Polymer Chemistry Series – serie

Semiconducting polymers are of great interest for applications in electroluminescent devices, solar cells, batteries and diodes. In recent years vast advances have been made in the area of controlled synthesis of semiconducting polymers, specifically polythiophenes. The book is separated into two main sections, the first will introduce the advances made in polymer synthesis, and the second will focus on the microstructure and property analysis that has been enabled because of the recent advances in synthetic strategies.Edited by one of the leaders in the area of polythiophene synthesis, this new book will bring the field up to date with more recent models for understanding semiconducting polymers. The book will be applicable to materials and polymers chemists in industry and academia from postgraduate level upwards.

Nitroxide-mediated polymerization is an important branch of controlled radical polymerization, which has revolutionised the preparation of polymer architectures and compositions. This is the first book dedicated to the topic and covers the history and development of nitroxide-mediated polymerization, as well as current techniques of academic and industrial interest. Nitroxide-Mediated Polymerization gathers together and comprehensively discusses all aspects of nitroxide-mediated polymerization, from fundamental principles through to industrial applications. A specific focus will be dedicated to the principle of the technique, its kinetics aspects, the synthesis of the controlling agents, the range of polymerizable monomers, its potential for preparation of advanced organic and hybrid materials and its status at the industrial stage. The book details all stages of the field, with chapters detailing the history, recent developments and novel materials in this fast developing area. Edited and written by expert researchers working in the field and academia this book focuses on highlighting the kinetic aspects of nitroxide-mediated polymerization, providing insight into the kinetics that can sometimes be hard to follow in published papers. The book will be of interest to polymer chemists and materials scientists at graduate level and above.

Information technology is essential to our daily life, and the limitations of silicone based memory systems mean a growing amount of research is focussed on finding an inexpensive alternative to meet our needs and allow the continued development of the industry. Inorganic silicone based technology is increasingly costly and complex and is physically limited by the problems of scaling down. Organic electrical memory devices are comparatively low cost, offer flexibility in terms of chemical structure, are compatible with flexible substrates and allow easy processing. For these reasons polymeric memory nanoscale materials are considered by many to be a potential substitute for conventional semiconductor memory systems. This edited book focusses solely on organic memory devices, providing a full background and overview of the area before bringing the reader up to date with the current and ongoing research in this area. The broad appeal of this book will be applicable to a wide range of researchers and those working in industry, in particular those working in materials, electrical and chemical engineering.

With tremendous growth over the last five years, mechanochemistry has become one of the most important topics in current polymer science research. With a particular focus on polymers and soft materials, Mechanochemistry in Materials looks at the subject from the application of macroscopic forces to solid systems of macroscopic dimensions.The book has been divided according to length scale covering both experimental and theoretical considerations simultaneously. The first section of the book focuses on inspiration from nature, exploring and explaining multiple biological phenomena. The second section discusses molecular mechanochemistry, including the theoretical understanding of the transduction of mechanical force and its impact on covalent bonds cleavage and formation. The final section considers the implementation of these phenomena at the mesoscale and discusses the use of supramolecular/reversible aspects with similarities to biological systems.The book provides a unique comparison with natural systems and contains all the important achievements in the area from the last decade. Appealing to a broad range of materials scientists, working in industry and academia, this well-presented and comprehensive title will be essential reading for researchers.

All aspects of the personal care industry will be comprehensively discussed in Polymers for Personal Care Products and Cosmetics, including biological targets, safety issues, and the legal and regulatory aspects of this large industry. There will be a broad overview of cosmetic ingredients, vehicles and finished products as well as coverage of the main methodologies for microbiology, safety and efficacy testing. The reader will be provided with a solid background of the fundamentals of the area, before being brought up to date on the future of this field, along with discussion of the latest materials trends and future perspectives. Written by a World renowned expert in the area, the book will provide a unique look into this fast developing industry from interviews carried out with key experts in industry and academia. The advantages and disadvantages of the technologies involved in the development of these materials will be highlighted, providing a balanced and thorough review of the current state-of-the-art research. This book will appeal to researchers, academics and students working in polymer and materials chemistry, particularly those with an interest in personal care products.

Many key aspects of life are based on naturally occurring polymers, such as polysaccharides, proteins and DNA. Unsurprisingly, their molecular functionalities, macromolecular structures and material properties are providing inspiration for designing new polymeric materials with specific functions, for example, responsive, adaptive and self-healing materials.Bio-inspired Polymers covers all aspects of the subject, ranging from the synthesis of novel polymers, to structure-property relationships, materials with advanced properties and applications of bio-inspired polymers in such diverse fields as drug delivery, tissue engineering, optical materials and lightweight structural materials.Written and edited by leading experts on the topic, the book provides a comprehensive review and essential graduate level text on bio-inspired polymers for biochemists, materials scientists and chemists working in both industry and academia.

Fluoropolymers display a wide range of remarkable properties and are used in a number of applications including high performance elastomers, thermoplastics, coatings for optical fibers, and hydrophobic and lipophobic surfaces. Fluorinated Polymers: Synthesis, Properties, Processing and Simulation covers the fundamentals of different fluorinated polymers. Topics include the kinetics of homopolymerisation and copolymerization, process chemistry, and controlled radical co-polymerisation techniques. Written by internationally recognized academic and industrial contributors, the book will be of interest to those in industry and academia working in the fields of materials science, polymer chemistry and energy applications of polymers. Together with Fluorinated Polymers: Applications, these books provide a complete overview of different fluorinated polymer materials and their uses.

The term ‘miktoarm polymers’ refers to asymmetric branched macromolecules, a relatively new entry to the macromolecular field. Recent advances in their synthesis and intriguing supramolecular chemistry in a desired medium has seen a fast expansion of their applications. The composition of miktoarm polymers can be tailored and even pre-defined to allow a desired combination of functions, meaning polymer chemists can have complete control of the overall architecture of these macromolecules. By carefully selecting the composition, they can create supramolecular structures with intriguing properties, particularly for applications in biology. Miktoarm Star Polymers features chapters from experts actively working in this field, and provides the reader with a unique introduction to the fundamental principles of this exciting macromolecular system. Topics covered include the design, synthesis, characterization, self-assembly and applications of miktoarm polymers.The book is an excellent overview and up to date guide to those working in research in polymer chemistry, materials science, and polymers for medical applications.

There is great interest in the preparation of synthetic receptor-based recognition units for cheap, robust, economic, and selective chemical sensors. Molecular imprinting provides the technology to prepare these synthetic units. There are still more and more syntheses of artificial molecular recognition constructs using analytes or their close structural analogues as templates for molecular imprinting. Stability of complexes of these constructs with the target analytes are often similar to those of biological receptors. Therefore, subsequent polymerization of these complexes results in molecularly imprinted polymers (MIPs) that have a selectivity close to that revealed by natural receptors.The book summarizes the latest developments and applications of molecular imprinting for selective chemical sensing with each chapter devoted to different analytical applications of molecularly imprinted polymers. Specific chapters include: designing of molecular cavities aided by computational modelling, application of molecularly imprinted polymers for separation as well as sensing of pharmaceuticals and nucleotides. The book is suitable for academics, postgraduates, and industrial researchers active in analytical chemistry, synthetic organic chemistry, molecular recognition, electrochemistry, and spectroscopy.

Click chemistry describes organic reactions which are highly efficient, regioselective and allow for mild reaction conditions. The archetypal click reaction of Cu(I)-catalyzed azide-alkyne cycloaddition (CuAAC) is used in many diverse areas and has been extensively developed for polymer synthesis, leading to the term of click polymerization. This technique enables the preparation of functional polymers with linear and topological structures that have the potential to be used in optoelectronics and biological fields.Edited by world renowned experts, Click Polymerization is the first book to comprehensively summarize this approach to polymer synthesis consolidating all the different reaction types in one resource. From the basic knowledge through to the latest developments in synthesis, chapters include transition-metal catalysed and metal-free azide-alkyne click polymerizations as well as thiol-ene, thiol-yne and thiol-epoxy click polymerizations.The book provides an authoritative guide to click polymerization techniques for graduate students and researchers interested in polymer chemistry and materials science.

New materials are required to solve global challenges such as the growing energy demand and reducing the threat of new and re-emerging diseases and infections. Metallopolymers is an exciting and promising area of research and this book focuses on the strategy of incorporating transition metals into macromolecules to design functional materials for addressing such problems.The book starts with an introduction to current global challenges and the role of materials science in tackling these, it then discusses the fundamentals of metallopolymers and their synthesis. The final chapters look at specific applications of the materials from photovoltaics and light-emitting diodes for energy conservation, to biological sensors and drug delivery platforms.Written by leading experts in the field, this book is an ideal reference for students and researchers working in polymer chemistry, organometallic chemistry and materials science interested in both the polymers and their applications in energy and health.

Fluoropolymers display a wide range of remarkable properties and are used in a number of applications including high performance elastomers, thermoplastics, coatings for optical fibers, and hydrophobic and lipophobic surfaces.Fluorinated Polymers: Applications covers the recent developments in the uses of fluoropolymers. Examples include materials for energy applications such as fuel cell membranes, lithium ion batteries and photovoltaics, as well as high-tech areas such as aerospace and aeronautics, automotives, building industries, textile finishings and electronics.Written by internationally recognized academic and industrial contributors, the book will be of interest to those in industry and academia working in the fields of materials science, polymer chemistry and energy applications of polymers.Together with Fluorinated Polymers: Synthesis, Properties, Processing and Simulation, these books provide a complete overview of different fluorinated polymer materials and their uses.

Fluoropolymers display a wide range of remarkable properties and are used in a number of applications including high performance elastomers, thermoplastics, coatings for optical fibers, and hydrophobic and lipophobic surfaces. The set contains two books, Fluorinated Polymers: Synthesis, Properties, Processing and Simulation and Fluorinated Polymers: Applications. The first book covers the fundamentals of fluoropolymers including the kinetics of homopolymerisation and copolymerization, process chemistry, and controlled radical co-polymerisation techniques. The second book discusses the recent developments in the uses of fluoropolymers. Examples include materials for energy applications such as fuel cell membranes, lithium ion batteries and photovoltaics, as well as high-tech areas such as aerospace and aeronautics, automotives, building industries, textile finishings and electronics. Written by internationally recognized academic and industrial contributors, the book will be of interest to those in industry and academia working in the fields of materials science, polymer chemistry and energy applications of polymers. Together these two books provide a complete overview of different fluorinated polymer materials and their uses.

Photoinitiating systems play a key role in the starting point of a polymerization reaction under exposure to a UV or a visible light. The number of publications discussing photoinitiating systems for polymerization has seen a significant growth in recent years and this book provides an update on their latest research developments.The book covers different types of photoinitiating systems including UV radical photoinitiators, long wavelength sensitive radical photoinitiators, cationic photoinitiators and water soluble photoinitiators as well as a chapter on how to design novel photoinitiators. The book then focusses on the applications of the photoinitiators from nanoparticles and materials to ionic liquids and solar cells.Edited by leading names in the field, the book is suitable for postgraduate students and researchers in academia and industry interested in polymer chemistry, organic chemistry, materials science and the applications of the materials.

In recent years polymerisation using organocatalysts has become an appealing alternative to more traditional metal-based catalysts. Conferring numerous advantages including low cost and ease of use, as well as the ability to precisely control the synthesis of advanced polymer structures, organocatalysts are increasingly used in polymer synthesis. Organic Catalysis for Polymerisation provides a holistic overview of the field, covering all process in the polymer synthesis pathway that are catalysed by organic catalysts. Sub-divided into two key sections for ease of use, the first focuses on recent developments in catalysis and the applications of catalysts to the full range of polymerisations that they have been utilised in; the second concerning monomers, arranges the field by monomer type and polymerisation mechanism. The book will therefore, provide a complimentary view of the field, providing both an overview of state-of-the-art catalyst development and also the best methodologies available to create specific polymer types. Edited by leading figures in the field and featuring contributions from researchers across the globe, this title will serve as an excellent reference for postgraduate students and researchers in both academia and industry interested in polymer chemistry, organic chemistry, catalysis and materials science.

Amphiphilic polymer co-networks (APCNs) are a type of polymeric hydrogel, their hydrophobic polymer segments and hydrophilic components produce less aqueous swelling, giving better mechanical properties than conventional hydrogels. This new class of polymers is attracting increasing attention, resulting in further basic research on the system, as well as new applications.This book focuses on new developments in the field of APCNs, and is organised in four sections: synthesis, properties, applications and modelling. Co-network architectures included in the book chapters are mainly those deriving from hydrophobic macro-cross-linkers, representing the classical approach; however, more modern designs are also presented. Properties of interest discussed include aqueous swelling, thermophysical and mechanical properties, self-assembly, electrical actuation, and protein adsorption. Applications described in the book chapters include the use of co-networks as soft contact lenses, scaffolds for drug delivery and tissue engineering, matrices for heterogeneous biocatalysis, and membranes of controllable permeability. Finally, an important theory chapter on the modelling of the self-assembly of APCNs is also included.The book is suitable for graduate students and researchers interested in hydrogels, polymer networks, polymer chemistry, block copolymers, self-assembly and nanomaterials, as well as their applications in contact lenses, drug delivery, tissue engineering, membranes and biocatalysis.

Polymeric materials form the basis of daily life. Despite the great contribution of traditional methodologies such as anionic and radical polymerizations in preparing various functional polymers, the increasing demand for polymers with new structures and functions has inspired the development of new synthetic techniques. Many new polymerizations including click polymerization, controlled/living radical polymerization, multicomponent polymerization have been well developed. Focusing on breakthroughs and recent progress, Synthetic Polymer Chemistry provides efficient tools for the synthesis of linear and topological polymers. Chapters cover topics including fabrication of supramolecular polymers, organocatalytic synthesis and olefin co(polymerization). This title will be a valuable reference for those working in polymer chemistry, as well as students and researchers interested in opto-electronic, biological and materials sciences.

Polymers with redox properties are electroactive macromolecules containing localized sites or groups that can be oxidized and reduced. Depending on the oxidation state, redox polymers can present different electronic, optical, mechanical or chemical properties. These polymers are finding new applications in materials science, as well as being included in the design of a number of electrochemical devices. Redox Polymers for Energy and Nanomedicine highlights trends in the chemistry, characterization and application of polymers with redox properties. The book starts with an introduction to redox polymers and covers several important topics including redox polymer types, state-of-the-art characterization techniques, synthetic strategies and theory and computational studies. The second part is devoted to the redox polymers applied in energy and nanomedicine. First, the most important redox polymer families in energy storage are reviewed, i.e, radical, phenothiazine, carbonyl and catechol containing polymers. The book also contains recent developments in redox polymers for biofuel cells and all-organic batteries. Second, the emerging applications of redox polymers in nanomedicine technologies such as, tissue engineering, drug-delivery, actuators or biosensors are explained in detail. With contributions from global experts, the book will be of interest to graduate students and researchers working in polymer science, electrochemistry, energy research and nanomedicine.

There is an immense variety of research on polymer functionalized graphene (PFG). Functionalization of graphene is necessary for improvement of the compatibility with polymers. Applications of these graphene polymer hybrids include in chemical and biological sensing, photovoltaic devices, supercapacitors and batteries, dielectric materials and drug/gene delivery vehicles. This book will shed light on the synthesis, properties and applications of these new materials, covering two methods (covalent and noncovalent) for producing polymer functionalized graphene. Chapters cover physical, optical, mechanical and electronic properties, applications of polymer functionalized graphene in energy harvesting and storage, and uses in biomedicine and bioengineering. Written by an expert in the field, Polymer Functionalized Graphene will be of interest to graduate students and researchers in polymer chemistry and nanoscience.

In the decade since the 1st Edition, healable polymeric materials have moved on from being a chemical curiosity to having useful applications across a broad range of fields.This 2nd Edition is fully revised with new sections on current and future applications in the following chapters: i) Reversible Covalent Bond Formation as a Strategy for Healable Polymer Networks; ii) Healable Supramolecular Polymeric Materials and iii) Encapsulation-based Self-healing Polymers and Composites.Polymers are used in many everyday technologies and their degradation due to environmental exposure has led to great interest in materials which can heal and repair themselves. In order to design new self healing polymers it's important to understand the fundamental healing mechanisms behind the material. Healable Polymer Systems outlines the key concepts and mechanisms underpinning the design and processing of healable polymers, and indicates potential directions for progress in the future development and applications of these fascinating and potentially valuable materials. Written by leading experts, the book provides polymer scientists with a compact and readily accessible source of reference for healable polymer systems.

Electrospinning techniques are used to produce novel nanoscale fibrous materials used in a diverse range of applications. The field has seen significant growth in the past 10 years and this new edition has been fully revised with new chapters added in more topical areas, in particular:Voltage polarityNanofiber-based face masksIt provides a snapshot of the current cutting-edge developments of the field. This balanced and authoritative book will appeal to a broad audience of postgraduate students, and industrial and academic researchers in the physical and life sciences as well as engineering.

Rubbers are ubiquitous materials that play irreplaceable roles in modern society, from tires, seals, hoses, vibration/noise control, biomedical devices, and stretchable electronics to soft robotics. The traditional rubber manufacturing and vulcanization process is energy-intensive, and the end-of-life rubber products are hard to reuse and recycle due to the permanently crosslinked chemical structures and the variety of processing additives involved. Innovation of sustainable rubber chemistry and technology is urgently needed.This book provides critical reviews of the latest developments in rubber technology, including energy-efficient devulcanization techniques, the dynamic crosslinking chemistry of rubbers, and an understanding of the trade-off between network dynamics and the properties of rubber. Further chapters explore the functionalization and hybridization of fillers and how blends, TPVs, and multiple networks influence the sustainability of rubber. The book concludes with an examination of new developments and real-world applications of rubber in the circular economy.

This book introduces in detail the development history, synthesis methods, physicochemical propertiesand the main application in agriculture, hygiene, construction, environmental management, bioscience and more, based on the multiple properties including absorption, flexibility, elasticity, sensitivity, etc.Edited by experts in the area, the book also highlights the biodegradability, commercial viability and market potential of SAPs, SAP composites, the feasibility of using biomass as raw materials for SAP production.This well-rounded consideration of the topic makes this book suitable for a range of academic professionals and industry professionals working in polymer science, material science and environmental science.

Polymer gels and supramolecular gels are an interesting classes of materials that continue to attract significant research interest. Bringing together recent scientific and technological advances, the volume offers an up-to-date overview for researchers and technologists alike. It discusses key aspects such as the fabrication and patterning of gel materials, their physical, optical, mechanical, and electronic characteristics, and their use in areas including energy technologies, environmental solutions, and biotechnology.Distinguished by its depth of analysis and broad international relevance, this work serves as an essential resource for readers seeking insight into contemporary developments and emerging directions in gel science.

Supramolecular polymers are a unique class of materials composed of monomeric units held together by reversible and highly directional secondary interactions. Over the past decade, the field of supramolecular polymers has experienced remarkable growth, driven by novel non-covalent forces and innovative building blocks. These advancements have provided deeper thermodynamic and kinetic insights into the processes of non-covalent supramolecular polymerization. The potential applications of supramolecular polymers in materials science and biomedicine are increasingly recognized and valued.This book, edited by leading experts in the field, begins with a comprehensive overview of the state-of-the-art developments in supramolecular polymer chemistry. It then shifts focus to explore the diverse applications of supramolecular polymers in various materials, including:Self-healing materialsBiomedicineOptoelectronicsAs such, this book provides an invaluable resource for researchers in chemistry, materials science, and related fields, offering a deep understanding of supramolecular polymers and their potential applications. By highlighting the latest research findings, this book serves as an important reference for those seeking to explore the exciting opportunities in this rapidly expanding field.

Polymeric corrosion inhibitors can efficiently reduce the problems brought on by corrosion. This book focuses on the basic properties of polymers as anticorrosive materials, their historical development, and their industrial uses. In fantastic detail, the book discusses:SynthesisCharacterisationMechanisms of inhibitionIndustrial uses of polymeric anticorrosive compounds

This book, edited by experts in the area, presents an overview of the different types of dielectric electroactive polymers, covering the basic principles of their main characteristics and functional responses, and their applications. The book emphasizes both the established concepts as well as the most recent advances in materials, processing technologies and applications.The compatibility of several of these polymers with additive manufacturing technologies, allowing improved integration into devices and tailored shapes, is further expanding their areas of application, being particularly relevant in the digitalization of society and industry.

The field of optoelectronic polymers has continuously expanded in the past two decades because of their innovative applications in a variety of technologies in optoelectronic, photonic and energy research. Groups across the world are still looking into the fundamentals, as well as their applications, which remain to be fully understood and envisioned. This is the first book on the topic for researchers who are entering the field, highlighting the remarkable basic science and technological potential of this class of materials. Chapters will focus on the fundamental concepts as well as up-and-coming research into the applications of these polymers. Chapters will look at topics such as pure organic phosphorescence and external stimuli-responsive luminescent materials that are not covered in other books.

‘Click’ reactions are a unique class of versatile synthetic tools used in organic and polymer chemistry to develop new materials. The high efficiency of the click reactions, combined with their easy and straightforward execution, have made them an inevitable tool for the development of a variety of advanced polymer materials with tailor-made architectures and stimuli-responsive features.This book aims to give a comprehensive overview and introduction on the use of ‘click’ chemistry in polymer science, including ‘click,’ ‘click-like,’ and reversible ‘click’ (or ‘un-click’) approaches in the design of macromolecules. Moreover, it will outline recent progress in utilizing different ‘click chemistry’ in the development of functional polymer materials for various applications, such as self-healing, hydrophobic, shape-memory, and bio-based materials.Written and edited by leading experts in the field, chapters cover the use of different ‘click’ reactions, like azide-alkyne, Diels-Alder, Alder-ene, thiol-X, electrophilic substitution, and trans (esterification/amination) reactions, in polymer science. It will also cover the concept of ‘trans-click’ reactions, which have come to the foreground on account of improving the exchangeable efficiency of covalent bonds in covalent adaptable polymer materials.Recognizing the present state-of-the-art, this book will be a suitable reference handbook with a valuable resource of information for students of all levels, for learning and teaching endeavors, and for researchers and scientists working on the next generation of advanced polymeric materials.