found exclusively with halides or oxides are only included for a few special cases). It provides a tool for additional crystal chemical studies and the development of new materials.
Ac-Au
Häftad, Engelska, 2013
798 kr
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The extraordinary quantity of material included in the Gmelin Handbook of Inorganic Chemistry can make it extremely difficult to find a specific compound using only a general un derstanding of the basic rules for the arrangement of the subject matter (the so-called "System ofthe Last Position").
TYPIX — Standardized Data and Crystal Chemical Characterization of Inorganic Structure Types
Häftad, Engelska, 2013
7 856 kr
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The crystaLLographer usuaLLy needs, as a compLement to his experimentaL work, a smaLL structure data compiLation. My first, some 25 years ago, was a hand-written List of structure types containing space group, unit ceLL data and positionaL atom coordinates. Some 20 years ago, when computers had become a more easiLy accessibLe tooL, a smaLL computer test fiLe was created with the help of Dr. Jan Portheine, which was LabeLLed TYPIX. Assisted by Dr. KLaus Yvon I inserted in the fiLe the somewhat more than 200 inorganic crystaL structure types which were of interest for our research or with which I was famiLiar from my previous experimentaL crystaL structure studies on intermetalLics and tetrahedraL structure compounds. We soon stopped our work on TYPIX because we reaLized that simpLy storing structure data copied from the Literature did not serve our finaL objective. I had, for exampLe, Listed the structures of certain isotypic compounds as separate distinct structure types because, due to a different setting or description given in the originaL Literature, I missed their isotypism.In other cases, with good Luck, I found the isotypism and succeeded in correctLy transforming one description to the other but then did not know which of the different but equivaLent descriptions I shouLd retain in my data coLLection.
Index
1st Supplement Volume 1
Häftad, Engelska, 2013
798 kr
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The GmeLin FormuLa Index published between 1975 and 1980 covered aLL voLumes of the Eighth Edition of the GmeLin Handbook that had appeared up to the end of 1974 in the case of Main VoLumes and up to the end of 1973 in the case of SuppLement VoLumes. The GmeLin FormuLa Index, First SuppLement, continues from there and covers the handbook voLumes published up to the end of 1979. This First SuppLement wiLL consist of eight voLumes, which wiLL appear at intervaLs of four to six months. The basic structure of the FormuLa Index has been fully retained in the First Supplement: The index Lists aLL eLements, compounds, ions, and systems having definite composition that are described in the handbook text. The first coLumn gives the empiricaL formuLa, whiLe the second gives the conventionaL formuLa. The third coLumn Lists the pertinent pages. (The detaiLs are avaiLabLe in "Instructions for the FormuLa Index", on the next pages. ) This First SuppLement was prepared and printed with extensive use of computers. In the future this wiLL allow publication of cumuLative indexes.The procedures were worked out together with the TechnicaL Section of the Gesellschaft fUr Information und Dokumentation mbH (GID), Frankfurt, and I take this occasion to thank them for their generous help. I wouLd aLso Like to thank our printers, Universitatsdruckerei H. SWrtz AG, WOrzburg, for their advice and cooperation.
U Uranium
Supplement Volume B2 Alloys of Uranium with Alkali Metals, Alkaline Earths, and Elements of Main Groups III and IV
Häftad, Engelska, 2013
798 kr
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The description of uranium and its compounds, for which the Gmelin Institute has started a series of volumes supplementing the main volume of 1936, follows in its arrangement closely the order chosen for the transuranium volumes.
Np, Pu… Transuranium Elements
INDEX. Alphabetical Index of Subjects and Substances
Häftad, Engelska, 2013
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1 583 kr
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Astatine is - besides radon and francium - the only natural radioelement which only has short-Lived isotopes, thereby excluding experiments with . 38% a-branching of 227 Ac - a member of the 235U series - there is no chance to recover substantial amounts of 219At from natural sources for sCientific research of At.
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The present volume describes organoberyllium compounds containing at least one berylli um-carbon bond, except the beryllium carbides and cyanides. No doubt the main reason for the apparent ban of all experimental organoberyllium chemistry is to be found in the established, and alleged, hazardous properties of beryllium compounds.
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The first supplement consisting of 3 volumes covered all the literature uniformly up to the end of 1977, whereas the two volumes of the 2nd supplement have extended the literature coverage of boron compounds to 1980 and the four volumes of the 3rd supplement to 1984.
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A broad coverage of boron topics is provided. Special attention is devoted to theoretical studies and calculations on small boron-hydrogen and boron-noble gas species including molecules like BH, which are rather favorite subjects of theoreticians for testing various methods of calculation.
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Volume 1 (systems with hydrogen and noble gases) of this particular supplement will be published subsequently, whereas Volume 3a (boron and nitrogen), Volume 3b (boron and nitrogen, boron and fluorine), and Volume 4 (boron compounds containing Cl, Br, I, S, Se, and Te, as well as a section containing carboranes) have already been published.
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The GmeLin FormuLa Index and its First SuppLement covered those voLumes of the Eighth Edition of the GmeLin Handbook which had been issued up to the end of 1979. The present Second SuppLement updates the Index by incLusion of the voLumes which appeared up to the end of 1987. With this Second SuppLement aLL compounds described in the GmeLin Handbook of Inorganic Chemistry in the period between 1924 and 1987 can be Located. The basic structure of the FormuLa Index remains the same as in the previous editions. Computer techniques were empLoyed in the preparation and print of the Second SuppLe- ment. The data acquisition, sorting, and further data handling were performed with the aid of a series of computer programs deveLoped by staff members of the former" Online Group" of the GmeLin Institute, now at ChempLex GmbH, and by the printer" UniversiHits- druckerei H. StOrtz AG, Wurzburg". Whereas the Handbook itself wiLL continue to appear in printed form, the present Second SuppLement of the Index is intended to be the Last one issued in print.The cumuLated contents of the Index and its SuppLements are contained in the GmeLin FormuLa Index (GFI) database which is avaiLabLe to the scientific community via STN. This database wiLL be updated annually to incLude the published Handbook voLumes.
Gmelin Handbuch der Anorganischen Chemie
Index
Häftad, Engelska, 2013
1 583 kr
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Sb Organoantimony Compounds Part 4
Compounds of Pentavalent Antimony with Three Sb-C Bonds
Häftad, Engelska, 2013
798 kr
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This fourth volume on organoantimony compounds describes pentavalent antimony com- pounds of the type R and R . The R denotes an organic group bonded by carbon 3SbX2 3Sb=X to the antimony atom. X represents a group, inorganic or organic, which is bonded to the antimony by an atom other than carbon. The X atoms in R may be part of a 3SbX2 ring system. In the case of bidentate X ligands like 02- , S2-, SO~-, CO~-, and others, the compounds are placed with the mononuclear RssbX compounds. 2 I once again thank Dr. Margot Becke and Dr. Ekkehard Fluck for the stimulus that led to this book. To the editor of the former volumes, Dr. Hubert Bitterert gratitude and memory are due. I especially thank Drs. Ulrich Kruerke and Marlies Mirbach for editing this volume, Mrs. Ursula Hettwer for systematically arranging the compounds, and Mr. Edgar Rudolph for preparing the index. Last but not least I thank my wife Sigrid for putting my handwritten manuscript into legible form.Gramschatz, Altes Forsthaus, June 1986 Markus Wieber x Explanations, Abbreviations, and Units Many eompounds in this voLume are presented in tabLes in whieh abbreviations are used and the units are omitted for the sake of eoneiseness. This neeessitates the foLLowing ctarifieation.
Sb Organoantimony Compounds
Part 5: Compounds of Pentavalent Antimony with Three, Two and One Sb-C Bonds
Häftad, Engelska, 2013
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This fifth volume on organoantimony compounds continues the description of pentavalent antimony compounds and concludes the entire series. The treatment of pentavalent compounds with three Sb-C bonds began in Part 4 with the RSbX type and is now completed with types RSb(X)Y, RR'SbX , RR'Sb(X)Y, 3 2 3 2 2 2 RR'R"SbX (Section 2.5.1) and the corresponding bi- and trinuclear compounds (Sec- 2 tions 2.5.2, p.87, and 2.5.3, p. 132). R, R', and R" denote different organic groups bonded through carbon to the antimony atom. X and Y represent inorganic or organic groups that are bonded to antimony by an atom other than carbon. R, X, and/or Y can also be chelating ligands. The remaining part of the volume completeLy covers all pentavalent antimony compounds containing two Sb-C bonds (RSbX , RSb(X )Y, RR'SbX , RR'Sb(X )Y, bi- and tetranucLear 2 3 2 2 3 2 compounds, Chapter 2.6, p. 134) and those containing one Sb-C bond (RSbX , RSb(X )Y, 4 3 RSb(X)Y , bi- and trinucLear compounds, Chapter 2.7, p. 237). These compounds form ad- 2 2 ducts with Lewis bases (symbol D) and form many ionic compLexes by the addition of saLts such as amine hydrochLorides (symbol MZ).The adducts and ionic compLexes are described immediately after the parent substances. The volume concludes with an Empirical Formula Index (p. 318) and a Ligand Formula Index (p. 357).
Th Thorium
Compounds with Carbon: Carbonates, Thiocyanates, Alkoxides, Carboxylates
Häftad, Engelska, 2013
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The present volume of the Gmelin thorium series describes the solid thorium-carbon compounds with the exception of the carbides and coordination compounds of the type 4 ThAn· X B, where B is a neutral ligand.
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The present volume in the organogermanium series describes mononuclear compounds containing only germanium-carbon and germanium-hydrogen bonds (Chapter 1.3). However, compound names were largely avoided, as most of the compounds are presented in tables and are only identified by their formulas.
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This volume C 3, as a part of the Gmelin "Thorium" Handbook, Series C, describes the thorium-nitrogen compounds.
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B 1 describes the compounds of nitrogen with noble gases and, in the major part, binary compounds composed of one nitrogen atom and hydrogen. The binary compounds of nitrogen and hydrogen comprise NH, NH , NH , NH , the corre 2 4 5 sponding ions, and some adducts.
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"Nitrogen" SuppL. Vol. 82 continues the description of binary compounds composed of nitrogen and hydrogen (nitrogen hydrides). While" Nitrogen" SuppL. Vol. 81 covers mono- nitrogen compounds, the present volume comprises compounds having two, three, four, or more nitrogen atoms. Hydrazine, N H , and its ions N2Ht and N2H~+ were not included. 2 4 (Reference is made to a voluminous monograph: E.W. Schmidt, Hydrazine and its Deriva- tives: Preparation, Properties, Applications, Chichester 1984, 1088 pages.) Among the dinitrogen compounds, the diazenyl cation, N H+, has been extensively inves- 2 tigated, especially in regards to spectroscopic and kinetic properties, because of its occur- rence in interstellar space. Chemically well-characterized are diazene, N H , the simplest 2 2 unsaturated nitrogen hydride which is used as a hydrogenation reagent, and the hydrazyl radical, N H , which is frequently present as an intermediate during the formation and 2 3 decay of nitrogen-hydrogen compounds. The major portion of this volume is taken up by hydrogen azide or hydrazoic acid, HN , the first member in the series of trinitrogen compounds.Known to be highly explosive 3 in pure form, it can be safely handled when diluted. Thus, a great deal of information is available mainly on its properties as a chemical reagent and its decomposition processes.
F Fluorine
Compounds with Oxygen and Nitrogen
Häftad, Engelska, 2013
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Thus, species such as NFt, NF , NF , and NF are considered first followed by the dinitrogen and 3 2 trinitrogen fluorides NF, NF, and NF and related ions.
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The present volume, Thorium C5, deals with the compounds of thorium and sulfur, selenium, tellurium, and boron, as well as with oxoacid compounds of the three chalcogen elements. Thorium sulfates are of some technological importance because they are formed in solution during recovery of thorium from monazite by sulfuric acid leaching.
S Sulfur-Nitrogen Compounds
Part 10a: Compounds with Sulfur of Oxidation Number II
Häftad, Engelska, 2013
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The present volume describes acyclic Sulfur-nitrogen compounds with sulfur of the oxida- tion number II. The first chapter deals with sulfur imide (S=NH), N-organyl-sulfur imides (S=NR, R = or- ganyl), and metal complexes of sulfur imides. N-Organyl-sulfur imides have not been isolated, but they can be trapped, for example, by cycloaddition and stabilized by coordination to transi- tion metals. 11 The following chapter present a detailed survey of other 8 -N compounds with one- coordinate sulfur, e.g., dithionitrous acid (S=N-SH) and derivatives, the salts of the dithionitryl ion (1 +) ([S=N=S]+), and N-thionitroso-diorganyl-amines (S=NNR , R = organyl). Only the reac- 2 tions of [S=N=S]+ AsF5, among the known [S=N=S]+ salts, have been extensively studied. Cycloadditions with alkenes and triple bonded compounds produce 1 ,3,2-dithiazolium salts and their derivatives. S=NN(CH )z and S=NN(C H )z form transition metal complexes. The 3 6 5 Iigand is coordinated via the S atom in a monodentate manner.
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PF3, (CH3)3SiCl -> (CH3)3SiF, and RC(O)Cl -> RC(O)F. Others include the conversion of (C6H5)3P into (C6H5)3PF2 and of (R3NC(S)S)2 into R2NCF3, R=alkyl. In organic chemistry, fluorides are easily accessible from alcohols, geminal fluorides RR'CF2 from the respective aldehydes or ketones, and acyl fluorides RC(O)F from carboxylic acides by using DAST. Because DAST is easy to handle and gives clean reactions in syntheses, this Gmelin volume devotes much space to the description of the chemical and physical properties od DAST.