Thomas M. Klapötke - Böcker

The 5th revised edition expands on the basic chemistry of high-energy materials of the previous editions and examines new research developments, including plastic bonded explosives and melt-castable dinitrate esters. Applications in military and civil fields are discussed. This work is of interest to advanced students in chemistry, materials science and engineering, as well as to all those working in defense technology.

This book discusses methods for the assessment of energetic compounds through heat of detonation, detonation pressure, velocity and temperature, Gurney energy and power. The authors focus on the detonation pressure and detonation velocity of non-ideal aluminized energetic compounds. This 2nd Edition includes an updated and improved presentation of simple, reliable methods for the design, synthesis and development of novel energetic compounds.

Chemistry of High-Energy Materials continues in this new and revised 6th edition to provide fundamental scientifi c insights into primary and secondary explosives, propellants, rocket fuels and pyrotechnics. It expands with new research developments, including new melt casts, reactive structure materials, a computational study on the detonation velocity of mixtures of solid explosives with non-explosive liquids, calculation of craters after explosions. This work is of interest to advanced students in chemistry, materials science and engineering, as well as to all those working in military and defense technology.

For a chemist who is concerned with the synthesis of new energetic compounds, it is essential to be able to assess physical and thermodynamic properties, as well as the sensitivity, of possible new energetic compounds before synthesis is attempted. Various approaches have been developed to predict important aspects of the physical and thermodynamic properties of energetic materials including (but not limited to): crystal density, heat of formation, melting point, enthalpy of fusion and enthalpy of sublimation of an organic energetic compound. Since an organic energetic material consists of metastable molecules capable of undergoing very rapid and highly exothermic reactions, many methods have been developed to estimate the sensitivity of an energetic compound with respect to detonationcausing external stimuli such as heat, friction, impact, shock and electrostatic discharge. This book introduces these methods and demonstrates those methods which can be easily applied.

Chemistry of High-Energy Materials continues in this new and revised 7th edition to provide fundamental scientific insights into primary and secondary explosives, propellants, rocket fuels and pyrotechnics. It expands with new research developments, including machine learning, new programs (e.g., RoseBoom), the production of propellants, supply of energetic materials in times of war, and flow chemistry. This work is of interest to advanced students in chemistry, materials science and engineering, as well as to all those working in military and defense technology.

This publication addresses the critical need for chemists engaged in the synthesis of new energetic compounds to comprehensively evaluate physical and thermodynamic properties, as well as sensitivity to various stimuli. The book delves into established and emerging methods for predicting key properties such as crystal density, heat of formation, and melting points, providing a thorough understanding of the subject matter.In this revised edition, we present updated insights across all chapters, exploring topics like enthalpy and entropy of fusion, heat of sublimation, and correlations among different types of sensitivities. Additionally, three new chapters focus on the assessment of energetic metal-organic complexes, including energetic metal-organic frameworks (MOFs) and energetic polymers, alongside strategies for predicting properties of novel energetic compounds.This book is an essential resource for researchers and practitioners in the field, offering practical techniques and a solid foundation for advancing the synthesis and application of energetic materials. Its relevance extends to both academic and industrial settings, making it a vital addition to the literature on energetic compounds. This book uniquely integrates theoretical methods with practical applications for predicting properties of energetic compounds.It addresses the gap in understanding the sensitivity and stability of new materials.Key features include updated methodologies, new chapters on metal-organic complexes, and comprehensive coverage of critical properties.

This book summarizes some recent developments in the area of high-energy high-density (HEDM) materials. Rather than being comprehensive in scope, emphasis is given to structural and bonding features of highly energetic - terials with possible applications as high explosives (secondary explosives) or propellants. In this book we do not focus on primary explosives (e.g. lead azidereplacements)sincebyde?nitiontheexplosiveperformance(detonation velocity and detonation pressure) of such materials - although very sensitive -are much less energetic than secondary (high) explosives. Modern HEDMs derive most of their energy (i) from oxidation of the c- bon backbone, as in traditional energetic materials, (ii) from ring or cage strain, or (iii) from their very high positive heat of formation. Examples of the?rstclassare traditionalexplosives, suchasTNT,RDXand HMX.Modern nitro-compounds, such as CL-20 or the recently reported hepta- and octa- trocubanes, belong to the second group of explosives and possess very high densities and enhance the energies utilizing substantial cage strain.Members of the third class of compounds are high-nitrogen compounds (up to 85% - trogencontent), such as aminotetrazole and nitrotetrazolederivatives, which show the desired remarkable insensitivity to electrostatic discharge, friction and impact, while having very high positive heats of formation and therefore very high explosive powers. The synthesis of energetic, non-nuclear materials for military application has been a long-term goal in various academic and military research groups worldwide. Some of the current challenges that face HEDMscientists are: * Demandforenvironmentallycompatibleandtoxicologicallyacceptable- plosives and propellants. Examples are replacements for TNT, RDX and HMXsince nitro-explosivesper se,aswellastheir environmental transf- mation products, are toxic.

This book summarizes some recent developments in the area of high-energy high-density (HEDM) materials. Rather than being comprehensive in scope, emphasis is given to structural and bonding features of highly energetic - terials with possible applications as high explosives (secondary explosives) or propellants. In this book we do not focus on primary explosives (e.g. lead azidereplacements)sincebyde?nitiontheexplosiveperformance(detonation velocity and detonation pressure) of such materials - although very sensitive -are much less energetic than secondary (high) explosives. Modern HEDMs derive most of their energy (i) from oxidation of the c- bon backbone, as in traditional energetic materials, (ii) from ring or cage strain, or (iii) from their very high positive heat of formation. Examples of the?rstclassare traditionalexplosives, suchasTNT,RDXand HMX.Modern nitro-compounds, such as CL-20 or the recently reported hepta- and octa- trocubanes, belong to the second group of explosives and possess very high densities and enhance the energies utilizing substantial cage strain.Members of the third class of compounds are high-nitrogen compounds (up to 85% - trogencontent), such as aminotetrazole and nitrotetrazolederivatives, which show the desired remarkable insensitivity to electrostatic discharge, friction and impact, while having very high positive heats of formation and therefore very high explosive powers. The synthesis of energetic, non-nuclear materials for military application has been a long-term goal in various academic and military research groups worldwide. Some of the current challenges that face HEDMscientists are: * Demandforenvironmentallycompatibleandtoxicologicallyacceptable- plosives and propellants. Examples are replacements for TNT, RDX and HMXsince nitro-explosivesper se,aswellastheir environmental transf- mation products, are toxic.