Bertrand R. Rowe - Böcker

InMay1988,theFirstInternationalConferenceonDissociativeRecombination:Theory, ExperimentandApplicationswasheldatChateauLakeLouise,Alberta,Canada. Thismeeting gaveaconsiderableimpetustothissubject,whichisofparticularinterestforalargevarietyof fieldsincludinginterstellarclouds,planetaryatmospheres,gaslasers,plasmaprocessing,ion sourcesandthermonuclearplasmas. Sincethen,indeed,severalcollaborationswereinitiated betweenexperimentalistsworkingwithdifferenttechniques,betweentheoreticiansdealingwith molecularstructureononehandanddynamicsontheotherhandandalsobetween experimentalistsandtheoreticians. Duringthelastfouryears,therefore,alargenumberof studieswerecarriedoutandraisedanewsetofquestions. Moreparticularly,theresultsthat wereobtainedconcerningcontroversialspeciessuchasH!andHeir,castingsomedoubton theverymechanismsbywhichdissociativerecombinationproceeds. The Second International Conference on Dissociative Recombination: Theory, ExperimentandApplications heldat"I'AbbayedeSaintJacutdelaMer",Brittany,France, May3-8,1992,camethereforeattherighttimetosurveythecurrentstateofthesubject.The symposiumbroughttogetherleadinginvestigatorsinthefieldsofmolecularionrecombination research,atomicandmoleculartheoryandexperiment,plasmasphysics,astrochemistryand aeronomy. Speakerspresentedtalksreviewingtheirownworkandthesewerefollowedby livelydiscussionsessions. Freetimeperiodsallowedparticipantstodiscoveranenchanting peninsulaofNorthBrittanywhilepursuingstimulatingscientificdiscussions. Thepapersinthis volumearebasedonthesetalksandfurtherdiscussions,withtheexceptionofcontributions fromT. AmanoandB. M. McLaughlinwhowereunabletoattend. Alistofparticipantsas wellasasouvenirgroupphotoisgivenattheendofthebook. WeareindebtedtoNATOforitsfinancialsupportwhichcontributedtothegreat successofthissecondmeeting. TheUniversityofRennesIandtheBalzerscompanyarealso acknowledgedfortheiradditionalsupportManythankstothewholestaffoftheabbeyforits kindnessandeffortsinprovidinguswithapropitiousenvironmentforsuchaworkshop. We arealsogratefultoL. Caubetforhervaluableadministrativeassistanceduringthepreparation ofthemeeting. Finallyaspecialmentionmustbegiventoallthesessionchairpersonsfortheir skillinorchestratingthediscussions. Lookingforwardtoattendingthethirdmeeting. TheEditors Bertrand R. Rowe J.Bria/l A. Mitchell Andre Callosa DepartementdePhysique DepartmentofPhysics DepartementdePhysique AtomiqueetMoleculaire TheUniversityofWesternOntario AtomiqueetMoleculaire UniversitedeRennesI London,Canada,N6A3K7 UniversitedeRennesI CampusdeBeaulieu CampusdeBeaulieu 35042RennesCedex, 35042RennesCedex, France France v CONTENTS ORALCONTRIBUTIONS PolyatomicIonDissociativeRecombination . 1 D. R. Bates RecentDevelopmentsandPerspectivesintheTreatmentofDissociative RecombinationandRelatedProcesses...11 A. Giusti-Suzor, I. F Schneider, and 0. Dulieu CharacteristicsofSuperexcitedStatesofMoleculesandMQDTStudiesofNO+ DissociativeRecombination...25 H. Sun, K. Nakashima, and H. Nakamura CalculationsforAr +Xe*andArXe+ +e 35 A. P. Hickman, DL Huestis, and R. P. Saxon Electron-IonContinuum-ContinuumMixinginDissociativeRecombination 47 s. L. Guberman ATheoreticalStudyoftheHCO+andHCS+ElectronicDissociativeRecombinations. . 59 D. Talbi, and Y Ellinger DissociativeRecombinationofCH;:SomeBasicInformationfromElectronic 2 StructureCalculations. 67 WP. Kraemer TheoreticalProblemsintheDissociativeRecombinationofH~ +e...75 H. Takagi RecentMergedBeamsInvestigationsofHydrogenMolecularIonRecombination...87 J B.A. Mitchell, F B. Yousif, P. Van der Donk, and T. J Morgan vii FlowingAfterglowStudiesofElectron-IonRecombinationusingLangmuirProbesand OpticalSpectroscopy...99 NG. Adams RecentFlowingAfterglowMeasurements . 113 B. R. Rowe InfraredSpectroscopicStudiesoftheDissociativeRecombinationProcessesofH...127 3 T. Amano RecombinationofClusterIons . 135 R. Johnsen PredissociationofExcitedStatesofH . . 145 3 H. Helm AStudyofHe e,3I,;)BoundandContinuumStates...155 2 CJ Gillan, B. M McLaughlin. and P. G. Burke ElectronCollisionInducedExcitationsandDissociationofHeH+usingthe R-MatrixMethod . . 163 BK Sarpal, J Tennyson, and L. A. Morgan AssociativeIonisationofHydrogen:ExperimentswithFastMergedBeams...173 F Brouillard, andX Urbain TheoryoftheAsssociativeIonisationReactionbetweenTwoLaser-Excited . 187 SodiumAtoms 0. Du!ieu, A. Giusti-Suzor, andF Masnou-Seeuws ResonantTheoryofDissociativeAttachment...195 J. J. Fabrikant MicroscopicandMacroscopicTheoriesofTermolecularRecombinationbetween AtomicIons...205 MR. Flannery DissociativeRecombinationinPlanetaryIonospheres . . 219 JL. Fox ChemistryofSupernova1987a . 243 A. Dalgarno DissociativeRecombinationinInterstellarClouds . .

Radioastronomy has painted an extraordinary picture of the Galactic interstellar medium, which displays an amazing organization and structuring of matter from very hot ultra-diluted media to very cold denser milieus considered as the cradles of stars. In these latter environments, the discovery of a chemical diversity of molecules, including those associated with precursors to life itself, immediately brought to light the question of the mechanisms leading to their formation and persistence at temperatures as low as 10 K. The chemical networks developed to understand telescope observations required a great deal of physical and chemical parameters relevant to interstellar conditions, particularly at very low temperatures. These included the rate coefficients of thousands of gas phase chemical reactions. Such data were missing in the 1970s, when the very first molecular discoveries were made. Then, in the early eighties, it was realized that uniform supersonic flows were ideal chemical reactors to study reaction kinetics at interstellar temperatures.Uniform Supersonic Flows in Chemical Physics reviews 40 years of use of such reactors, the so-called CRESU machines, focusing on major breakthroughs brought to chemical physics, physical chemistry, astrophysics and astrochemistry by the various experiments carried out with such apparatuses. The wealth of kinetic data at very low temperatures provided new targets for the predictions of theory, with new theoretical methods being developed to explain observed behavior. The first two chapters describe the physical context of reaction kinetics at very low temperatures and the requirements needed to run optimally such uniform supersonic flows, together with a historical perspective. Chapters 3 to 9 describe the various families of chemical processes that have been explored within the CRESU technique, highlighting major advances and offering an exhaustive up-to-date bibliography. Chapters 10 and 11 show how these experimental results have helped in improving the ideas in quantum chemistry and interstellar modeling. The book concludes with an overview of potential perspectives and new routes to be explored.