R. D. Levine – författare

This book takes a fresh look at the wave function mathematics that provide the theoretical underpinnings of molecular spectroscopy. Original work demonstrating the advantages of algebraic theory over the conventional geometric approach to the subject is presented. This new approach has important implications for modern spectroscopy. Many examples are given to show comparisons of the two methods, and the relationship of the new method to current experiments.

Algebraic Theory of Molecules presents a fresh look at the mathematics of wave functions that provide the theoretical underpinnings of molecular spectroscopy. Written by renowned authorities in the field, the book demonstrates the advantages of algebraic theory over the more conventional geometric approach to developing the formal quantum mechanics inherent in molecular spectroscopy. Many examples are provided that compare the algebraic and geometric methods, illustrating the relationship between the algebraic approach and current experiments. The authors develop their presentation from a basic level so as to enable newcomers to enter the field while providing enough details and concrete examples to serve as a reference for the expert. Chemical physicists, physical chemists, and spectroscopists will want to read this exciting new approach to molecular spectroscopy.

Lasers and chemical change is the study of radiation and molecules in dis­ equilibrium. The distinguishing feature of such systems is the extreme de­ parture from thermal equilibrium: the radiation is usually confined to a narrow frequency range, is well coll imated, and is far brighter than black body radiation; the chemical composition and also the distribution of mole­ cules over their different energy states are often markedly displaced from that expected at equilibrium. Such systems can be used as a source of laser radiation and, reversedly, lasers can rapidly and selectively displace mole­ cular systems from equilibrium. The subsequent evolution of the initially prepared state can then be monitored - again using lasers. One purpose of this book is to introduce the concepts required to d- cuss systems of radiation and molecules in disequilibrium. These include the physics of (laser) radiation and of radiation-matter interaction and molecular structure and spectroscopy. Excellent textbooks of these topics are available and our survey (in Chap. 3) is only intended to accent the es­ sential points, with special reference to atomic and molecular radiation physics. Considerably more attention is given to the topic of disequilibrium in chemical systems (Chap. 2). In particular we consider both inter- and intra­ molecular dynamics with special reference to energy requirements and energy disposal in chemical reactions and to what goes on in between - intramole­ cular energy migration.