Tristram Chivers - Böcker

Ring systems represent a very important branch of organic chemistry. Benzene is perhaps the pre-eminent example and provides the benchmark for the so-called aromatic character of cyclic systems. Cycloalkanes are another prominent class of organic compounds and these saturated ring systems form a homologous series known as alicyclics. Materials that are constructed from organic polymers such as polythene, polystyrene, polyisoprene (natural rubber) and polyvinyl chloride are common features of our daily lives. Most of these and related organic polymers are generated from acyclic precursors by free radical, anionic, cationic or organometallic polymerisation processes or by condensation reactions. The focus of this book is monocyclic inorganic ring systems of the p-block elements and the polymers that are, in many cases derived from them. Bicyclic or polycyclic arrangements are considered when they are closely related to those of monocyclic systems. Inorganic heterocycles that are more accurately described as coordination complexes of chelating inorganic ligands are included only when they are directly related to an inorganic homocycle or heterocycle by the replacement of one p-block element by a more metallic p-block element. After a short introductory chapter, the first half of the book is comprised of seven chapters that deal with the fundamentals of the subject intended for undergraduates or researchers who are unfamiliar with the topic, covering the following areas: - synthetic methods - characterisation techniques - delocalisation in inorganic rings - paramagnetic inorganic rings - inorganic macrocycles - ligand chemistry - inorganic polymers (general concepts including, synthesis, structure and bonding, characterisation methods, properties and applications) The final four chapters discuss in detail the chemistry of inorganic homo- and hetero-cycles involving the elements of groups 13-16 (the p-block elements). The focus is on relating the early seminal contributions to the field with exciting new developments. From the fundamental standpoint, novel structures and new bonding concepts are highlighted, in addition to synthetic approaches. This is the first book that addresses both the fundamental and applied aspects of inorganic ring systems through an emphasis of their use as precursors to inorganic polymers and other useful materials (e.g. semiconductors and ceramics). The book is intended primarily for senior undergraduates and graduate students in inorganic chemistry, as well research workers in the field of inorganic ring systems and polymers. At the undergraduate level it serves as a supplementary text to the more general inorganic chemistry text books and at the graduate level it would be the text of choice for a course in the area of inorganic rings and polymers.

Chalcogen-nitrogen chemistry involves the study of compounds that exhibit a linkage between nitrogen and sulfur, selenium or tellurium atoms. Since the publication of A Guide to Chalcogen-Nitrogen Chemistry in 2005, the emphasis of investigations of chalcogen-nitrogen compounds has advanced from a focus on fundamental studies to the development of practical applications, as indicated by the title of this new edition. Pharmaceutical applications of organic sulfur-nitrogen compounds include drugs for the treatment of various diseases, as well as probes for locating tumour cells. From a materials perspective, carbon-containing chalcogen-nitrogen heterocycles have applications in everyday devices such as LEDs and solar cells. A new technology based on binary sulfur nitrides is being used for fingerprint detection in forensic science. As a result, this book includes seven new chapters and updates the others with extensive literature coverage of developments since 2005 while retaining earlier seminal results. This comprehensive text is essential for anyone working in the field, and the four introductory chapters emphasise general concepts that will be helpful to the non-specialist. The treatment is unique in providing a comparison of sulfur, selenium and tellurium compounds. Each chapter is designed to be self-contained, and there are extensive cross-references between chapters.