Byung Chan Eu - Böcker

For almost 20 years the author has conducted research on both macroscopic and molecular theories. The results of his investigation, which can be found in this work, are that irreversible thermodynamics and kinetic theory of matter are not separable especially for nonlinear irreversible processes occurring in systems removed far from equilibrium and thus must be examined together in a mutually consistent manner. Includes coverage of such topics as mass and momentum conservation law, bilinear and quadratic forms for entropy production, viscous phenomena, boundary conditions for velocities and much more.

In this monograph, nonequilibrium statistical mechanics is developed by means of ensemble methods on the basis of the Boltzmann equation, the generic Boltzmann equations for classical and quantum dilute gases, and a generalized Boltzmann equation for dense simple fluids. The theories are developed in forms parallel with the equilibrium Gibbs ensemble theory in a way fully consistent with the laws of thermodynamics. The generalized hydrodynamics equations are the integral part of the theory and describe the evolution of macroscopic processes in accordance with the laws of thermodynamics of systems far removed from equilibrium. The book should be of interest to researchers in the fields of statistical mechanics, condensed matter physics, gas dynamics, fluid dynamics, rheology, irreversible thermodynamics and nonequilibrium phenomena.

This monograph presents, from the viewpoint of continuum mechanics, an emerging field of irreversible thermodynamics, in which linear irreversible thermodynamics are extended to the nonlinear regime and macroscopic phenomena far removed from equilibrium are studied in a manner consistent with the laws of thermodynamics. The tool to develop this thermodynamic theory of irreversible processes is generalized thermodynamics, which also extends the classical hydrodynamics of Navier, Stokes and Fourier to nonlinear irreversible processes.

This book presents the fundamentals of irreversible thermodynamics for nonlinear transport processes in gases and liquids, as well as for generalized hydrodynamics extending the classical hydrodynamics of Navier, Stokes, Fourier, and Fick. Together with its companion volume on relativistic theories, it provides a comprehensive picture of the kinetic theory formulated from the viewpoint of nonequilibrium ensembles in both nonrelativistic and, in Vol. 2, relativistic contexts.Theories of macroscopic irreversible processes must strictly conform to the thermodynamic laws at every step and in all approximations that enter their derivation from the mechanical principles. Upholding this as the inviolable tenet, the author develops theories of irreversible transport processes in fluids (gases or liquids) on the basis of irreversible kinetic equations satisfying the H theorem. They apply regardless of whether the processes are near to or far removed from equilibrium, or whether they are linear or nonlinear with respect to macroscopic fluxes or thermodynamic forces. Both irreversible Boltzmann and generalized Boltzmann equations are used for deriving theories of irreversible transport equations and generalized hydrodynamic equations, which rigorously conform to the tenet. All observables described by the so-formulated theories therefore also strictly obey the tenet.

This book presents the fundamentals of irreversible thermodynamics for nonlinear transport processes in gases and liquids, as well as for generalized hydrodynamics extending the classical hydrodynamics of Navier, Stokes, Fourier, and Fick. Together with its companion volume on nonrelativistic contexts, it provides a comprehensive picture of the relativistic covariant kinetic theory of gases and relativistic hydrodynamics of gases.Relativistic theories of macroscopic irreversible processes must strictly conform to the thermodynamic laws at every step and in all approximations that enter their derivation from the mechanical principles. Upholding this as the inviolable tenet, the author develops theories of irreversible transport processes in fluids (gases or liquids). They apply regardless of whether the processes are near to or far removed from equilibrium, or whether they are linear or nonlinear with respect to macroscopic fluxes or thermodynamic forces.The irreversible covariant Boltzmann as well as the covariant form of the Boltzmann-Nordheim-Uehling-Uhlenbeck equation is used for deriving theories of irreversible transport equations and generalized hydrodynamic equations for either classical gases or quantum gases. They all conform rigorously to the tenet. All macroscopic observables described by the so-formulated theories therefore are likewise expected to strictly obey the tenet.

This book presents the fundamentals of irreversible thermodynamics for nonlinear transport processes in gases and liquids, as well as for generalized hydrodynamics extending the classical hydrodynamics of Navier, Stokes, Fourier, and Fick.

This book presents the fundamentals of irreversible thermodynamics for nonlinear transport processes in gases and liquids, as well as for generalized hydrodynamics extending the classical hydrodynamics of Navier, Stokes, Fourier, and Fick.

In this monograph, the density ?uctuation theory of transport coe?cients of simple and complex liquids is described together with the kinetic theory of liquids, the generic van der Waals equation of state, and the modi?ed free volume theory. The latter two theories are integral parts of the density ?- tuation theory, which enables us to calculate the density and temperature dependence of transport coe?cients of liquids from intermolecular forces. The terms nanoscience and bioscience are the catch phrases currently in fashion in science. It seems that much of the fundamentals remaining unsolved or poorly understood in the science of condensed matter has been overshadowed by the frenzy over the more glamorous disciplines of the former, shunned by novices, and are on the verge of being forgotten. The transport coe?cients of liquids and gases and related thermophysical properties of matter appear to be one such area in the science of macroscopic properties of molecular systems and statisticalmechanicsofcondensedmatter. Evennano-andbiomaterials,h- ever, cannot be fully and appropriately understood without ?rm grounding and foundations in the macroscopic and molecular theories of transport pr- ertiesandrelatedthermophysicalpropertiesofmatterinthecondensedphase. Oneisstilldealingwithsystemsmadeupofnotafewparticlesbutamultitude of them, often too many to count, to call them few-body problems that can be understoodwithoutthehelpofstatisticalmechanicsandmacroscopicphysics. In the density ?uctuation theory of transport coe?cients, the basic approach taken is quite di?erent from the approaches taken in the conventional kinetic theories of gases and liquids.

Until recently the formal statistical mechanical approach offered no practicable method for computing the transport coefficients of liquids, and so most practitioners had to resort to empirical fitting formulas. This has now changed, as demonstrated in this innovative monograph. The author presents and applies new methods based on statistical mechanics for calculating the transport coefficients of simple and complex liquids over wide ranges of density and temperature. These molecular theories enable the transport coefficients to be calculated in terms of equilibrium thermodynamic properties, and the results are shown to account satisfactorily for experimental observations, including even the non-Newtonian behavior of fluids far from equilibrium.

In this monograph, nonequilibrium statistical mechanics is developed by means of ensemble methods on the basis of the Boltzmann equation, the generic Boltzmann equations for classical and quantum dilute gases, and a generalised Boltzmann equation for dense simple fluids. The theories are developed in forms parallel with the equilibrium Gibbs ensemble theory in a way fully consistent with the laws of thermodynamics. The generalised hydrodynamics equations are the integral part of the theory and describe the evolution of macroscopic processes in accordance with the laws of thermodynamics of systems far removed from equilibrium. Audience: This book will be of interest to researchers in the fields of statistical mechanics, condensed matter physics, gas dynamics, fluid dynamics, rheology, irreversible thermodynamics and nonequilibrium phenomena.

This monograph presents, from the viewpoint of continuum mechanics, a newly emerging field of irreversible thermodynamics, in which linear irreversible thermodynamics are extended to the nonlinear regime and macroscopic phenomena far removed from equilibrium are studied in a manner consistent with the laws of thermodynamics. The tool to develop this thermodynamic theory of irreversible processes are the generalized thermodynamics, which also extends the classical hydrodynamics of Navier, Stokes and Fourier to nonlinear irreversible processes. On the basis of mathematically rigorous representations of the first and the second law of thermodynamics, phenomenological theory (continuum mechanics) deductions are made from the thermodynamic laws of R. Clausius and Lord Kelvin and by this continuum mechanics theories are formulated for macroscopic irreversible processes occurring far removed from equilibrium. Non-equilibrium thermodynamics are developed for thermodynamic functions.

This book enables the reader to learn, in a single volume, equilibrium and nonequilibrium thermodynamics as well as generalized forms of hydrodynamics for linear and nonlinear processes applied to various hydrodynamic flow processes — including chemical oscillation phenomena and pattern formations, shock wave phenomena, sound wave propagations, and Liesegang pattern formation, amongst others.Chemical Thermodynamics introduces advanced undergraduate students and graduate students to the fundamental ideas and notions of the first and second laws of thermodynamics by seamlessly combining equilibrium and nonequilibrium thermodynamics in a unicameral viewpoint based on the first and second law of thermodynamics. Part I of the book discusses equilibrium thermodynamics in historical deference, covering topics generally dealt with in traditional equilibrium thermodynamics. In Part II, the concept of entropy for reversible processes is extended and developed for thermodynamics of irreversible processes by using the concept of calortropy (heat evolution), so that the mathematical theory of macroscopic processes in matter, including a generalized form of hydrodynamics, is ensured to remain consistent with the thermodynamic laws.