Adolf Slawisch – författare

The present volume belongs to a series of handbooks dealing with organorhenium com­ pounds. 1t covers the Literature up to the end of 1993, but some more recent data published in 1994 have also been considered. Patents, conference reports, and dissertations generally were not reviewed. An empirical formula index, a Ligand formula index, and a transition metals cross reference table provide ready access to all compounds covered. The following comments may be helpful for rapidly finding the compound(s) you wish to get information of. ln the Gmelin series "Organometallic Compounds" the term "organometallic" is re­ served for all compounds containing at Least one carbon-to-metal bond. For all volumes published in this series, see p. VI. The series on organorhenium compounds started with the description of mononuclear compounds in Volumes 1 to 4 (Volume 4 is still to be published) and continues with the present Volume 5 describing all binuclear organorhenium compounds having 0 to 10 CO groups as Ligands, except (C0) Re which will be included in the next volume together 10 2 with all other binuclear compounds having carbenes, isonitriles, and "L Ligands (n > 1) bonded to rhenium as weiL as all other polynuclear organorhenium compounds.

The present voLume is a continuation of Series 8 on the mononucLear organoiron com- pounds and describes 545 compounds. It covers the Literature compLeteLy to the end of 1983 and incLudes many references to the Literature up to mid-1984. This voLume continues the description of mononucLear organoiron derivatives by treating compounds of the type 4LFe(COh where 4L incLudes seven-, eight-, and nine-membered ring. systems. OnLy a few Larger rings of the 4LFe(COh type compounds are known, and they are aLso incLuded. In the symboL mL , n is the number of organic Ligands L in the n compound, and m is the number of Fe-C bonds formed from an L Ligand as aLready expLained in the prefaces to "KobaLt-Organische Verbindungen" 1, New SuppL. Ser., VoL. 5, 1973, and "NickeL-Organische Verbindungen" 1, New SuppL. Ser., VoL. 16, 1975. Se ries 8 so far comprises voLumes 81 to 812, and a survey of this series has been given in the preface to 87 (1981). Much of the data, particuLarLy in tabLes, is given in abbreviated form without dimensions; for expLanation see p. VIII. AdditionaL remarks, if necessary, are given in the heading of the tabLes.A formuLa index for voLumes 88, 89, and 810 wiLL be given in "Organoiron Compounds" 810.

"Organoiron Compounds" A, Ferrocene 10 systematicalty covers the literature through the end of 1986 and includes so me references published more recently. A formula index provides ready access to the compounds covered. This volume ends the description of mononuclear unbridged disubstituted ferrocenes, 1 2 FeC HRR . The description of the unbridged disubstituted ferrocenes was initiated with lO a 1 2 "Organoiron Compounds" A, Ferrocene 7 (starting with R and R containing C and Hand 1 containing halogen at least in R\ and continuing with compounds containing 0 at least in R to form alcohols and phenols, their esters, ethers, acetals, and aldehydes), and was foltowed 1 by "Organoiron Compounds" A, Ferrocene 8 (with at least R containing 0). "Organoiron 1 Compounds" A, Ferrocene 9 treated compounds in wh ich at least R contains N, S, Se, B, or Si. This volume now comprises the rest of the disubstituted ferrocenes containing P, As, or a 1 metal at least in R . Beyond that it includes the description of alt the mononuclear unbridged trisubstituted ferrocenes, FeClOH7R1R2R3. Series A so far comprises volumes A 1 to A 10 and has been surveyed in the preface to A 7 (1980). The data in tables are given in abbreviated form without dimensions; for dimensions, explanations, and further abbreviations used, see p. X (next page). Additional remarks are given in the headings of the tables where necessary.

"Organoiron Compounds" A, Ferrocene 10 systematicalty covers the literature through the end of 1986 and includes so me references published more recently. A formula index provides ready access to the compounds covered. This volume ends the description of mononuclear unbridged disubstituted ferrocenes, 1 2 FeC HRR . The description of the unbridged disubstituted ferrocenes was initiated with lO a 1 2 "Organoiron Compounds" A, Ferrocene 7 (starting with R and R containing C and Hand 1 containing halogen at least in R\ and continuing with compounds containing 0 at least in R to form alcohols and phenols, their esters, ethers, acetals, and aldehydes), and was foltowed 1 by "Organoiron Compounds" A, Ferrocene 8 (with at least R containing 0). "Organoiron 1 Compounds" A, Ferrocene 9 treated compounds in wh ich at least R contains N, S, Se, B, or Si. This volume now comprises the rest of the disubstituted ferrocenes containing P, As, or a 1 metal at least in R . Beyond that it includes the description of alt the mononuclear unbridged trisubstituted ferrocenes, FeClOH7R1R2R3. Series A so far comprises volumes A 1 to A 10 and has been surveyed in the preface to A 7 (1980). The data in tables are given in abbreviated form without dimensions; for dimensions, explanations, and further abbreviations used, see p. X (next page). Additional remarks are given in the headings of the tables where necessary.

"Organoiron Compounds" A, Ferrocene 8 systematically covers the Literature through the end of 1984 and even includes some references published more recently. A formula index for the volumes "Organoiron Compounds" A, Ferrocene 7 and 8 provides ready access to the compounds covered. 1 2 1 This volume continues the description of ferrocenes FeC HRR in which at least R 10 8 contains C, H, and 0. The description of these type of compounds started in "Organoiron Compounds" A, Ferrocene 7 (with alcohols and phenols, their esters, ethers and acetones, and aldehydes). Series Aso far comprises volumes A 1 to A 8, and it has been surveyed in the preface to A 7 (1980). The data in tables are given in abbreviated form without dimensions; for dimensions, explanations, and further abbreviations used, see p. VIII (next page). Additional remarks, if necessary, are given in the headings of the tables. Frankfurt Adolf Slawisch November 1985 VIII Remarks on Abbreviations and Dimensions Many compounds in this volume are presented in tables in which numerous abbreviations are used, and the dimensions are omitted for the sake of conciseness. This necessitates the following clarification: Temperstures are given in oc, otherwise K stands for Kelvin. Abbreviations used with temperatures are m.p. for melting point, b.p. for boiling point, dec. for decomposition, and sub!. for sublimation. The solvent in parentheses following the m.p. is the solvent from which the compound is recrystallized.