Organic Nitro Chemistry - Böcker

Nitrocarbons are good nitrating agents, oxidants, and electron acceptors, and each known nitrocarbon has its own unique and interesting chemistry. Interest in synthesizing both known and new ('unknown') nitrocarbons stems from their value as potential explosive and propellant ingredients. In addition, the new chemistry developed in efforts to synthesize nitrocarbons has led to applications to many other synthetic problems.

Comprehensive and up-to-date, the book brings together for the first time synthetic nitration methods and mechanistic aspects of both aromatic and aliphatic nitrations. Researchers and students will appreciate the complete perspective of the whole field that this unique work offers.

The most useful reactions of organonitro compounds in organic synthesisCompounds containing nitro groups are useful intermediates for the synthesis of natural products and other complex organic molecules. The Nitro Group in Organic Synthesis focuses on reactions that proceed under mild conditions, important functional groups that can be synthesized by conversion of nitro groups, and the stereoselectivity of reactions of nitro compounds. These issues are of great importance to practicing researchers in today's pharmaceutical, agrochemical, and fine chemical industries.The Nitro Group in Organic Synthesis also emphasizes environmentally-friendly methods for nitration, the importance of aliphatic nitro compounds, and modern preparation of nitro compounds. Other topics discussed include:* Henry reaction* Asymmetric Michael addition* Alkylation, acylation, halogenation, and related reactions of RNO2* Substitution and elimination of NO2 and RNO2The Nitro Group in Organic Synthesis is a useful resource for researchers and students in organic and medicinal chemistry.