R. B. Cundall – författare

Ion Association in Proton Transfer Reactions: Use of ESR for the Quantitative Determination of Gas Phase Atom and Radical Concentrations summarizes the basic information essential for the measurement of both gas phase atoms and free radicals concentration by electron spin resonance (ESR) spectroscopy. Organized into two chapters, this book first explains the ion association in proton transfer reactions, and then characterizes the ion pairs. The second chapter focuses on the specific use of the ESR spectroscopy. This book also details the gas phase species detected by ESR spectroscopy, including each of the spectra, and the intensities of the spectral lines of the various atoms and radicals. The actual measurements made by this instrument are also shown.

Progress in Reaction Kinetics, Volume 9 summarizes recent advances that have been made with regards to reaction kinetics. Kinetic applications of nuclear magnetic resonance spectroscopy are described, and tunneling reactions of solvated electrons in liquids and glasses are discussed. The reactions of free radicals generated by organic compounds are also considered. This volume consists of three chapters and begins with a discussion of basic NMR theory, including the NMR phenomenon and nuclear spin relaxation processes. Special attention is paid to the dynamic characteristics of chemical exchange reactions which occur in a system at equilibrium, along with techniques for determining chemical exchange parameters from time domain spectra and time dependent frequency domain spectra. The reader is then introduced to tunneling reactions of solvated electrons in liquids and glasses, with emphasis on the mode of transport by which the electron induces such a reaction. A model of diffusion-controlled reactions incorporating a tunneling reaction mechanism is described. A chapter analyzing the use of radiation to produce reactions of free radicals from organic compounds in aqueous solution, including hydrocarbons and carbonyl compounds, concludes the book. This book will be of interest to scientists, students, and researchers working in the fields of chemistry and the molecular sciences.

Progress in Reaction Kinetics, Volume 7 is a three-chapter book that first discusses the ion association in proton transfer reactions. Chapter 2 details the use of ESR for the quantitative determination of gas phase atom and radical concentrations. The last chapter centers on the modulation techniques in chemical kinetics.

Progress in Reaction Kinetics, Volume 6 covers various aspects of kinetics. It presents quantitative data on the reaction rates observed in hydrocarbon-active nitrogen systems, noble gases, acids and bases, and rare gas metastable atoms. Comprised of six chapters, the volume begins by discussing the reactions of nitrogen atoms with hydrocarbons. It then illustrates the development of flash protolysis techniques and moves on to chemi-ionization and chemical applications of rare gases. The text concludes by describing salt and medium effects in ionic reactions in aqueous solutions. Students and scientists who wish to increase their understanding of reactions occurring in various chemical reaction systems will find this volume invaluable.

Progress in Reaction Kinetics, Volume 10 discusses several topics concerning reaction kinetics. The first chapter tackles the dynamics of reactive collisions; this chapter also covers the experimental methods, theoretical methods, atom-molecule reactions, and molecule-molecule reaction. The second chapter discusses reactive, inelastic, and radiative processes involving electronically excited atoms, which include emission process, energy transfer, ionization process, and chemical reaction. The third chapter tackles luminescence kinetics of metal complexes in solution; this chapter includes the theoretical and experimental background, paradigm problem, and ligand-centered luminescent systems. This book will be of great use to researchers whose work involves kinetics research.