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Phase Equilibrium Engineering, Second Edition, Volume Thirteen offers a comprehensive study on the application of phase equilibrium tools for chemical process development. This updated edition shifts the focus from computing phase equilibria using thermodynamic relationships to designing and controlling phase conditions essential for various processes. The book emphasizes thermodynamic modeling of mixtures crucial for process synthesis, simulation, design, and optimization, providing updated chapters, new sections, case studies, and additional chapters based on the latest experimental work. The book delves into the relationship between mixture molecular properties, the selection of thermodynamic models, and applicable process technologies. It includes a classification of mixtures, separation processes, thermodynamic models, and technologies to guide engineers. The phase conditions required for reacting systems at subcritical and supercritical conditions are studied. The four cardinal points of phase equilibrium engineering-chemical plant/process, laboratory, phase equilibria modeling, and simulation-are harmonized to improve the design and operation of chemical processes.

Traditionally, the teaching of phase equilibria emphasizes the relationships between the thermodynamic variables of each phase in equilibrium rather than its engineering applications. This book changes the focus from the use of thermodynamics relationships to compute phase equilibria to the design and control of the phase conditions that a process needs.

Phase Equilibrium Engineering presents a systematic study and application of phase equilibrium tools to the development of chemical processes. The thermodynamic modeling of mixtures for process development, synthesis, simulation, design and optimization is analyzed. The relation between the mixture molecular properties, the selection of the thermodynamic model and the process technology that could be applied are discussed. A classification of mixtures, separation process, thermodynamic models and technologies is presented to guide the engineer in the world of separation processes. The phase condition required for a given reacting system is studied at subcritical and supercritical conditions.

The four cardinal points of phase equilibrium engineering are: the chemical plant or process, the laboratory, the modeling of phase equilibria and the simulator. The harmonization of all these components to obtain a better design or operation is the ultimate goal of phase equilibrium engineering.