Friedrich Kremer - Böcker

The dielectric properties especially of glassy materials are nowadays explored at widely varying temperatures and pressures without any gap in the spectral range from µHz up to the Infrared, thus covering typically 20 decades or more.

This book describes the dynamics of low molecular weight and polymeric molecules when they are constrained under conditions of geometrical confinement.

This book describes the dynamics of low molecular weight and polymeric molecules when they are constrained under conditions of geometrical confinement. It covers geometrical confinement in different dimensionalities:(i) in nanometer thin layers or self supporting films (1-dimensional confinement)(ii) in pores or tubes with nanometric diameters (2-dimensional confinement)(iii) as micelles embedded in matrices (3-dimensional) or as nanodroplets.The dynamics under such conditions have been a much discussed and central topic in the focus of intense worldwide research activities within the last two decades. The present book discusses how the resulting molecular mobility is influenced by the subtle counterbalance between surface effects (typically slowing down molecular dynamics through attractive guest/host interactions) and confinement effects (typically increasing the mobility). It also explains how these influences can be modified and tuned, e.g. through appropriate surface coatings, film thicknesses or pore diameters. "Dynamics in Confinement" sums up the present state-of-the-art and introduces to the analytical methods of choice for the study of dynamics in nanometer-scale confinement.

The dielectric properties especially of glassy materials are nowadays explored at widely varying temperatures and pressures without any gap in the spectral range from µHz up to the Infrared, thus covering typically 20 decades or more.

The interaction of electromagnetic waves with matter in the frequency range between 10-6 and 1012 Hz is the domain of broadband dielectric spectroscopy. In this extraordinarily extended dynamic range molecular and collective dipolar fluctuations, charge transport and polarisation effects at inner and outer boundaries take place and determine the dielectric properties of the material being studied. Hence, broadband dielectric spectroscopy enables one to gain a wealth of information on the dynamics of bound (dipoles) and mobile charge carriers depending on the details of a molecular system. It is the intention of this book to be both an introductory course to broadband dielectric spectroscopy as well as a monograph describing recent dielectric contributions to current topics. In this respect the book will correspond to the needs of graduate students but also to specialized researchers, molecular physicists, polymer scientists and materials scientists in academia and in industry.

Both an introductory course to broadband dielectric spectroscopy and a monograph describing recent dielectric contributions to current topics, this book is the first to cover the topic and has been hotly awaited by the scientific community.