R.C. Larock – författare
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The field of organometallic chemistry has enjoyed explosive growth in recent years. During this time a rapidly increasing number of metals have found utility in organic synthesis as the corresponding organometallic compounds. The sub ject of "Organic Synthesis by Means of Transition Metal Complexes" was reviewed in the first volume of this series of monographs. This volume deals primarily with the appli cation of organomercury compounds in organic synthesis (exclusive of solvomercuration-demercuration reactions), but will of necessity involve a number of reactions of other organometallics as well. Organomercurials are among the oldest known organo metallics and were perhaps the first to have an entire book devoted to their chemistry, when Whitmore wrote an American Chemical Society monograph on the subject in 1921. Subsequently, two very detailed monographs on the subject have appeared. In 1967 "The Organic Compounds of Mercury", volume 4 in the series "Methods of Elemento Organic Chemistry" appeared and this was followed in 1974 by Houben Weyl's full volume, Band XIII/2b, devoted entirely to the organometallic compounds of mercury. These books cover the entire field of organomercury chemistry.
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The widespread utilization of organometallic reagents in organic synthesis has been one of the major developments in organic chemistry in recent years. The earlier Springer monograph entitled "Organic Synthesis by Means of Trans i- tion Metal Complexes" covered many of the more recent advances in this area. The present volume covers applica- tions of the very valuable solvomercuration-demercuration sequence in organic synthesis. Organomercurials have played an important role in organic chemistry for over a century. They have been known since 1852 and major monographs covering their chemistry have appeared in 1921 ("Organic Compounds of Mercury" by F. C. Whitmore), 1967 ("The Organic Compounds of Mercury", volume 4 in the series "Methods of Elemento- Organic Chemistry", edited by L. G. Makarova and A. N. Nesmeyanov) and 1974 ("Metallorganische Verbindungen- Hg", Houben-Weyl: Methoden der Organischen Chemie, 4th ed., Vol. 13/2b, edited by H. Staub, K. P. Zeller and H. Leditsche).My own personal interest in the application of organo- mercurials in organic synthesis goes back to the late 1960's when I first became involved in the development of new synthetic routes to organomercurials. In 1976 I wrote a chapter entitled "Organomercurials as Reagents and Inter- mediates in Organic Synthesis" for a book entitled "New Applications of Organometallic Reagents in Organic Syn- thesis". That chapter was subsequently pared down to a brief review article in Angewandte Chemie which appeared in 1978 and a further article in Tetrahedron Reports in 1982.