Series On Neutron Techniques And Applications - Böcker

Modulation spectrometry of neutrons refers to a measuring principle, characterized by classification of neutron histories in a probabilistic way, not the usual deterministic way. In order to accomplish this, neutron beams entering the sample are modulated by high-transmission, white-beam selectors of the multislit type, such as Fourier or statistical choppers or high-frequency-modulated spin-flippers. In this scheme it is impossible to decide in a unique way through which particular slit any single neutron passed, but the distribution of histories for a large population of neutrons can nevertheless be correctly obtained, by classifying each conceivable history either as a high-probability or as a low-probability event, based on the actual observed state of the neutron selector. So far the principle has been successfully applied to powder diffraction, but it seems to offer extra degrees of freedom if applied to measuring dispersion curves of coherent excitations, such as phonons in single crystals.

This important book presents a comprehensive account of the techniques and applications of single crystal neutron diffraction in the area of chemical crystallography and molecular structure. Beginning with a brief description of the general principles and the reasons for choosing the technique — the “why” — the book covers the methods for both the production of neutrons and the measurement of their scattering by molecular crystals — the “how” — followed by a detailed survey of past, present and future applications — the “what”. The coverage of both steady state and pulsed neutron sources and instrumentation is extensive, while the survey of applications is the most comprehensive yet undertaken. The book endeavours to show why the technique is an essential method for studying areas as diverse as hydrogen bonding and weak interactions, organometallics, supramolecular chemistry and crystal engineering, metal hydrides, charge density and pharmaceuticals. It is an ideal reference source for the research worker interested in using neutron diffraction to study the structure of molecules.

Neutron scattering has become a key technique for investigating the properties of materials on an atomic scale. The uniqueness of this method is based on the fact that the wavelength and energy of thermal neutrons ideally match interatomic distances and excitation energies in condensed matter, and thus neutron scattering is able to directly examine the static and dynamic properties of the material. In addition, neutrons carry a magnetic moment, which makes them a unique probe for detecting magnetic phenomena.In this important book, an introduction to the basic principles and instrumental aspects of neutron scattering is provided, and the most important phenomena and materials properties in condensed matter physics are described and exemplified by typical neutron scattering experiments, with emphasis on explaining how the relevant information can be extracted from the measurements.

Neutron scattering has become a key technique for investigating the properties of materials on an atomic scale. The uniqueness of this method is based on the fact that the wavelength and energy of thermal neutrons ideally match interatomic distances and excitation energies in condensed matter, and thus neutron scattering is able to directly examine the static and dynamic properties of the material. In addition, neutrons carry a magnetic moment, which makes them a unique probe for detecting magnetic phenomena.In this important book, an introduction to the basic principles and instrumental aspects of neutron scattering is provided, and the most important phenomena and materials properties in condensed matter physics are described and exemplified by typical neutron scattering experiments, with emphasis on explaining how the relevant information can be extracted from the measurements.