Reviews in Mineralogy & Geochemistry – serie

Volume 1 of Reviews in Mineralogy introduces to the mineralogy of sulfides. It covers the Determination, Relationships, and Classification of Sulfide Mineral Structures, Sulfide Crystal Chemistry, Electron Interactions and Chemical Bonding in Sulfides, Experimental Methods in Sulfide Synthesis, Sulfide Phase Equilibriaand Sulfide Petrology.The Short Course on Sulfide Mineralogy was given November 15-17, 1974, preceding the annual meetings of the affiliated societies of the Geological Society of America, at the Sheraton Four Ambassadors Hotel in Miami, Florida, USA with eighty persons in attendance.

Volume 3 of Reviews in Mineralogy provides an up-to-date review of the mineralogy and petrology of rock-forming opaque oxide minerals. It was the textbook for the short course on rock-forming oxide minerals sponsored by the Mineralogical Society of America at the Colorado School of Mines, November 5-7, 1976. The contributors hope that the work will be valuable not only to participants in the short course, but also to others desiring a modern review of the subject.

Volume 4 of Reviews in Mineralogy was prepared to serve as notes for a short course on the Mineralogy and Geology of Natural Zeolites held in Seattle, Washington, November 4-6, 1977. The title of the short course reads Natural Zeolites; however, the subject matter treated in the course and reviewed here deals primarily with those zeolites that occur in sedimentary rocks and which have formed by authigenic or burial diagenetic processes. Unfortunately, only limited coverage has been given to the classical occurrences of zeolites--the megascopic crystals in the vugs and cavities of basalts and other basic igneous rocks. Our only justification is that since the late 1950s, almost all major efforts on zeolites have been directed towards the "sedimentary" occurrences, and it is these occurrences of zeolites in sedimentary rocks that are still unfamiliar to many geologists and mineralogists. It is our intention that this short course and these notes will play a small role in alleviating this unfamiliarity.

Volume 6 of Reviews in Mineralogy was originated from notes prepared for a short course on Marine Minerals held in La Jolla, California, November 2-3, 1979. Chapters in this volume are devoted to marine manganese oxide, iron oxide, silica polymorphs, zeolite, clay, phosphorite, barite, evaporite, and placer minerals. Carbonates are not included; coverage of this important mineral group warrants a separate monograph. The extremely interesting sulfide and hydrothermal mineral assemblages recently discovered at oceanic spreading centers are also not discussed here.

Marine Minerals was first published in 1979 as Volume 6 of the series entitled Short course. In 1980 the Mineralogical Society of America changed the name of the series to Reviews in Mineralogy, and for that reason this, the second printing of Marine Minerals has been reissued under the new banner. Only minor corrections have been made.

Volume 7 of Reviews in Mineralogy reviews the essential aspects of pyroxene research. Recently, Deer, Howie and Zussman (DHZ) published a second edition of their volume in the Rock-Forming Minerals series, Single-Chain Silicates, Vol. 2A (John Wiley, New York, 1978). The present volume is intended to be complementary to DHZ and to provide material covered lightly or not at all in DHZ, such as electron microscopy, spectroscopy, and detailed thermodynamic treatments. However, because the range of pyroxene research has grown so much in recent years, there still are important areas not covered comprehensively in either of these volumes. Some of these areas are kinetics, diffusion, crystal defects, deformation, and nonsilicate pyroxene crystal chemistry. Because of these omissions and because this volume is intended for use with the MSA Short Course on Pyroxenes to be held at Emory University in conjunction with the November, 1980 meeting of the Society, a Symposium on Pyroxenes was organized by J. Stephen Huebner for the meeting that is designed to present the latest research results on several different topics, including those above. With DHZ, this volume, and publications from the Symposium, the student of pyroxenes should be well-equipped to advance our knowledge of pyroxenes in the decades ahead.

Volume 8 of Reviews in Mineralogy treats a Short Course in Kinetics, which brings together the fundamentals needed to explain field observations using kinetic data. It is hoped that this book may serve, not only as a reference for researchers dealing with the rates of geochemical processes, but also as a text in courses on geochemical kinetics.

The book is organized with a rough temperature gradient in mind, i.e. low temperature kinetics at the beginning and igneous kinetics at the end. However, the topics in each chapter are general enough that they can be applied often to any geochemical domain: sedimentary, metamorphic or igneous. The theory of kinetics operates at two complementary levels: the phenomenological and the atomistic. The former relies on macroscopic variables (e.g. temperature or concentrations) to describe the rates of reactions or the rates of transport; the latter relates the rates to the basic forces operating between the particular atomic or molecular species of any system. This book deals with both descriptions of the kinetics of geochemical processes.

Most of Volume 9A of Reviews in Mineralogy treats amphiboles and other hydrous pyriboles as isolated systems. It reviews the structural complexity and resulting chemical variability and diversity of petrologic behavior of amphiboles, whereby Volume 9A contains a hefty dose of petrology and in contrast, Volume 9B is dedicated more to an exploration of the social life of amphiboles and the amphibole personality in real rocks and in the experimental petrology laboratory.

This volume was prepared in conjunction with the Mineralogical Society of America Short Course on Amphiboles and Other Hydrous Pyriboles, Fall, 1981.

Volume 9B of Reviews in Mineralogy is dedicated more to an exploration of the social life of amphiboles and the amphibole personality in real rocks and in the experimental petrology laboratory. The chemical complexity of amphibole, which Robinson et al., refer to as "a mineralogical shark in a sea of unsuspecting elements," permits amphiboles to occur in a very wide variety of rock types, under a large range of pressure and temperature conditions, and in association with an impressive number of other minerals. The description of amphibole petrology and of petrologists' attempts to understand amphibole phase relations are therefore not simple matters, as the length of this volume suggests. Although they do not cover every type of amphibole occurrence, it is hoped that the papers in this volume will provide the amphibole student and researcher with an up-to-date summary of the most important aspects of amphibole petrology.

Volume 9B, Amphiboles: Petrology and Experimental Phase Relations, was begun in 1981 in preparation for the Short Course on Amphiboles and Other Hydrous Pyriboles presented at Erlanger, Kentucky, October 29 - November 1, 1981, prior to the annual meetings of the Geological Society of America and associated societies. Unfortunately, only the first chapter was in manuscript form at the time of the short course, and publication was delayed by one year.

Volume 10 of Reviews in Mineralogy reviews the use of a powerful probe into metamorphic process: mineral assemblages and the composition of minerals. Put very simply, this volume attempts to answer the question: "What can we learn about metamorphism through the study of minerals in metamorphic rocks?" It is not an encyclopedic summary of metamorphic mineral assemblages; instead it attempts to present basic research strategies and examples of their application. Moreover, in order to limit and unify the subject matter, it concentrates on the chemical aspects of metamorphism and regrettably ignores other important kinds of studies of metamorphic rocks and minerals conducted by structural geologists, structural petrologists, and geophysicists.

Volume 5 of Reviews in Mineralogy emphasizes the crystal chemistry and related physical properties of the major rock-forming orthosilicates. Though in some chapters more attention is given to phase equilibria and paragenesis than in others, these are for the most part cursorily treated with references to the more important papers and to review articles (also see Deer, Howie and Zussman, 1962, Rock-forming Minerals, Vol. 1, Ortho- and Ring Silicates).

Volume 2 of Reviews in Mineralogy displays the Short Course on Feldspar Mineralogy in Salt Lake City in October 1975. The workshops on x-ray single-crystal, powder diffraction methods and electron optical techniques as applied to the study of feldspars are the substance of which became the nine chapters of the first edition of Feldspar Mineralogy.It will be noted by readers experienced with feldspars that there are many new ideas appearing in Chapters 3, 4 and 5 that have neither received scrutiny by review (other than ourselves) nor survived practical tests of time in the research community. There is some danger in this, but the editor decided the greater risk was to produce a review volume soon to be outdated. Inevitably, given the different goals of individual authors in their assigned topics, some repetition of material has occurred, although usually with quite different emphases. Chapters 1, 2, 9 and 10, in which plagioclase structures and diffraction patterns and their Al,Si distributions, phase equilibria and exsolution textures are featured, are notable in this regard.

Volume 11 of Reviews in Mineralogy attempts to synthesize our present understanding of certain aspects of the mineralogy and chemistry of the rock-forming carbonates. This review follows, by ten years, a major assessment of (sedimentary) carbonate minerals by Lippmann (1973). There is only minor overlap of subject material, and I hope that this difference reflects fairly how this field has developed.In this volume, some of the papers are general (i.e., those addressing crystal chemistry and phase relations), and they provide overviews of a fundamental nature and are of interest to many. Others are more specialized in coverage and generally reflect the different approaches used in carbonate geochemistry. The final chapter introduces transmission electron microscopy, a relatively new and powerful technique for mineralogical research that has great potential in carbonate research.

Volume 12 of Reviews in Mineralogy introduces to fluid inclusions. It covers the folowing questions: when and where inclusions form. how they change, how to prepare material and make microthermometric measurementsl, how to interpret these data, and what has been found in applications of fluid-inclusion studies to each of a series of different geologic environments. This book also attempts to discuss the many applications of fluid inclusions to the study of and understanding of geologic processes and the geologic environments in which they acted.

Volume 13 of Reviews in Mineralogy attempts to gather together much of our knowledge of micas, the most abundant phyllosilicate, and to indicate promising areas of future research. Chapters 1-3 lay the foundations of the classification, structures, and crystal chemistry of micas. Chapter 4 treats bonding and electrostatic modeling of micas. Chapters 5 and 6 cover spectroscopic and optical properties. Chapters 7-13, the bulk of the volume, are devoted to geochemistry and petrology. These include phase equilibria and the occurrences, chemistry, and petrology of micas in igneous, metamorphic, and sedimentary rocks, pegmatites, and certain ore deposits. Some treatments are exhaustive. All are at the forefront of our present knowledge, and indicate clearly the practical applications'of the study of micas to ascertaining various parameters of origin and crystallization history, as well as the many problems that still exist. The aim of this type of treatment is to provide a reference volume for teachers and students and to enable researchers to pick more easily those directions and problems for which future research is most needed or is apt to be most productive or most challenging.

Volume 14 of Reviews in Mineralogy covers a short course about the relations among the microscopic structure of minerals and their macroscopic thermodynamic properties. Understanding the micro-to-macro relations provides a rigorous theoretical foundation for formulation of energy relations. With such a foundation, measured parameters can be understood, and extrapolation and prediction of thermodynamic properties beyond the range of measurement can be done with more confidence than if only empirical relations are used.The purpose of this course is to consider the microscopic factors that influence the free energy of minerals: atomic environments, bonding, and crystal structure. These factors influence the structural energy and the detailed nature of the lattice vibrations which are an important source of entropy and enthalpy at temperatures greater than 0 K. The same factors determine the relative energy of different phases, and thereby; the relative stability of different minerals. Configurational entropy terms arising from disorder also contribute to the energy and entropy. In transition metal compounds there are additional energy and entropy terms arising from the electronic configurations, leading to additional stabilizations, magnetic ordering, and, incidentally, color.Organized by Sue Kieffer and Alex Navrotsky, the course was presented by the ten authors of this book on the campus of Washington College in Chestertown, Maryland. This was the second of MSA's short courses to be given in conjunction with meetings of the American Geophysical Union.

Volume 15 of Reviews in Mineralogy is written with two goals in mind. The first is to derive the 32 crystallographic point groups, the 14 Bravais lattice types and the 230 crystallographic space group types. The second is to develop the mathematical tools necessary for these derivations in such a manner as to lay the mathematical foundation needed to solve numerous basic problems in crystallography and to avoid extraneous discourses. To demonstrate how these tools can be employed, a large number of examples are solved and problems are given. The book is, by and large, self-contained. In particular, topics usually omitted from the traditional courses in mathematics that are essential to the study of crystallography are discussed. For example, the techniques needed to work in vector spaces with noncartesian bases are developed. Unlike the traditional group-theoretical approach, isomorphism is not the essential ingredient in crystallographic classification schemes. Because alternative classification schemes must be used, the notions of equivalence relations and classes which are fundamental to such schemes are defined, discussed and illustrated. For example, we will find that the classification of the crystallographic space groups into the traditional 230 types is defined in terms of their matrix representations. Therefore, the derivation of these groups from the point groups will be conducted using the 37 distinct matrix groups rather than the 32 point groups they represent.

Volume 16 of Reviews in Mineralogy inroduces to high-temperature stable isotope geochemistry and should provide an entry into the pertinent literature, as well as some understanding of the basic concepts and potential applications.The first three chapters focus on the theory and experimental data base for equilibrium, disequilibrium, and kinetics of stable isotope exchange reactions among geologically important minerals and fluids. The fourth chapter discusses the primordial oxygen isotope variations in the solar system prior to formation of the Earth, along with a discussion of isotopic anomalies in meteorites. The fifth chapter discusses isotopic variations in the Earth's mantle and the sixth chapter reviews the variations in the isotopic compositions of natural waters on our planet. In Chapters 7, 8, 9 and 10, these isotopic constraints and concepts are applied to various facets of the origin and evolution of igneous rocks, bringing in much material on radiogenic isotopes as well, because these problems require a multi-dimensional attack for their solution. In Chapters 11 and 12, the problems of hydrothermal alteration by meteoric waters and ocean water are considered, together with discussions of the physics and chemistry of hydrothermal systems and the 18O/16O history of ocean water. Finally, in Chapters 13 and 14, these concepts are applied to problems of metamorphic petrology and ore deposits, particularly with respect to the origins of the fluids involved in those processes.

Volume 17 of Reviews in Mineralogy is based on a short course, entitled "Thermodynamic Modeling of Geological Materials: Minerals, Fluids amd Melts," October 22-25, 1987, at the Wickenburg Inn near Phoenix, Arizona.

Contents:Thermodynamic Analysis of Phase Equilibria in Simple Mineral SystemsModels of Crystalline solutionsThermodynamics of Multicomponent Systems Containing Several Solid SolutionsThermodynamic Model for Aqueous Solutions of Liquid-like DensityModels of Mineral Solubility in Concentrated Brines with Application to Field ObservationsCalculation of the Thermodynamic Properties of Aqueous Species and the Solubilities of Minerals in Supercritical Electrolyte SolutionsIgneous FluidsOre Fluids: Magmatic to SupergeneThermodynamic Models of Molecular Fluids at the Elevated Pressures and Temperatures of Crustal MetamorphismMineral Solubilities and Speciation in Supercritical Metamorphic FluidsDevelopment of Models for Multicomponent Melts: Analysis of Synthetic SystemsModeling Magmatic Systems: Thermodynamic RelationsModeling Magmatic Systems: Petrologic Applications

Volume 18 of Reviews in Mineralogy provides a general introduction to the use of spectroscopic techniques in Earth Sciences. It gives an Introduction To Spectroscopic Methods and covers Symmetry, Group Theory And Quantum Mechanics; Spectrum-Fitting Methods; Infrared And Raman Spectroscopy; Inelastic Neutron Scattering; Vibrational Spectroscopy Of Hydrous Components; Optical Spectroscopy; Mossbauer Spectroscopy; MAS NMR Spectroscopy Of Minerals And Glasses; NMR Spectroscopy And Dynamic Processes In Mineralogy And Geochemistry; X-Ray Absorption Spectroscopy: Applications In Mineralogy ind Geochemistry; Electron Paramagnetic Resonance; Auger Electron And X-Ray Photelectron Spectroscopies and Luminescence, X-Ray Emission and New Spectroscopies.

The authors of this volume presented a short course, entitled "Spectroscopic Methods in Mineralogy and Geology", May 13-15, 1988, in Hunt Valley, Maryland.

Volume 13 of Reviews in Mineralogy presents much of our present-day knowledge of micas. Since 1984 was too much material available to attempt to cover all of the hydrous phyllosilicates in one volume, the micas were treated first because of their abundance in nature and the fact that many detailed studies had been carried out on them. The serpentines, kaolins, smectites, chlorites, etc. would have to wait their turn. Now, four years later, that tum has come. Hence the peculiar nature of the title of this volume.

We know less about the rest of the phyllosilicates than we do about the micas, primarily because many of them are of finer grain sizes and lower crystallinities than most of the micas. As a result, we have been unable to determine as much detail regarding their structures, crystal chemistries, and origins. One compensating factor that has helped greatly in the accumulation of knowledge about these minerals is that some of them occur in large deposits that are of great economic value and thus stimulate interest. For this reason considerable emphasis in this volume will be related to the occurrence, origin, and petrology of the minerals.

Volume 20 of Reviews in Mineralogy attempted to: (1) provide examples illustrating the state-of-the-art in powder diffraction, with emphasis on applications to geological materials; (2) describe how to obtain high-quality powder diffraction data; and (3) show how to extract maximum information from available data.

In particular, the nonambient experiments are examples of some of the new and exciting areas of study using powder diffraction, and the interested reader is directed to the rapidly growing number of published papers on these subjects. Powder diffraction has evolved to a point where considerable information can be obtained from ug-sized samples, where detection limits are in the hundreds of ppm range, and where useful data can be obtained in milliseconds to microseconds. We hope that the information in this volume will increase the reader's access to the considerable amount of information contained in typical diffraction data.

Volume 21 of Reviews in Mineralogy treats a short course on the rare earth elements to about 80 participants in San Francisco, California, December 1-3, 1989, just prior to the fall meeting of the American Geophysical Union.

Contents:Cosmochemistry of the Rare Earth Elements: Condensation and Evaporation ProcessesRadiogenic Isotope Geochemistry of Rare Earth ElementsPartitioning of Rare Earth Elements between Major Silicate Minerals and Basaltic MeltsAn Approach to Trace Element Modeling Using a Simple Igneous System as an ExampleRare Earth Elements in Upper Mantle RocksRare Earth Elements in Metamorphic RocksRare Earth Elements in Sedimentary Rocks: Influence of Provenance and Sedimentary ProcessesAqueous Geochemistry of Rare Earth ElementsRare Earth Elements in Lunar MaterialsCompositional and Phase Relations among Rare Earth Element MineralsEconomic Geology of Rare Earth MineralsCathodoluminescence Emission Spectra of Rare Earth Element Activators in Minerals

Volume 23 of Reviews in Mineralogy and accompanying MSA short course covers chemical reactions that take place at mineral-water interfaces. We believe that this book describes most of the important concepts and contributions that have driven mineral-water interface geochemistry to its present state. We begin in Chapter 1 with examples of the global importance of mineral-water interface reactions and a brief review of the contents of the entire book. Thereafter, we have divided the book into four sections, including atomistic approaches (Chapters 2- 3), adsorption (Chapters 4-8), precipitation and dissolution (Chapters 9-11), and oxidation-reduction reactions (Chapters 11-14).

Volume 24 of Reviews in Mineralogy attempted to bring together the basic data and fundamental theoretical constraints on magmatic processes with applications to specific problems in igneous petrology. The Mineralogical Society of America (MSA) sponsored the short course on "Modern Methods of Igneous Petrolgy: Understanding Magmatic Processes" at the Cathedral Hill Hotel in San Francisco, California in December 1990. It was organized by the editors, Jim Nicholls and Kelly Russell, and presented by the authors of this volume to about 80 participants in conjunction with the Fall Meeting of the American Geophysical Union.

Volume 25 of Reviews in Mineralogy was published to be used as the textbook for the Short Course on Fe-Ti Oxides: Their Petrologic and Magnetic Significance, held May 24-27, 1991, organized by B.R. Frost, D.H. Lindsley, and SK Banerjee and jointly sponsored by the Mineralogical Society of America and the American Geophysical Union.It has been fourteen and a half years since the last MSA Short Course on Oxide Minerals and the appearance of Volume 3 of Reviews in Mineralogy. Much progress has been made in the interim. This is particularly evident in the coverage of the thermodynamic properties of oxide minerals: nothing in Volume 3, while in contrast, Volume 25 has three chapters (6, 7, and 8) presenting various aspects of the thermodynamics of oxide minerals; and other chapters (9, 11, 12) build extensively on thermodynamic models. The coverage of magnetic properties has also been considerably expanded (Chapters 4, 8, and 14). Finally, the interaction of oxides and silicates is emphasized in Chapters 9, 11, 12, 13, and 14. Because Volume 3 is out of print and will not be readily available to newcomers to our science, as much as possible we have tried to make Volume 25 a replacement for, rather than a supplement to, the earlier volume. Chapters on crystal chemistry, phase equilibria, and oxide minerals in both igneous and metamorphic rocks have been rewritten or extensively revised.

Volume 26 of Reviews in Mineralogy provides a multidisciplinary review of our current knowledge of contact metamorphism. As in any field of endeavor, we are provided with new questions, thereby dictating future directions of study. Hopefully, this volume will provide inspiration and direction for future research on contact metamorphism.The Mineralogical Society of America sponsored the short course on Contact Metamorphism, October 17-19, 1991, at the Pala Mesa Resort, Fallbrook, California, prior to its annual meeting with the Geological Society of America.

Volume 27 of Reviews in Mineralogy provides a background to the TEM as a mineralogical tool, to give an introduction to the principles underlying its operation, and to explore mineralogical applications and ways in which electron microscopy can augment our knowledge of mineral structures, chemistry, and origin. Much time will be devoted to mineralogical applications. It provides sufficient information to allow mineralogists and petrologists to have an informed understanding of the data produced by transmission electron microscopy and to have enough knowledge and experience to undertake initial studies on their own. The opening chapters cover the principles of electron microscopy and chemical analysis using the TEM; while the following chapters consider mineralogical, petrological, and geochemical applications and their implications, for both low- and high-temperature geological environments.

The Mineralogical Society of America sponsored a short courses in conjunction with their annual meetings with the Geological Society of America, and this volume represents the proceedings of the eighteenth in the sequence. This TEM course was convened October 23-25, 1992, at Hueston Woods State Park, College Comer, Ohio.