Rong Cao, PhD, is Director of the Fujian Institute of Research on the Structure of Matter (FJIRM) and Director of the Institute of Urban Environment at the Chinese Academy of Sciences (CAS). He received his doctorate in Chemical Physics from the FJIRM, CAS. He is the recipient of multiple awards, including the China Youth Science and Technology Award and the National Candidate of New Century Talents Project in 2006.

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• Volume 11 Introduction 1Jian Zhang, Guo-Cong Guo, Rong Cao, and Xin-Tao Wu2 Coordination-Assembled Metal–Organic Macrocycles and Cages 9Xiao-Zhen Li, Yu-Ling Liang, Li-Peng Zhou, Li-Xuan Cai, Qiang-Yu Zhu, Zhuo Wang, Xiao-Qing Guo, Dan-Ni Yan, Shao-Jun Hu, Shao-Chuan Li, Shi-Yu Wu, Shi-Long Han, Ran Chen, Pei-Ming Cheng, Kai Cheng, Xiao-Shan Feng, Tian-Pu Sheng, Can He, Feng-Rong Dai, and Qing-Fu Sun2.1 Introduction 92.2 Metallacycles 92.3 Metallacages 352.4 Conclusion 77Acknowledgments 77References 773 Structural Chemistry of Metal-Oxo Clusters 81Xiaofeng Yi, Weihui Fang, Jinying Liu, Cheng Chen, Mingyan Wu, and Lei Zhang3.1 Oxo Clusters of Transition Metal 813.2 Oxo Clusters of Main Group Metal 1113.3 Oxo Clusters of Lanthanides 1223.4 Conclusion 149Acknowledgments 149References 1494 Synthetic Approaches, Structural Diversities, and Biological Aspects of Molybdenum (Tungsten)-Based Heterometallic Sulfide Clusters and Coordination Polymers 163Du Shaowu and Wu Xintao4.1 Introduction 1634.2 Synthesis of Mo–Fe–S Cuboidal Clusters for the Structural Modeling of the Iron–Molybdenum Cofactor(FeMoco) 1674.3 Rationally Designed Synthesis of Mo(W)–Cu(Ag)–S Clusters 1734.4 Rationally Designed Synthesis of W(Mo)–Ag–S Coordination Polymers 1824.5 Conclusion 190Acknowledgments 191References 1915 Group 11–15 Metal Chalcogenides 195Jian-Rong Li, Mei-Ling Feng, Bing Hu, and Xiao-Ying Huang5.1 Introduction 1955.2 Inorganic–Organic Hybrid Chalcogenides Based on II–VI Semiconductors 1985.3 Discrete Chalcogenide Clusters Synthesized in Ionic Liquids 2095.4 Chalcogenidostannates 2185.5 Chalcogenidoantimonates 2345.6 Selected Properties 2605.7 Conclusion 275Acknowledgments 276References 277Volume 26 The Structures of Metal–Organic Frameworks 283Yuehong Wen, Xintao Wu, and Qi-Long Zhu7 Structural Design and Rational Synthesis 391Qipu Lin8 Structural Topologies and Interpenetration in the Coordination Polymers 425Fei Wang, Hai-Xia Zhang, and Jian Zhang9 Inorganic Chalcogenides: From Zero-Dimensional Clusters to Three-Dimensional Frameworks 465Hua Lin, Xin-Tao Wu, and Qi-Long Zhu10 Relationship Between Structure and Electroluminescent, Photochromic, or Second-Order Nonlinear Optical Property 531Ming-Sheng Wang, San-Gen Zhao, Qian Wang, and Zhong-Ning Che11 Relationship Between Structure and Ferroelectric Properties 601Wuqian Guo, Zhihua Sun, Zhiyun Xu, Shiguo Han, and Junhua LuoVolume 312 The Relationship Between Structure and Electric Property 669Guan-E Wang, Yonggang Zhen, Guo-Dong Wu, Huanli Dong, and Gang Xu13 Understanding Magneto-Structural Correlations Toward Design of Molecular Magnets 777Zhu Zhuo, Guo-Ling Li, and You-Gui Huang14 Relationship Between MOF Structures and Gas Absorption Properties 833Qi Yin and Tian-Fu Liu15 Relationship Between Structure and Separation Property 881Zhanfeng Ju, El-Sayed M. El-Sayed, and Daqiang Yuan16 Catalysis in Metal–Organic Frameworks: Relationship Between Activities and Structures 953Yuan-Biao Huang, Teng Zhang, and Rong CaoIndex 995

Rong Cao, PhD, is Director of the Fujian Institute of Research on the Structure of Matter (FJIRM) and Director of the Institute of Urban Environment at the Chinese Academy of Sciences (CAS). He received his doctorate in Chemical Physics from the FJIRM, CAS. He is the recipient of multiple awards, including the China Youth Science and Technology Award and the National Candidate of New Century Talents Project in 2006.

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• Volume 11 Introduction 1Jian Zhang, Guo-Cong Guo, Rong Cao, and Xin-Tao Wu2 Coordination-Assembled Metal–Organic Macrocycles and Cages 9Xiao-Zhen Li, Yu-Ling Liang, Li-Peng Zhou, Li-Xuan Cai, Qiang-Yu Zhu, Zhuo Wang, Xiao-Qing Guo, Dan-Ni Yan, Shao-Jun Hu, Shao-Chuan Li, Shi-Yu Wu, Shi-Long Han, Ran Chen, Pei-Ming Cheng, Kai Cheng, Xiao-Shan Feng, Tian-Pu Sheng, Can He, Feng-Rong Dai, and Qing-Fu Sun2.1 Introduction 92.2 Metallacycles 92.3 Metallacages 352.4 Conclusion 77Acknowledgments 77References 773 Structural Chemistry of Metal-Oxo Clusters 81Xiaofeng Yi, Weihui Fang, Jinying Liu, Cheng Chen, Mingyan Wu, and Lei Zhang3.1 Oxo Clusters of Transition Metal 813.2 Oxo Clusters of Main Group Metal 1113.3 Oxo Clusters of Lanthanides 1223.4 Conclusion 149Acknowledgments 149References 1494 Synthetic Approaches, Structural Diversities, and Biological Aspects of Molybdenum (Tungsten)-Based Heterometallic Sulfide Clusters and Coordination Polymers 163Du Shaowu and Wu Xintao4.1 Introduction 1634.2 Synthesis of Mo–Fe–S Cuboidal Clusters for the Structural Modeling of the Iron–Molybdenum Cofactor(FeMoco) 1674.3 Rationally Designed Synthesis of Mo(W)–Cu(Ag)–S Clusters 1734.4 Rationally Designed Synthesis of W(Mo)–Ag–S Coordination Polymers 1824.5 Conclusion 190Acknowledgments 191References 1915 Group 11–15 Metal Chalcogenides 195Jian-Rong Li, Mei-Ling Feng, Bing Hu, and Xiao-Ying Huang5.1 Introduction 1955.2 Inorganic–Organic Hybrid Chalcogenides Based on II–VI Semiconductors 1985.3 Discrete Chalcogenide Clusters Synthesized in Ionic Liquids 2095.4 Chalcogenidostannates 2185.5 Chalcogenidoantimonates 2345.6 Selected Properties 2605.7 Conclusion 275Acknowledgments 276References 277Volume 26 The Structures of Metal–Organic Frameworks 283Yuehong Wen, Xintao Wu, and Qi-Long Zhu7 Structural Design and Rational Synthesis 391Qipu Lin8 Structural Topologies and Interpenetration in the Coordination Polymers 425Fei Wang, Hai-Xia Zhang, and Jian Zhang9 Inorganic Chalcogenides: From Zero-Dimensional Clusters to Three-Dimensional Frameworks 465Hua Lin, Xin-Tao Wu, and Qi-Long Zhu10 Relationship Between Structure and Electroluminescent, Photochromic, or Second-Order Nonlinear Optical Property 531Ming-Sheng Wang, San-Gen Zhao, Qian Wang, and Zhong-Ning Che11 Relationship Between Structure and Ferroelectric Properties 601Wuqian Guo, Zhihua Sun, Zhiyun Xu, Shiguo Han, and Junhua LuoVolume 312 The Relationship Between Structure and Electric Property 669Guan-E Wang, Yonggang Zhen, Guo-Dong Wu, Huanli Dong, and Gang Xu13 Understanding Magneto-Structural Correlations Toward Design of Molecular Magnets 777Zhu Zhuo, Guo-Ling Li, and You-Gui Huang14 Relationship Between MOF Structures and Gas Absorption Properties 833Qi Yin and Tian-Fu Liu15 Relationship Between Structure and Separation Property 881Zhanfeng Ju, El-Sayed M. El-Sayed, and Daqiang Yuan16 Catalysis in Metal–Organic Frameworks: Relationship Between Activities and Structures 953Yuan-Biao Huang, Teng Zhang, and Rong CaoIndex 995