Two-Dimensional Correlation Spectroscopy

Isao Noda, Proctor and Gamble Company, Ohio, USA. Yukihiro Ozaki, Kwansei Gakuin University, Japan.

• Preface xiAcknowledgements xiii1 Introduction 11.1 Two-dimensional Spectroscopy 11.2 Overview of the Field 31.3 Generalized Two-dimensional Correlation 61.4 Heterospectral Correlation 91.5 Universal Applicability 102 Principle of Two-dimensional Correlation Spectroscopy 152.1 Two-dimensional Correlation Spectroscopy 152.2 Generalized Two-dimensional Correlation 172.3 Properties of 2D Correlation Spectra 202.4 Analytical Expressions for Certain 2D Spectra 242.5 Cross-correlation Analysis and 2D Spectroscopy 313 Practical Computation of Two-dimensional Correlation Spectra 393.1 Computation of 2D Spectra from Discrete Data 393.2 Unevenly Spaced Data 413.3 Disrelation Spectrum 433.4 Computational Efficiency 434 Generalized Two-dimensional Correlation Spectroscopy in Practice 474.1 Practical Example 474.2 Pretreatment of Data 524.3 Features Arising from Factors other than Band Intensity Changes 565 Further Expansion of Generalized Two-dimensional Correlation Spectroscopy – Sample–Sample Correlation and Hybrid Correlation 655.1 Sample–Sample Correlation Spectroscopy 655.2 Hybrid 2D Correlation Spectroscopy 725.3 Additional Remarks 746 Additional Developments in Two-dimensional Correlation Spectroscopy – Statistical Treatments, Global Phase Maps, and Chemometrics 776.1 Classical Statistical Treatments and 2D Spectroscopy 776.2 Global 2D Phase Maps 816.3 Chemometrics and 2D Correlation Spectroscopy 867 Other Types of Two-dimensional Spectroscopy 957.1 Nonlinear Optical 2D Spectroscopy 967.2 Statistical 2D Correlation Spectroscopy 997.3 Other Developments in 2D Correlation Spectroscopy 1108 Dynamic Two-dimensional Correlation Spectroscopy Based on Periodic Perturbations 1158.1 Dynamic 2D IR Spectroscopy 1158.2 Dynamic 2D IR Dichroism Spectra of Polymers 1218.3 Repetitive Perturbations Beyond DIRLD 1539 Applications of Two-dimensional Correlation Spectroscopy to Basic Molecules 1699.1 2D IR Study of the Dissociation of Hydrogen-bonded N-Methylacetamide 1709.2 2D NIR Sample–Sample Correlation Study of Phase Transitions of Oleic Acid 1749.3 2D NIR Correlation Spectroscopy Study of Water 1769.4 2D Fluorescence Study of Polynuclear Aromatic Hydrocarbons 17910 Generalized Two-dimensional Correlation Studies of Polymers and Liquid Crystals 18710.1 Temperature and Pressure Effects on Polyethylene 18710.2 Reorientation of Nematic Liquid Crystals by an Electric Field 19510.3 Temperature-dependent 2D NIR of Amorphous Polyamide 19910.4 Composition-based 2D Raman Study of EVA Copolymers 20310.5 Polarization Angle-dependent 2D IR Study of Ferroelectric Liquid Crystals 20911 Two-dimensional Correlation Spectroscopy and Chemical Reactions 21711.1 2D ATR/IR Study of Bis(hydroxyethyl terephthalate) Oligomerization 21711.2 Hydrogen–Deuterium Exchange of Human Serum Albumin 22212 Protein Research by Two-dimensional Correlation Spectroscopy 23112.1 Adsorption and Concentration-dependent 2D ATR/IR Study of β-Lactoglobulin 23212.2 pH-dependent 2D ATR/IR Study of Human Serum Albumin 23612.3 Aggregation of Lipid-bound Cytochrome c 24113 Applications of Two-dimensional Correlation Spectroscopy to Biological and Biomedical Sciences 24513.1 2D NIR Study of Milk 24613.2 2D IR Study of Synthetic and Biological Apatites 25113.3 Identification and Quality Control of Traditional Chinese Medicines 25314 Application of Heterospectral Correlation Analysis 25714.1 Correlation between different Spectral Measurements 25714.2 SAXS/IR Dichroism Correlation Study of Block Copolymer 25814.3 Raman/NIR Correlation Study of Partially Miscible Blends 26014.4 ATR/IR–NIR Correlation Study of BIS(hydroxyethyl terephthalate) Oligomerization 26214.5 XAS/Raman Correlation Study of Electrochemical Reaction of Lithium with CoO 26415 Extension of Two-dimensional Correlation Analysis to Other Fields 27115.1 Applications of 2D Correlation beyond Optical Spectroscopy 27115.2 2D Correlation Gel Permeation Chromatography (GPC) 27115.3 2D Mass Spectrometry 28115.4 Other Unusual Applications of 2D Correlation Analysis 28215.5 Return to 2D NMR Spectroscopy 28315.6 Future Developments 288Index 291