William T. Coffey - Böcker

This series provides the chemical physics field with a forum for critical, authoritative evaluations of advances in every area of the discipline. Fractals, Diffusion, and Relaxation in Disordered Complex Systems is a special guest-edited, two-part volume of Advances in Chemical Physics that continues to report recent advances with significant, up-to-date chapters by internationally recognized researchers. This special volume includes chapters on: Dielectic Relaxation Phenomena in Complex MaterialsEvolution of the Dynamic Susceptibility in Super-Cooled Liquids and GlassesSlow Relaxation, Anomalous Diffusion, and Aging in Equilibrated or Non-equilibrated EnvironmentsAging and Non-Ergodicity Behavior of Blinking Quantum DotThe Continuous Time Random Walk Versus the Generalized Master Equation

Fractals, Diffusion, and Relaxation in Disordered Complex Systems is a special guest-edited, two-part volume of Advances in Chemical Physics that continues to report recent advances with significant, up-to-date chapters by internationally recognized researchers.

Fractals, Diffusion and Relaxation in Disordered Complex Systems is a special guest-edited, two-part volume of Advances in Chemical Physics that continues to report recent advances with significant, up-to-date chapters by internationally recognized researchers.

The book is suitable for a lecture course on the theory of Brownian motion, being based on final year undergraduate lectures given at Trinity College, Dublin. Topics that are discussed include: white noise; the Chapman-Kolmogorov equation — Kramers-Moyal expansion; the Langevin equation; the Fokker-Planck equation; Brownian motion of a free particle; spectral density and the Wiener-Khintchin theorem — Brownian motion in a potential application to the Josephson effect, ring laser gyro; Brownian motion in two dimensions; harmonic oscillators; itinerant oscillators; linear response theory; rotational Brownian motion; application to loss processes in dielectric and ferrofluids; superparamagnetism and nonlinear relaxation processes.As the first elementary book on the Langevin equation approach to Brownian motion, this volume attempts to fill in all the missing details which students find particularly hard to comprehend from the fundamental papers contained in the Dover reprint — Selected Papers on Noise and Stochastic Processes, ed. N Wax (1954) — together with modern applications particularly to relaxation in ferrofluids and polar dielectrics.

Presenting in a coherent and accessible fashion current results in nanomagnetism, this book constitutes a comprehensive, rigorous and readable account, from first principles of the classical and quantum theories underlying the dynamics of magnetic nanoparticles subject to thermal fluctuations.Starting with the Larmor-like equation for a giant spin, both the stochastic (Langevin) equation of motion of the magnetization and the associated evolution (Fokker-Planck) equation for the distribution function of the magnetization orientations of ferromagnetic nanoparticles (classical spins) in a heat bath are developed along with their solution (using angular momentum theory) for arbitrary magnetocrystalline-Zeeman energy. Thus, observables such as the magnetization reversal time, relaxation functions, dynamic susceptibilities, etc. are calculated and compared with the predictions of classical escape rate theory including in the most general case spin-torque-transfer. Regarding quantum effects, which are based on the reduced spin density matrix evolution equation in Hilbert space as is described at length, they are comprehensively treated via the Wigner-Stratonovich formulation of the quantum mechanics of spins via their orientational quasi-probability distributions on a classically meaningful representation space. Here, as suggested by the relevant Weyl symbols, the latter is the configuration space of the polar angles. Hence, one is led, by mapping the reduced density matrix equation onto that space, to a master equation for the quasi-probability evolution akin to the Fokker-Planck equation which may be solved in a similar way. Thus, one may study in a classical-like manner the evolution of observables with spin number ranging from an elementary spin to molecular clusters to the classical limit, viz. a nanoparticle. The entire discussion hinges on the one-to-one correspondence between polarization operators in Hilbert space and the spherical harmonics allied to concepts of spin coherent states long familiar in quantum optics.Catering for the reader with only a passing knowledge of statistical and quantum mechanics, the book serves as an introductory text on a complicated subject where the literature is remarkably sparse.

This volume is the second edition of the first-ever elementary book on the Langevin equation method for the solution of problems involving the Brownian motion in a potential, with emphasis on modern applications in the natural sciences, electrical engineering and so on. It has been substantially enlarged to cover in a succinct manner a number of new topics, such as anomalous diffusion, continuous time random walks, stochastic resonance etc, which are of major current interest in view of the large number of disparate physical systems exhibiting these phenomena. The book has been written in such a way that all the material should be accessible to an advanced undergraduate or beginning graduate student. It draws together, in a coherent fashion, a variety of results which have hitherto been available only in the form of research papers or scattered review articles.

Our original objective in writing this book was to demonstrate how the concept of the equation of motion of a Brownian particle — the Langevin equation or Newtonian-like evolution equation of the random phase space variables describing the motion — first formulated by Langevin in 1908 — so making him inter alia the founder of the subject of stochastic differential equations, may be extended to solve the nonlinear problems arising from the Brownian motion in a potential. Such problems appear under various guises in many diverse applications in physics, chemistry, biology, electrical engineering, etc. However, they have been invariably treated (following the original approach of Einstein and Smoluchowski) via the Fokker-Planck equation for the evolution of the probability density function in phase space. Thus the more simple direct dynamical approach of Langevin which we use and extend here, has been virtually ignored as far as the Brownian motion in a potential is concerned. In addition two other considerations have driven us to write this new edition of The Langevin Equation. First, more than five years have elapsed since the publication of the third edition and following many suggestions and comments of our colleagues and other interested readers, it became increasingly evident to us that the book should be revised in order to give a better presentation of the contents. In particular, several chapters appearing in the third edition have been rewritten so as to provide a more direct appeal to the particular community involved and at the same time to emphasize via a synergetic approach how seemingly unrelated physical problems all involving random noise may be described using virtually identical mathematical methods. Secondly, in that period many new and exciting developments have occurred in the application of the Langevin equation to Brownian motion. Consequently, in order to accommodate all these, a very large amount of new material has been added so as to present a comprehensive overview of the subject.