Transition Metal Hydrides

Inbunden, Engelska, 1991

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Beskrivning

Internationally renowned authors review recent advances in the understanding of the structure and reactivity of transition metal hydrides. This up-to-date analysis of transition metal hydrides examines the recent upsurge of experimental studies devoted to transition metal hydrides in both gas phase and solution. It also explores the recent emergence of new refinements in the methodologies and techniques used to delineate reaction mechanisms in solution.

Produktinformation

Utgivningsdatum:1991-12-06
Mått:162 x 243 x 28 mm
Vikt:730 g
Format:Inbunden
Språk:Engelska
Antal sidor:412
Förlag:John Wiley & Sons Inc
ISBN:9780471187684

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Mer om författaren

A. Dedieu is the author of Transition Metal Hydrides, published by Wiley.

Innehållsförteckning

1. Introduction to Transition Metal Hydrides What is a Transition Metal Hydride?Importance of Transition Metal Hydrides in CatalysisTheoretical Approaches to Studying Metal Hydrides (DFT, MO Theory)2. Electronic Structure and BondingMetal-Hydrogen Bond CharacterBack-Donation and its Influence on StabilityFactors Affecting Hydride Stability (Metal Oxidation State, Ligand Effects)3. Structural Features of Transition Metal HydridesCoordination Geometry and Hydride PositionX-ray Crystallography and Neutron Diffraction StudiesSpectroscopic Characterization (NMR, IR)4. Formation of Transition Metal Hydrides Oxidative Addition of H2, Heterolytic Cleavage of H2, and Protonation of a Metal Complex.5. Reactivity of Transition Metal HydridesInsertion Reactions (CO, Olefins)Reductive EliminationHydrogen Transfer ReactionsBeta-Hydride Elimination6. Catalytic Applications of Transition Metal HydridesHydrogenation Reactions (Alkenes, Alkynes, Carbonyl Compounds)HydrosilylationHydroborationAsymmetric Catalysis7. Selected Case Studies The Wilkins on Catalyst (Rh-based), The Crabtree Catalyst (Ir-based), and Metal Hydrides in Polymerization Reactions.8. Recent Advances and Future Directions Computational Modeling of Hydride Reactivity, Development of New Catalysts for Hydrogen Storage, and Biomimetic Hydride Transfer Systems.