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    1. Naturvetenskap och teknik
    2. Matematik och naturvetenskap
    3. Kemi

    Handbook of High Field Dynamic Nuclear Polarization

    AvVladimir K. Michaelis,Robert G. Griffin

    Inbunden, Engelska, 2020

    Del i serien eMagRes Books

    1 629 kr

    Beställningsvara. Skickas inom 11-20 vardagar. Fri frakt över 249 kr.

    Beskrivning

    Addresses Dynamic Nuclear Polarization (DNP) as a technique for sensitivity-enhancement in solid-state NMR spectroscopyThis comprehensive handbook is a compendium of the current state-of-the art of high field Dynamic Nuclear Polarization—from long-proven, early developments, up to today’s hot topics. It covers all the relevant subjects that have made a direct or indirect contribution toward advancing this field, and focuses on topics such as: the theory behind the effects seen within DNP; instrumentation required for carrying out DNP; and specific applications of DNP including protein monitoring, catalysis, nanoparticles, biological and clinical studies. Development and application of techniques that have indirectly contributed to advancing MAS DNP NMR, such as DNP experiments on static solids within microwave resonant structures, and high-field EPR, are also examined.Handbook of High Field Dynamic Nuclear Polarization is presented in three sections—Theoretical Aspects, DNP Development (instrumentation / radical / sample), and DNP NMR Applications. The first section offers chapters on; solid and cross effect DNP; thermal mixing; Overhauser; and dissolution DNP. The second looks at: microwave technology, gyrotron, and IOE; homebuilt and commercial DNP spectrometers; and glassing vs. solvent-free DNP. The final section provides information on; amyloid, membrane, and nanocrystalline proteins; metals, and surface enhanced DNP; pharmaceuticals; nanoparticles; and much more.  Covers one of the biggest developing fields in magnetic resonanceRelevant to students, academics, and industry within the physical, materials, medical, and biochemical sciencesAn excellent starting point and point-of-reference for researchers in the fieldEdited by a widely respected team with contributions from key researchers in the NMR communityPart of the eMagRes Handbook SeriesHandbook of High Field Dynamic Nuclear Polarization is an ideal reference for all researchers and graduate students involved in this complex, interdisciplinary field.About eMagRes Handbooks eMagRes publishes a wide range of online articles on all aspects of magnetic resonance in physics, chemistry, biology and medicine. The existence of this large number of articles, written by experts in various fields, is enabling the publication of a series of eMagRes Handbooks on specific areas of NMR and MRI. The chapters of each of these handbooks will comprise a carefully chosen selection of eMagRes articles. In consultation with the eMagRes Editorial Board, the eMagRes Handbooks are coherently planned in advance by specially-selected Editors, and new articles are written to give appropriate complete coverage. The handbooks are intended to be of value and interest to research students, postdoctoral fellows and other researchers learning about the scientific area in question and undertaking relevant experiments, whether in academia or industry.Have the content of this Handbook and the complete content of eMagRes at your fingertips!Visit: www.wileyonlinelibrary.com/ref/eMagRes

    Produktinformation

    • Utgivningsdatum:2020-01-30
    • Mått:193 x 249 x 28 mm
    • Vikt:1 179 g
    • Format:Inbunden
    • Språk:Engelska
    • Serie:eMagRes Books
    • Antal sidor:472
    • Förlag:John Wiley & Sons Inc
    • ISBN:9781119441649

    Utforska kategorier

    • Kemi inom Naturvetenskap och teknik

    Mer om författaren

    Editors Vladimir K. Michaelis is Assistant Professor in the Department of Chemistry at the University of Alberta. Robert G. Griffin is Professor of Chemistry and Director of the Francis Bitter Magnet Laboratory at the Massachusetts Institute of Technology. Björn Corzilius is Professor of Physical Chemistry in the Institute of Chemistry at the University of Rostock. Shimon Vega is Professor in the Department of Chemical Physics at the Weizmann Institute of Science, Israel.

    Innehållsförteckning

    • Contributors xiSeries Preface xviiPreface xixAcknowledgments xxiPart A: Concepts, Theory, & Instrumentation 11 The Discovery and Demonstration of Dynamic Nuclear Polarization–A Personal and Historical Account 3Charles P. Slichter2 DNP Mechanisms 15Krishnendu Kundu, Frédéric Mentink-Vigier, Akiva Feintuch, and Shimon Vega3 Pulsed Dynamic Nuclear Polarization 71Kong Ooi Tan, Sudheer Jawla, Richard J. Temkin, and Robert G. Griffin4 MAS-DNP Enhancements: Hyperpolarization, Depolarization, and Absolute Sensitivity 87Sabine Hediger, Daniel Lee, Frédéric Mentink-Vigier, and Gaël De Paëpe5 Polarizing Agents: Evolution and Outlook in Free Radical Development for DNP 103Gilles Casano, Hakim Karoui, and Olivier Ouari6 Paramagnetic Metal Ions for Dynamic Nuclear Polarization 121Björn Corzilius7 Instrumentation for High-field Dynamic Nuclear Polarization NMR Spectroscopy 143Guy M. Bernard and Vladimir K. Michaelis8 Millimeter-wave Sources for DNP-NMR 155Monica Blank and Kevin L. Felch9 Cryogenic Platforms and Optimized DNP Sensitivity 169Yoh Matsuki and Toshimichi Fujiwara10 Versatile Dynamic Nuclear Polarization Hardware with Integrated Electron Paramagnetic Resonance Capabilities 189Alisa Leavesley, Ilia Kaminker, and Songi Han11 Dissolution Dynamic Nuclear Polarization Methodology and Instrumentation 219Dennis Kurzbach and Sami Jannin12 Introduction to Dissolution DNP: Overview, Instrumentation, and Human Applications 239Jan H. Ardenkjaer-Larsen13 Liquid-state Overhauser DNP at High Magnetic Fields 261Vasyl P. Denysenkov and Thomas F. Prisner14 Overhauser DNP in Liquids on 13C Nuclei 279Marina Bennati and Tomas OrlandoPart B: Applications 28915 DNP and Cellular Solid-state NMR 291Alessandra Lucini Paioni, Marie A.M. Renault, and Marc Baldus16 Cryo-trapped Intermediates of Retinal Proteins Studied by DNP-enhanced MAS NMR Spectroscopy 305Johanna Becker-Baldus and Clemens Glaubitz17 DNP Solid-state NMR of Biological Membranes 323Burkhard Bechinger18 DNP in Materials Science: Touching the Surface 337Pierrick Berruyer, Lyndon Emsley, and Anne Lesage19 Growing Signals from the Noise: Challenging Nuclei in Materials DNP 353Frédéric A. Perras, Takeshi Kobayashi, and Marek Pruski20 DNP-enhanced Solid-state NMR Spectroscopy of Active Pharmaceutical Ingredients 373Li Zhao, Arthur C. Pinon, Lyndon Emsley, and Aaron J. Rossini21 In Vivo Hyperpolarized 13C MRS and MRI Applications 405Irene Marco-Rius and Arnaud Comment22 Dissolution Dynamic Nuclear Polarization 421Walter KöckenbergerIndex 435