Solution Thermodynamics and Its Application to Aqueous Solutions

A Differential Approach

AvYoshikata Koga

Häftad, Engelska, 2017

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Beskrivning

Solution Thermodynamics and its Application to Aqueous Solutions: A Differential Approach, Second Edition introduces a differential approach to solution thermodynamics, applying it to the study of aqueous solutions. This valuable approach reveals the molecular processes in solutions in greater depth than that gained by spectroscopic and other methods.

The book clarifies what a hydrophobe, or a hydrophile, and in turn, an amphiphile, does to H_{2O. By applying the same methodology to ions that have been ranked by the Hofmeister series, the author shows that the kosmotropes are either hydrophobes or hydration centers, and that chaotropes are hydrophiles. This unique approach and important updates make the new edition a must-have reference for those active in solution chemistry.}

Unique differential approach to solution thermodynamics allows for experimental evaluation of the intermolecular interaction
Incorporates research findings from over 40 articles published since the previous edition
Numerical or graphical evaluation and direct experimental determination of third derivatives, enthalpic and volumetric AL-AL interactions and amphiphiles are new to this edition
Features new chapters on spectroscopic study in aqueous solutions as well as environmentally friendly and hostile water aqueous solutions

Produktinformation

Utgivningsdatum:2017-03-28
Mått:152 x 229 x 42 mm
Vikt:720 g
Format:Häftad
Språk:Engelska
Antal sidor:444
Upplaga:2
Förlag:Elsevier Science
ISBN:9780444636294

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Mer om författaren

Dr. Koga's group introduced a new approach to the thermodynamic studies of aqueous solutions. They devised methods of measuring various thermodynamic quantities differentially. These methods allow them to experimentally evaluate the intermolecular interaction, the key quantity in the so-called "many-body problem. The group has started applying this new methodology to aqueous solutions of biopolymers. As a recognition of his contribution to solution thermodynamics, he was awarded the Society Award by The Japan Society of Calorimetry and Thermal Analysis in 2006. In 2011, he obtained for the first time in the world a fourth derivative of Gibbs energy and named it "Acceleration of the effect of solute on entropy-volume cross fluctuation density."

Innehållsförteckning

Part A: A Differential Approach in Solution ThermodynamicsI: Basics of Thermodynamics - Derivatives of Gibbs Energy, GII: Solution Thermodynamics - Use of the Second and Third Derivatives of GIII: Determination of the Second and Third Derivatives of GIV: Fluctuation and Partial Molar Fluctuation - Understanding H2OPart B: Studies of Aqueous Solutions Using the Second, the Third, and the Fourth Derivatives of GV: Mixing Schemes in Aqueous Mono-olsVI: Mixing Schemes in Aqueous Solutions of NonelectrolytesVII: Effects of Nonelectrolytes on the Molecular Organization of H2O - 1-Propanol (1P) Probing MethodologyVIII: Effects of Ions on the Molecular Organization of H2O - 1-Propanol (1P)-Probing MethodologyIX: Interactions in Ternary Aqueous Solutions - General TreatmentX: Differential Approach Applied to Spectroscopic Studies on Aqueous SolutionsXI: The Koga Line - Boundary Between Environmentally Friendly and Hostile Water and Aqueous SolutionsXII: In Closing - Executive Summary of the Effect of Solute on H2O