Sodium-Ion Batteries

Energy Storage Materials and Technologies

Inbunden, Engelska, 2022

2 183 kr

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Beskrivning

Sodium-Ion Batteries An essential resource with coverage of up-to-date research on sodium-ion battery technology Lithium-ion batteries form the heart of many of the stored energy devices used by people all across the world. However, global lithium reserves are dwindling, and a new technology is needed to ensure a shortfall in supply does not result in disruptions to our ability to manufacture reliable, efficient batteries. In Sodium-Ion Batteries: Energy Storage Materials and Technologies, eminent researcher and materials scientist Yan Yu delivers a comprehensive overview of the state-of-the-art in sodium-ion batteries (SIBs), including their design principles, cathode and anode materials, electrolytes, and binders. The author discusses high-performance rechargeable sodium-ion battery technology in the contexts of energy, power density, and electrochemical stability for commercialization. Exploring a wide range of literature on the recent progress made by researchers on sodium-ion battery technology, the book provides valuable perspectives on designing better materials for SIBs to unlock their practical capabilities. A thorough introduction to sodium-ion batteries, including their key materials and likely future developmentsComprehensive explorations of design principles of electrode materials and electrolytes for sodium-ion batteriesPractical discussions of cathode materials for sodium-ion batteries, including transition metal oxides, polyanionic compounds, Prussian blue analogues and organic compoundsIn-depth examinations of anode materials for sodium-ion batteries, including carbon-based materials, metal chalcogenides, metal alloys, phosphorus and Na metal anodesPerfect for materials scientists, inorganic chemists, electrochemists, and physical chemists, Sodium-Ion Batteries: Energy Storage Materials and Technologies will also earn a place in the libraries of catalytic and polymer chemists.

Produktinformation

Utgivningsdatum:2022-03-23
Mått:170 x 244 x 32 mm
Vikt:1 162 g
Format:Inbunden
Språk:Engelska
Antal sidor:560
Förlag:Wiley-VCH Verlag GmbH
ISBN:9783527348961

Utforska kategorier

Mer om författaren

Yan Yu, PhD is Full Professor of Material Science at the University of Science and Technology of China. Her research is focused on the design of novel nanomaterials for clean energy, especially for batteries and the fundamental science of energy storage systems.

Innehållsförteckning

Foreword xiiiPreface xv1 Introduction to Sodium-Ion Batteries 11.1 Brief Outline 11.2 Key Materials 41.3 Toward Future Development 13References 142 Design Principles for Sodium-Ion Batteries 172.1 Introduction 172.2 Basic Design Principles 182.2.1 Energy Density 182.2.2 Power Density 202.2.3 Cycling Life 202.2.4 Safety 212.2.5 Cost 212.3 Design Principles for Electrode Materials 222.3.1 Transport Properties 222.3.2 Size Effects 262.3.3 Morphology and Structure 282.4 Design Principles for Electrolytes 332.4.1 Transport Properties 332.4.2 Electrochemical Stability Window 352.4.3 Thermal Stability 362.4.4 Interfacial Compatibility 372.4.5 Safety Issues 372.5 Conclusions 38References 383 Transition Metal Oxide Cathodes for Sodium-Ion Batteries 413.1 Introduction 413.2 Sodium-free Transition Metal Oxides 433.2.1 Vanadium Oxides 433.2.2 Manganese Dioxides 473.3 Sodium-inserted Layered Metal Oxides 483.3.1 NaFeO2 513.3.2 NaxCoO2 543.3.3 NaxMnO2 553.3.4 NaxNiO2 613.3.5 NaxVO2 653.3.6 NaxCrO2 663.3.7 Mixed Cation Oxides 693.3.8 Other Emerging Metal Oxides 703.4 Concluding Remarks 72References 734 Polyanion-Type Cathodes for Sodium-Ion Batteries 794.1 Introduction 794.2 Phosphates 804.2.1 NaMPO4 (M = Fe and Mn) 804.2.2 NASICON-Type Phosphates 834.2.2.1 NASIClON-type Na3V2(PO4)3 834.2.2.2 NASICON-type Na3MnTi(PO4)3 894.3 Pyrophosphates 904.3.1 NaMP2O7 (M = Fe, V, and Ti) 914.3.2 Na2MP2O7 (M = Co, Fe, Mn, Cu, and Zn) 934.3.3 Na4M3(PO4)2P2O7 (M = Fe, Co, Mn, Ni, and Mg) 984.3.4 Other Pyrophosphates 1024.4 Fluorinated Phosphate Cathodes 1054.4.1 NaVPO4F 1054.4.2 Na2MPO4F (M = Fe, Mn, and Ni) 1074.4.3 Na3(VO1−xPO4)2F1+2x (0≤ x ≤1) 1104.5 Sulfates 1164.5.1 NaxFey(SO4)z 1164.5.2 Fluorosulfates 1194.6 Silicates 1194.7 Other Polyanion-Type Compounds 1214.8 Concluding Remarks 125References 1265 Prussian Blue Analogue Cathodes for Sodium-Ion Batteries 1375.1 Introduction 1375.2 Crystal Structure 1385.3 Electrochemistry Mechanisms 1425.4 Preparation Approaches 1445.4.1 Coprecipitation 1455.4.2 Self-decomposition of Precursors 1475.5 Optimizing Electrochemical Performance 1485.5.1 Effect of Lattice Architecture on Electrochemistry 1495.5.1.1 Substitution of Cation 1495.5.1.2 Inserting Cation 1505.5.1.3 Vacancy 1515.5.1.4 Water Molecules 1515.5.2 Effect of Morphological Optimizations on Electrochemistry 1525.5.3 NaxMFe-PBAs with Two Na+ Insertion Sites 1545.5.4 NaxMFe-PBAs with One Na+ Insertion Sites 1555.6 Concluding Remarks 156References 1576 Organic Cathodes for Sodium-Ion Batteries 1616.1 Introduction 1616.2 C=O Reaction 1636.2.1 Quinones 1646.2.2 Carboxylates 1736.2.3 Anhydrides 1756.2.4 Amides 1776.3 Doping Reaction 1816.3.1 Conductive Polymers 1826.3.2 Organic Radical Compounds 1886.3.3 Microporous Polymers 1926.4 C=N Reaction 1946.4.1 Schiff Base Organic Compounds 1946.4.2 Pteridine Derivatives 1966.5 Concluding Remarks 197References 1987 Intercalation-Type Anode Materials for Sodium-Ion Batteries 2037.1 Introduction 2037.2 Carbon-Based Anode Materials 2037.2.1 Graphite Anode 2047.2.2 Hard Carbon Anode 2057.2.3 Soft Carbon Anode 2107.3 Titanium-Based Anode Materials 2117.3.1 TiO2 2127.3.1.1 Amorphous TiO2 2127.3.1.2 Anatase TiO2 2137.3.1.3 TiO2-B 2147.3.1.4 Rutile TiO2 2167.3.2 Li4Ti5O12 2187.3.3 Na2Ti3O7 2217.3.3.1 Surface Modifications 2247.3.3.2 Micro-Nano Structure Design 2247.3.3.3 Self-Supported Electrode Design 2257.3.3.4 Anion Doping 2287.3.3.5 Cation Doping 2307.3.4 NaTi2(PO4)3 2317.3.4.1 Structure and Properties of NaTi2(PO4)3 2317.3.4.2 Modification Strategies of NaTi2(PO4)3 2327.3.5 TiNb2O7 2377.3.5.1 Structure and Properties of TiNb2O7 2377.3.5.2 Modification Strategies of TiNb2O7 2377.4 Concluding Remarks 239References 2398 Phosphorus/Phosphide Anodes for Sodium–Ion Batteries on Alloy and Conversion Reactions 2458.1 Introduction 2458.2 Phosphorus Anodes 2468.2.1 Phosphorus Allotropes 2468.2.2 Na-Storage Mechanism for Phosphorus-Based Materials 2498.2.2.1 Na-Storage Mechanism for Red Phosphorus 2498.2.2.2 Na-Storage Mechanism for Black Phosphorus 2508.2.3 Phosphorus-Based Materials for Na–Ion Batteries 2538.2.3.1 Red Phosphorus for Na–Ion Batteries 2538.2.3.2 Black Phosphorus and Phosphorene for Na-Ion Batteries 2588.3 Metal Phosphide Anodes 2618.3.1 Na-Storage Mechanism for Metal Phosphides 2618.3.2 Metal Phosphides for Na-Ion Batteries 2628.3.2.1 Tin Phosphide Materials 2628.3.2.2 Cobalt Phosphide Materials 2658.3.2.3 Iron Phosphide Materials 2668.3.2.4 Nickel Phosphide Materials 2678.3.2.5 Copper Phosphide Materials 2688.4 Concluding Remarks 269References 2709 Metal Oxides/Chalcogenides/Alloys for Sodium-Ion Batteries on Alloy and Conversion Reactions 2739.1 Introduction 2739.2 Metal Oxides 2739.2.1 Conversion-type Oxides 2739.2.2 Conversion-alloy-type Oxides 2779.3 Metal Chalcogenides 2789.3.1 Metal Sulfides 2789.3.1.1 SnS/SnS2 2799.3.1.2 Sb2S3/Bi2S3 2819.3.1.3 MoS2/WS2 2829.3.1.4 FeSx/CoSx/NiSx 2839.3.1.5 Other Monometal Sulfides Including CuSx/VSx/TiS2 2869.3.1.6 Bimetallic Sulfides 2889.3.2 Metal Selenides 2909.3.2.1 SnSe/SnSe2 2919.3.2.2 Sb2Se3/Bi2Se3 2919.3.2.3 MoSe2/WSe2 2929.3.2.4 FeSex/CoSe2/NiSe2 2939.3.2.5 Other Monometal Selenides 2959.3.2.6 Bimetallic Selenides 2969.3.3 Metal Tellurides 2989.4 Metal Alloys 2999.4.1 Tin (Sn) 2999.4.2 Antimony (Sb) 3029.4.3 Bismuth (Bi) 3049.4.4 Intermetallic Compounds 307References 30910 Effective Strategies to Restrain Dendrite Growth of Na Metal Anodes 31510.1 Introduction 31510.2 Liquid Electrolyte Optimization for Na Metal Anodes 31610.2.1 Traditional Electrolyte 31610.2.2 High-concentration Electrolyte 31910.2.3 Ionic Liquids 32210.3 Construction of Novel Current Collectors for Na Metal Anodes 32310.3.1 Metallic Current Collectors 32310.3.2 Carbon-Based Current Collectors 32410.3.3 3D Scaffolds/Na Metal 32510.4 Alloy-Based Na Metal Anodes 32710.4.1 Alkali-metal Alloys 32710.4.2 Other Metals/Na Alloys 33210.5 Conclusions 335References 33511 Organic Liquid Electrolytes for Sodium-Ion Batteries 33911.1 Introduction 33911.2 Electrolyte Properties 33911.3 Sodium Salts 34011.4 Solvents 34611.4.1 Carbonate Ester-Based Electrolytes 34611.4.2 Carboxylate Ester-Based Electrolytes 34711.4.3 Ether-Based Electrolytes 35211.5 Functional Additives 35811.5.1 Basic Characteristics of Additives 35811.5.2 Additives for Na-Ion Batteries 35911.5.2.1 SEI-Forming Additives for Anodes 36011.5.2.2 CEI-Forming Additives for Cathodes 36311.5.3 Additives for Na Metal 36511.5.4 Safety Inspired Additives 36911.6 Novel Concentration Electrolyte Systems 37211.6.1 High-Concentration Electrolytes 37211.6.2 Local High-Concentration Electrolytes 37311.6.3 Low-Concentration Electrolytes 37611.7 Concluding Remarks 377References 37812 Ionic Liquid Electrolytes for Sodium-Ion Batteries 38312.1 Introduction 38312.2 The Cationic Species in Ionic Liquids 38412.3 The Anionic Species in Ionic Liquids 38512.4 Electrolyte Properties 38812.4.1 Physicochemical Properties 38812.4.2 Electrochemical Properties 38912.4.3 Thermal Properties 39112.5 Stability of Ionic Liquids 39212.5.1 Thermal and Electrochemical Stability 39212.5.2 Electrochemical Properties 39312.5.3 Electrolyte/Electrode Interfaces 39612.6 Concluding Remarks 398References 39913 Solid-State and Gel Electrolytes for Sodium-Ion Batteries 40113.1 Introduction 40113.2 Electrolyte Characteristics 40113.2.1 Energy Density 40113.2.2 Ionic Conductivity 40313.2.3 Chemical Stability 40413.2.4 Mechanical Stability 40613.2.5 Thermal Stability 40613.3 Polymer Electrolytes 40613.3.1 Solid Polymer Electrolytes (SPEs) 40613.3.1.1 PEO-Based Electrolyte 40713.3.1.2 PVA-Based Electrolyte 41113.3.1.3 PAN-Based Electrolyte 41413.3.1.4 PVP-Based Electrolyte 41413.3.1.5 PVDF-Based Electrolyte 41413.3.2 Na Polymer Single-Ion Conductors 41513.3.3 Adding Ceramic Additives to Polymer Electrolytes 41713.3.4 Gel Polymer Electrolytes (GPEs) 42013.3.4.1 PMMA-Based GPE 42013.3.4.2 PVDF-Based GPE 42113.3.4.3 Nafion-Based GPE 42413.3.5 Adding Ceramic Filler to GPEs 42413.3.6 Cross-linked GPEs 42513.3.7 Ionic Liquid-Based GPEs 42513.4 Inorganic Solid-State Electrolytes 42713.4.1 Oxide-Based Solid-State Electrolytes 42713.4.1.1 Beta-Alumina 42713.4.1.2 NASICON 42913.4.2 Sulfide-Based Solid-State Electrolytes 43313.4.2.1 Na3PS4 43313.4.2.2 Na3SbS4 43913.4.2.3 Na10SnP2S12 44013.4.3 Complex Hydrides 44113.5 Concluding Remarks 443References 44414 Binders for Sodium-Ion Batteries 44914.1 Introduction 44914.2 Main Functions and Performance Requirements of Binders 45014.3 Polyvinylidene Fluoride (PVDF) 45314.3.1 Chemical Properties of PVDF 45314.3.2 Application of PVDF in Na-Ion Batteries 45414.4 Polyacrylic Acid (PAA) 45514.5 Carboxymethyl Cellulose (CMC) 45814.6 Styrene Butadiene Rubber (SBR) 46114.7 Other Binders 46214.7.1 Sodium Alginate (SA) 46214.7.2 Xanthan Gum (XG) 46314.7.3 Guar Gum (GG) 46314.7.4 Polyimide (PI) 46314.8 Concluding Remarks 464References 46415 Sodium-Ion Full Batteries 46715.1 Introduction 46715.2 Aqueous Sodium-Ion Full Batteries 46815.3 Nonaqueous Sodium-Ion Full Batteries 48215.3.1 Carbon-Anode-based Sodium-Ion Full Batteries 48315.3.2 Non-Carbon-Anode-based Sodium-Ion Full Batteries 48615.4 Solid-state Sodium-Ion Full Batteries 49315.4.1 Quasi-Solid-State Sodium-Ion Full Batteries 49315.4.2 All-Solid-state Sodium-Ion Full Batteries (ASSSIFBs) 49815.4.2.1 Polymer-Electrolyte-based ASSSIFBs 49815.4.2.2 Ceramic-Electrolyte-based ASSSIFBs 49815.4.2.3 Composite-Electrolyte-based ASSSIFBs 50315.4.2.4 New Types of ASSSIFBs 504References 50616 Perspectives for Sodium-Ion Batteries 509Index 519