Inorganic Materials Series – serie

“… the book does an excellent job of putting together several different classes of materials. Many common points emerge, and the book may facilitate the development of hybrids in which the qualities of the “parents” are enhanced.” –Angew. Chem. Int. Ed. 2011 With applications in optoelectronics and photonics, quantum information processing, nanotechnology and data storage, molecular materials enrich our daily lives in countless ways. These materials have properties that depend on their exact structure, the degree of order in the way the molecules are aligned and their crystalline nature. Small, delicate changes in molecular structure can totally alter the properties of the material in bulk.There has been increasing emphasis on functional metal complexes that demonstrate a wide range of physical phenomena. Molecular Materials represents the diversity of the area, encapsulating magnetic, optical and electrical properties, with chapters on: Metal-Based Quadratic Nonlinear Optical MaterialsPhysical Properties of MetallomesogensMolecular Magnetic MaterialsMolecular Inorganic Conductors and SuperconductorsMolecular NanomagnetsStructured to include a clear introduction, a discussion of the basic concepts and up-to-date coverage of key aspects, each chapter provides a detailed review which conveys the excitement of work in that field.Additional volumes in the Inorganic Materials Series:Low-Dimensional Solids | Molecular Materials | Porous Materials | Energy Materials

In the past few decades, the increasingly routine use of advanced structural probes for studying the structure and dynamics of the solid state has led to some dramatic developments in the field of porous solids. These materials are fundamental in a diverse range of applications, such as shape-selective catalysts for energy-efficient organic transformations, new media for pollutant removal, and gas storage materials for energy technologies. Porosity in inorganic materials may range from the nano-scale to the macro-scale, and the drive towards particular properties remains the goal in this fast-developing area of research. Covering some of the key families of inorganic solids that are currently being studied, Porous Materials discusses: Metal Organic Frameworks MaterialsMesoporous SilicatesOrdered Porous Crystalline Transition Metal OxidesRecent Developments in Templated Porous Carbon MaterialsSynthetic Silicate Zeolites: Diverse Materials Accessible Through GeoinspirationAdditional volumes in the Inorganic Materials Series:Low-Dimensional Solids | Molecular Materials | Functional Oxides | Energy Materials

Functional oxides have a wide variety of applications in the electronic industry. The discovery of new metal oxides with interesting and useful properties continues to drive much research in chemistry, physics, and materials science. In Functional Oxides five topical areas have been selected to illustrate the importance of metal oxides in modern materials chemistry: Noncentrosymmetric Inorganic Oxide MaterialsGeometrically Frustrated Magnetic MaterialsLithium Ion Conduction in OxidesThermoelectric OxidesTransition Metal Oxides - Magnetoresistance and Half-MetallicityThe contents highlight structural chemistry, magnetic and electronic properties, ionic conduction and other emerging areas of importance, such as thermoelectricity and spintronics.Functional Oxides covers these complex concepts in a clear and accessible manner providing an excellent introduction to this broad subject area.

With physical properties that often may not be described by the transposition of physical laws from 3D space across to 2D or even 1D space, low-dimensional solids exhibit a high degree of anisotropy in the spatial distribution of their chemical bonds. This means that they can demonstrate new phenomena such as charge-density waves and can display nanoparticulate (0D), fibrous (1D) and lamellar (2D) morphologies. This text presents some of the most recent research into the synthesis and properties of these solids and covers: Metal Oxide NanoparticlesInorganic Nanotubes and NanowiresBiomedical Applications of Layered Double HydroxidesCarbon Nanotubes and Related StructuresSuperconducting BoridesIntroducing topics such as novel layered superconductors, inorganic-DNA delivery systems and the chemistry and physics of inorganic nanotubes and nanosheets, this book discusses some of the most exciting concepts in this developing field.Additional volumes in the Inorganic Materials Book Series:Molecular MaterialsFunctional OxidesPorous MaterialsEnergy MaterialsAll volumes are sold individually or as comprehensive 5 Volume Set.

In an age of global industrialisation and population growth, the area of energy is one that is very much in the public consciousness. Fundamental scientific research is recognised as being crucial to delivering solutions to these issues, particularly to yield novel means of providing efficient, ideally recyclable, ways of converting, transporting and delivering energy. This volume considers a selection of the state-of-the-art materials that are being designed to meet some of the energy challenges we face today. Topics are carefully chosen that show how the skill of the synthetic chemist can be applied to allow the targeted preparation of inorganic materials with properties optimised for a specific application.Four chapters explore the key areas of: Polymer ElectrolytesAdvanced Inorganic Materials for Solid Oxide Fuel CellsSolar Energy MaterialsHydrogen Adsorption on Metal Organic Framework Materials for Storage ApplicationsEnergy Materials provides both a summary of the current status of research, and an eye to how future research may develop materials properties further.Additional volumes in the Inorganic Materials Series:Molecular MaterialsFunctional OxidesPorous MaterialsLow-Dimensional Solids

Inorganic materials are at the heart of many contemporary real-world applications, in electronic devices, drug delivery, bio-inspired materials and energy storage and transport. In order to underpin novel synthesis strategies both to facilitate these applications and to encourage new ones, a thorough review of current and emerging techniques for materials characterisation is needed.Examining important techniques that allow investigation of the structures of inorganic materials on the local atomic scale, Local Structural Characterisation discusses:  Solid-State NMR SpectroscopyX-Ray Absorption and Emission SpectroscopyNeutrons and Neutron SpectroscopyEPR Spectroscopy of Inorganic MaterialsAnalysis of Functional Materials by X-Ray Photoelectron SpectroscopyThis addition to the Inorganic Materials Series provides a detailed and thorough review of these spectroscopic techniques and emphasises the interplay between chemical synthesis and physical characterisation.

Inorganic materials show a diverse range of important properties that are desirable for many contemporary, real-world applications. Good examples include recyclable battery cathode materials for energy storage and transport, porous solids for capture and storage of gases and molecular complexes for use in electronic devices. An understanding of the function of these materials is necessary in order to optimise their behaviour for real applications, hence the importance of 'structure–property relationships'.The chapters presented in this volume deal with recent advances in the characterisation of crystalline materials. They include some familiar diffraction methods, thoroughly updated with modern advances. Also included are techniques that can now probe details of the three-dimensional arrangements of atoms in nanocrystalline solids, allowing aspects of disorder to be studied. Small-angle scattering, a technique that is often overlooked, can probe both ordered and disordered structures of materials at longer length scales than those probed by powder diffraction methods.Addressing both physical principals and recent advances in their applications, Structure from Diffraction Methods covers:  Powder DiffractionX-Ray and Neutron Single-Crystal DiffractionPDF Analysis of NanoparticlesElectron CrystallographySmall-Angle ScatteringIdeal as a complementary reference work to other volumes in the series (Local Structural Characterisation and Multi Length-Scale Characterisation), or as an examination of the specific characterisation techniques in their own right, Structure from Diffraction Methods is a valuable addition to the Inorganic Materials Series.

Showcasing recent developments in inorganic materials in an area of societal interest and importance, this book provides an up-to-date introduction to the contemporary use of functional solids in emerging technologies. Energy Storage and Conversion Materials describes the application of inorganic materials in the storage and conversion of energy, with an emphasis on how solid-state chemistry allows development of new functional solids for energy applications. Dedicated chapters cover co-electrolysis, low temperature fuel cells, oxide thermoelectric devices for energy conversion, solid-state Li batteries and thermochemical energy conversion. Edited and written by world-renowned scientists, this book will provide a comprehensive introduction for advanced undergraduates, postgraduates and researchers wishing to learn about the topic.

Energy is an important area of contemporary research, with clear societal benefits. It is a fast-developing and application-driven research area, with chemistry leading the discovery of new solids, which are then studied by physicists and materials scientists.Solar Energy Capture Materials introduces a range of the different inorganic materials used, with an emphasis on how solid-state chemistry allows development of new functional solids for energy applications. Dedicated chapters cover silicon-based photovoltaic devices, compound semiconductor-based solar cells, dye-sensitized solar cells (DSC), solution processed solar cells and emerging materials.Edited and written by world-renowned scientists, this book will provide a comprehensive introduction for advanced undergraduates, postgraduates and researchers wishing to learn about the topic.

Using inorganic solid adsorbents/sorbents is a promising approach for carbon dioxide (CO2) capture and is attracting intense attention from both academic and industrial fields.Pre-combustion Carbon Dioxide Capture Materials presents a range of the different inorganic materials that can be used as pre-combustion CO2 adsorbents/sorbents with specific emphasis on their design, synthesis, characterization, performance, and mechanism. Dedicated chapters cover layered double hydroxide (LDH) derived adsorbents, MgO-based adsorbents, CaO-based sorbents and alkali ceramics based sorbents. Edited and written by world-renowned scientists in each class of CO2 capture material, this book will provide a comprehensive introduction for advanced undergraduates, postgraduates and researchers wishing to learn about the topic.

Inorganic solid adsorbents/sorbents are attractive materials for capturing carbon dioxide (CO2) from flue gases after fossil fuel combustion.Post-combustion Carbon Dioxide Capture Materials introduces the key inorganic materials used as adsorbents/sorbents with specific emphasis on their design, synthesis, characterization, performance, and mechanism. Dedicated chapters cover carbon-based adsorbents, zeolite- and silica-based adsorbents, metal–organic framework (MOF)-based adsorbents, and alkali-metal-carbonate-based adsorbents. The final chapter discusses the practical application aspects of these adsorbents used in carbon dioxide capture from flue gases.Edited and written by world-renowned scientists in each class of the specific material, this book will provide a comprehensive introduction for advanced undergraduates, postgraduates and researchers from both academic and industrial fields wishing to learn about the topic.

The development of novel materials whose structure, properties or function are inspired by nature or living matter is a wide and dynamically evolving field. There is virtually no field of scientific endeavour that has not felt the touch of the ‘bioinspired’ ethos. Bioinspired Inorganic Materials provides an up-to-date review of the research, with some historical context. The emphasis throughout is on how bioinspiration is being used for cutting-edge applications. Chapters in the book cover big breakthroughs in bioinspiration for energy applications, surface technology, metamaterials and ceramics for regenerative medicine. Edited and written by world-renowned scientists, this book will provide a comprehensive introduction for advanced undergraduates, postgraduates and researchers wishing to learn about the topic.

This book provides a contemporary research-led overview of the applications of inorganic materials in biomedicine. It begins with a short introduction summarising key concepts in inorganic materials (layered materials, framework materials etc.), and explaining the need for new materials in medicine. It then discusses the key areas in which inorganic materials have been applied, considering: drug delivery; imaging; diagnostics and theranostics; hard matter restoration; and vaccines. Each chapter gives an overview of the major extant challenges in the research area, before presenting a systematic review of how inorganic materials have been applied to gain traction in the field. A clear focus is maintained on the fate of the applied materials in vivo, clinical considerations, and the path to translation from lab to clinic. With contributions from leading researchers, Biomedical Applications of Inorganic Materials will provide a comprehensive introduction for advanced undergraduates, postgraduates and researchers wishing to learn about the topic.

Biomaterials offer the potential to restore and supplement the function of tissues and organs following injury or disease. The use of inorganic materials in the clinic to date has been widespread, in the form of metallic joint replacements and ceramic dental and bone implants. Exciting new medical applications continue to emerge, enabled by innovative materials for neural interfaces and as anti-fouling agents. The Chemistry of Inorganic Biomaterials overviews the underlying chemistry behind the most common and cutting-edge inorganic materials in current use, or approaching use, in vivo. Framed from the context of the overarching material class/application, it provides a balanced and critical overview of the field by bringing together experts in both the fundamental inorganic and material chemistry, as well as key clinical considerations for biomedical applications. Written in an accessible style, this book will be of interest to advanced undergraduates, postgraduates and researchers in biomaterials, inorganic materials and materials chemistry.

Thermoelectric devices convert a heat flux directly into electrical power. They afford opportunities to achieve efficiency savings in a variety of applications, through the conversion of otherwise waste heat into useful electrical energy. Operated in reverse mode, they provide effective thermal management in areas ranging from cooling of electronic components to battery conditioning in electric vehicles. Implementation of thermoelectric technology requires materials with improved performance and stability, containing readily-available and inexpensive elements. A range of thermoelectric materials for use in different temperature regimes has emerged. Knowledge of the complex relationship between composition, structure and physical properties is central to understanding the performance of these advanced materials.This book provides both an introduction to the field of thermoelectrics and a survey of the state-of-the-art. Chapters review the important new families of advanced materials that have emerged and taken the field beyond traditional thermoelectric materials such as Bi2Te3, PbTe and SiGe. The emphasis is on the relationship between chemical composition, structure over a range of length scales and the physical properties that underlie performance. Edited by a leader in the field, and with contributions from global experts, Inorganic Thermoelectric Materials serves as an introduction to thermoelectric materials and is accessible to advanced undergraduates and postgraduates, as well as experienced researchers

Inorganic nanomaterials are an extremely broad and versatile class of materials and their enhanced chemical, thermal and mechanical stability with respect to their organic counterparts make them appealing candidates for a wide range of technological applications. Recent research has explored novel synthesis routes relying on non-standard conditions and in many cases, these unconventional routes are inherently sustainable. This book will provide a much needed overview of the fast-developing areas of green synthesis of metal nanoparticles, metal oxides and metal sulphides. These have a broad range of applications, including in catalysis, electronics, optics and nanomedicine. It will also show how it is possible to combine environmental and economical sustainability and will provide readers with a state-of-the-art and updated overview of lesser-known and emerging synthesis routes for inorganic nanomaterials. Suitable for advanced undergraduates, postgraduates and other researchers, it provides a convenient introduction to the topic.

Functional, flexible and lightweight products are in high demand for modern technologies ranging from microelectronics to energy storage devices. The majority of polymers are thermal and electrical insulators, which hinder their use in these applications. The conductivity of polymers can be significantly enhanced by the incorporation of conducting inorganic nanoparticles. However, this relies not only on the structure and function of the inorganic particles, but is highly determined by the morphology and dispersion of the nanoparticles, interfacial interactions and fabrication technologies of the composites. This book highlights the synthesis, chemistry and applications of two-dimensional (2D) inorganic nanoplatelets in polymer nanocomposites. Chapters cover technical challenges, such as surface functionalisation, compatibilization, interfacial interaction, dispersion, and manufacturing technologies of the polymer nanocomposites. The book also discusses the applications of these polymer nanocomposites in electronics and energy storage. With contributions from global experts, the book provides a much-needed overview of the field, giving advanced undergraduates, postgraduates and other researchers with a convenient introduction to the topic.

Computer Simulation of Porous Materials covers the key approaches in the modelling of porous materials, with a focus on how these can be used for structure prediction and to either rationalise or predict a range of properties including sorption, diffusion, mechanical, spectroscopic and catalytic. The book covers the full breadth of (micro)porous materials, from inorganic (zeolites), to organic including porous polymers and porous molecular materials, and hybrid materials (metal-organic frameworks). Through chapters focusing on techniques for specific types of applications and properties, the book outlines the challenges and opportunities in applying approaches and methods to different classes of systems, including a discussion of high-throughput screening. There is a strong forward-looking focus, to identify where increased computer power or artificial intelligence techniques such as machine learning have the potential to open up new avenues of research. Edited by a world leader in the field, this title provides a valuable resource for not only computational researchers, but also gives an overview for experimental researchers. It is presented at a level accessible to advanced undergraduates, postgraduates and researchers wishing to learn more about the topic.

MOFs for Gas Adsorption and Separation explores the cutting-edge world of metal–organic frameworks (MOFs), showcasing their transformative potential in gas storage and separation. This comprehensive guide explores the chemical and structural versatility of MOFs, highlighting their applications in capturing pollutants, CO2, hydrocarbons, and water. With contributions from leading experts, the book offers a fundamental overview of MOF materials, their exceptional sorption properties, and the host–guest chemistry that drives their functionality. Ideal for advanced undergraduates, postgraduates, and researchers, this essential resource provides a historical context and a detailed examination in the context of contemporary inorganic materials science. Whether you're a scientist, engineer, or student, this book is your gateway to understanding the fast-developing field of MOFs and their impact on materials, energy, and the environment.

Photoactive coordination complexes of the transition metal elements have long been of interest, with the last few decades seeing a wealth of studies dedicated to their photophysical properties and excited state behaviour. Light-driven applications for these materials are now being realised, such as light-emitting devices, biological imaging probes, and novel chemotherapy agents.This book focusses on the methods of study and applications of photoactive coordination complexes of the d-block elements. The reader will be introduced to the initial design and fundamental photophysical properties of these molecules, before learning how these molecules have been adapted, developed and utilised within a variety of real-world devices, materials and applications. This book will also provide the reader with a clear vision for the future and the remaining challenges that lie ahead in the further development of light-activated functional materials.

Applications of Neutron Scattering to Inorganic Materials offers a comprehensive introduction to a powerful suite of neutron scattering techniques that underpin modern inorganic materials research. Edited by Dr Lucy Clark (University of Birmingham), this volume brings together leading experts to explore how neutron-based methods reveal critical insights into structure–property–function relationships across a diverse range of materials. From neutron diffraction and total scattering to quasi-elastic and inelastic neutron spectroscopy, each chapter presents a pedagogical overview of the technique, recent advances in instrumentation, and its application to contemporary materials challenges—including magnetism, catalysis, and energy materials. Designed for advanced undergraduates, postgraduates, and researchers entering the field, this book fills a critical gap in the literature, integrating fundamental principles with cutting-edge research. It is an essential resource for those seeking to understand and apply neutron scattering in the context of inorganic materials chemistry.

Two-dimensional (2D) materials for photocatalytic applications have attracted attention in recent years due to their unique thickness-dependent physiochemical properties. 2D materials offer enhanced functionality over traditional three-dimensional (3D) photocatalysts due to modified chemical composition and electronic structures, as well as abundant surface active sites. This book reviews the applications of 2D-related nano-materials in solar-driven catalysis, providing an up-to-date introduction to the design and use of 2D-related photo(electro)catalysts. This includes not only application areas such as fine chemicals synthesis, water splitting, CO2 reduction, and N2 fixation, but also catalyst design and preparation. Some typical 2D and 2D-related materials (such as layered double hydroxides (LDHs), layered metal oxides, transition metal dichalcogenide (TMDs), metal–organic frameworks (MOFs), graphene, g-C3N4, etc.) are classified, and relationships between structure and property are demonstrated, with emphasis on how to improve 2D-related materials performance for practical applications. While the focus of this book will primarily be on experimental studies, computational results will serve as a necessary reference. With chapters written by expert researchers in their fields, Photocatalysis Using 2D Nanomaterials will provide advanced undergraduates, postgraduates and other researchers convenient introductions to these topics.

Much of traditional solid state chemistry invokes changes in the structures and properties of solids via addition or substitution of cations. In the vast majority of cases, the anion remains a constant, and due in part to the ubiquity of oxygen, that anion is oxide. This book considers the role and importance of pnictides, chalcogenides, carbides and halides, among others, in redefining modern solid state materials chemistry. The true flexibility of the anion is explored in a summary of heteroanionic (“mixed anion”) materials in which two or more anions can be incorporated in crystalline structures, either “ab initio” or via doping and substitution. The concept of “pseudo oxides” (where compounds with multiple anions isoelectronic to O2- can be designed) is explored. Throughout, the onus of the volume is on linking fundamental solid state chemistry with properties, performance and applications to illustrate how useful - and sometimes unique - materials can be designed “beyond oxides”.Written in an accessible style, Non-oxide and Heteroanionic Materials provides a valuable resource for advanced undergraduates and postgraduates across solid state chemistry, catalysis and materials science, as well as researchers looking for an introduction to the subject.

In the first book dedicated to this rapidly expanding research area, Mechanical Behaviour of Metal-Organic Framework Materials, provides a convenient introduction to how chemistry determines structure-mechanical property relationships and functional performance. Much of the research efforts in metal-organic framework (MOF) and hybrid framework materials focus on synthesis and adsorption related properties. But practical applications of MOFs require a precise understanding of mechanical properties and knowledge of structure-property relationships, to ensure robustness in device manufacturing and mechanical resilience for long-term performance. Readers will learn through key experimental and theoretical techniques for studying MOF mechanical properties including elastic and plastic behaviour, framework dynamics, high-pressure response, rate effects, anomalous mechanical behaviour and failure mechanisms. Edited by a pioneer of the field and with contributions by leading researchers developing the new science of “MOF Mechanics”, this book is suitable for both students and researchers who are new to the field.

The science of carbon materials has experienced a renaissance in recent decades, with Nobel prizes having been awarded for the discovery of C60 in 1996, and graphene in 2010. Other areas of carbon science have also flourished, with notable advances having been made in the synthesis of diamond by chemical vapour deposition and in the preparation and applications of carbon dots.Elemental Carbon provides an overview of the most rapidly developing areas of contemporary carbon science, including both well-established materials such as graphite and carbon black and new forms such as graphene. As well as giving a brief history of each topic, the five chapters provide reviews of the latest research, covering synthesis, chemical and physical properties, and applications.Aimed at advanced undergraduates, postgraduates and other researchers in academia and industry, this book provides an invaluable introduction to these increasingly important materials.

Flexible metal–organic frameworks (MOFs) are a unique class of porous materials that feature stimuli-responsive flexible structures and dynamic structural transformation behaviours. Exhibiting structural changes in response to physical or chemical stimuli creates related functions that can be developed for practical applications. The specific components and architectures of flexible MOFs are key to their unique properties, so understanding their chemistry is of critical importance for more targeted construction and functional research. This book provides an accessible overview of the historical background of the chemistry of flexible MOFs and their features; in particular, design and synthesis, dynamic structure analysis, flexibility, function and theoretical treatment, and interpretation of the mechanisms as well as their applications. It gives readers a fundamental understanding of this chemistry and will be of great help to young researchers, as well as those already familiar with conventional porous materials in creating new materials.