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      1. Naturvetenskap och teknik
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      Metal-Fluorocarbon Based Energetic Materials

      AvErnst-Christian Koch

      Inbunden, Engelska, 2012

      1 693 kr

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      2 525 kr

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      Beskrivning

      Metal-Fluorocarbon Based Energetic Materials This exciting new book details all aspects of a major class of pyrolants and elucidates the progress that has been made in the field, covering both the chemistry and applications of these compounds.Written by a pre-eminent authority on the subject from the NATO Munitions Safety Information Analysis Center (MSIAC), it begins with a historical overview of the development of these materials, followed by a thorough discussion of their ignition, combustion and radiative properties. The next section explores the multiple facets of their military and civilian applications, as well as industrial synthetic techniques. The critical importance of the associated hazards, namely sensitivity, stability and aging, are discussed in detail, and the book is rounded off by an examination of the future of this vital and expanding field.The result is a complete guide to the chemistry, manufacture, applications and required safety precautions of pyrolants for both the military and chemical industries.From the preface:“... This book fills a void in the collection of pyrotechnic literature... it will make an excellent reference book that all researchers of pyrolants and energetics must have...” Dr. Bernard E. Douda, Dr. Sara Pliskin, NAVSEA Crane, IN, USA

      Produktinformation

      • Utgivningsdatum:2012-01-25
      • Mått:175 x 249 x 22 mm
      • Vikt:816 g
      • Format:Inbunden
      • Språk:Engelska
      • Antal sidor:360
      • Förlag:Wiley-VCH Verlag GmbH
      • ISBN:9783527329205

      Utforska kategorier

      • Övrig teknik och tillämpad vetenskap inom Naturvetenskap och teknik
      • Tillverkningsteknik inom Naturvetenskap och teknik

      Mer om författaren

      Dr. Ernst-Christian Koch is Technical Specialist Officer at the NATO Munitions Safety Information Center (MSIAC), Brussels, Belgium. He studied chemistry at the Technical University of Kaiserslautern, Germany and was awarded his doctoral degree by the same university in 1995. Before joining NATO in 2008, Dr. Koch spent 12 years working as a scientist for the German defense industry, developing energetic mate-rials and countermeasures. He is author of more than 20 peer reviewed papers and two book chapters. He holds more than 100 patents on energetic materials and countermeasures. Dr. Koch is a Lecturer on Energetic Materials at Technical University of Kaiserslautern/Germany and Pardubice Univer-sity/Czech Republic and he currently serves as Vice President of the International Pyrotechnics Society and as an Editorial Board Member of Propellants Explosives Pyrotechnics.

      Innehållsförteckning

      • Foreword xiiiPreface xvAcknowledgment xvii1 Introduction to Pyrolants 1References 32 History 62.1 Organometallic Beginning 62.2 Explosive & Obscurant Properties 82.3 Rise of Fluorocarbons 102.4 Rockets Fired Against Aircraft 132.5 Metal/Fluorocarbon Pyrolants 15References 17Further Reading 193 Properties of Fluorocarbons 203.1 Polytetrafluoroethylene (PTFE) 203.2 Polychlorotrifluoroethylene (PCTFE) 223.3 Polyvinylidene Fluoride (PVDF) 243.4 Polycarbon Monofluoride (PMF) 253.5 Vinylidene Fluoride–Hexafluoropropene Copolymer 273.5.1 LFC-1 283.6 Vinylidene Fluoride–Chlorotrifluoroethylene Copolymer 283.7 Copolymer of TFE and VDF 303.8 Terpolymers of TFE, HFP and VDF 313.9 Summary of chemical and physical properties of common fluoropolymers 33References 334 Thermochemical and Physical Properties of Metals and their Fluorides 36References 415 Reactivity and Thermochemistry of Selected Metal/Fluorocarbon Systems 425.1 Lithium 425.2 Magnesium 455.3 Titanium 475.4 Zirconium 525.5 Hafnium 535.6 Niob 535.7 Tantalum 545.8 Zinc 555.9 Cadmium 565.10 Boron 575.11 Aluminium 595.12 Silicon 635.13 Calcium Silicide 645.14 Tin 65References 666 Ignition and Combustion Mechanism of MTV 686.1 Ignition and Pre-Ignition of Metal/Fluorocarbon Pyrolants 686.2 Magnesium–Grignard Hypothesis 68References 777 Ignition of MTV 80References 858 Combustion 878.1 Magnesium/Teflon/Viton 878.2 Porosity 958.3 Burn Rate Description 968.4 Combustion of Metal–Fluorocarbon Pyrolants with Fuels Other than Magnesium 978.5 Underwater Combustion 114References 1159 Spectroscopy 1199.1 Introduction 1199.2 UV–VIS Spectra 1209.3 MWIR Spectra 1359.4 Temperature Determination 141References 14810 Infrared Emitters 15110.1 Decoy Flares 15110.2 Nonexpendable Flares 15310.3 Metal–Fluorocarbon Flare Combustion Flames as Sources of Radiation 15810.4 Infrared Compositions 16510.5 Operational Effects 18410.6 Outlook 191References 19311 Obscurants 19711.1 Introduction 19711.2 Metal–Fluorocarbon Reactions in Aerosol Generation 199References 20812 Igniters 210References 21413 Incendiaries, Agent Defeat, Reactive Fragments and Detonation Phenomena 21613.1 Incendiaries 21613.2 Curable Fluorocarbon Resin–Based Compositions 21713.3 Document Destruction 21813.4 Agent Defeat 22113.5 Reactive Fragments 22313.6 Shockwave Loading of Metal–Fluorocarbons and Detonation-Like Phenomena 229References 232Further Reading 23414 Miscellaneous Applications 23514.1 Submerged Applications 23514.2 Mine-Disposal Torch 23814.3 Stored Chemical Energy 24014.4 Tracers 24014.5 Propellants 241References 24415 Self-Propagating High-Temperature Synthesis 24715.1 Introduction 24715.2 Magnesium 24915.3 Silicon and Silicides 252References 25616 Vapour-Deposited Materials 258References 26217 Ageing 264References 27018 Manufacture 27118.1 Introduction 27118.2 Treatment of Metal Powder 27118.3 Mixing 27318.4 Pressing 28618.5 Cutting 28918.6 Priming 28918.7 Miscellaneous 28918.8 Accidents and Process Safety 290References 29619 Sensitivity 29919.1 Introduction 29919.2 Impact Sensitivity 30019.3 Friction and Shear Sensitivity 30119.3.1 Metal/Fluorocarbon 30319.4 Thermal Sensitivity 30419.4.1 MTV 30419.5 ESD Sensitivity 30519.6 Insensitive Munitions Testing 31019.7 Hazards Posed by Loose In-Process MTV Crumb and TNT Equivalent 321References 32320 Toxic Combustion Products 32620.1 MTV Flare Composition 32620.2 Obscurant Formulations 33020.3 Fluorine Compounds 331References 33221 Outlook 334References 335Index 337
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