Sustainable Chemistry Series - Böcker

This book investigates the development of sorption-enhanced reaction processes (SERPs) with detailed modeling and simulation, design and operation of units. SERPs are processes intensified by combining adsorption and reaction, reaction and membranes or reaction/adsorption/membranes in a single unit in order to overcome thermodynamic limitations of conversion in reversible reactions. The focus here is on gas phase and liquid phase processes involving different technologies, including pressure swing adsorptive reactors, membrane reactors and simulated moving bed reactors. Emphasis is also given to presenting data and practical applications of SERP products.Sorption-Enhanced Reaction Processes provides undergraduate and graduate students of chemistry and chemical engineering, researchers and industrial engineers with a clear path towards process development of SERP, whatever the area of application.

There is a wide consensus that furfural, a renewable commodity currently obtained from lignocellulosic agro-residues with a production volume of around 300 kTon per year, is a key feedstock for leveraging lignocellulosic residues in future biorefineries. Several chemicals are already being manufactured from furfural due to its advantageous production cost. Furthermore, a vast number of others are also technically viable, to produce from oil.This book compiles the vast existing information into relevant stages of transformations of furfural as renewable chemicals, biofuels and bioresins focusing on the relevant chemical and engineering aspects of processes to obtain them, including reactors and catalysis. It offers essential information for improving the economic and environmental viability of current commercial applications and upcoming future applications.It should be of particular interests to graduate and advanced undergraduate students, as well as, engineers and academic researchers alike who are working in the field.

Lignin is one of the most abundant plant-derived feedstock on earth and qualifies as a renewable material. However, lignin is widely recognized as waste byproduct of the cellulosic ethanol and pulp and paper industry. How to properly modify lignin and develop it into functional polymers is a huge challenge, but an attractive research topic in both industry and academia.This book brings together leading engineering approaches to address the challenges of lignin valorization. It presents the chemistry and properties of different types of lignin, and explores the cutting-edge approaches of lignin modifications. Unlike any existing texts, this book not only summarizes the traditional ways of using lignin, but also presents various potential applications of lignin materials together with advanced processing techniques.The basis of lignin (its chemistry, types and properties) is described, as are different approaches to modify it. The features of lignin and its copolymers are explored and aligned with their potential applications. In addition to the carbon materials from lignin, the advanced fabrication approaches to engineer lignin-based micro/nano-structural materials are summarized.

Currently the field of nanocatalysis is undergoing many exciting developments and the design of silica-based organic-inorganic hybrid nanocatalysts is a key focus of the researchers working in this field.This book aims to present a succinct overview of the recent research progress directed towards the fabrication of silica-based organic-inorganic hybrid catalytic systems encompassing the key advantages of silica nanoparticles and silica-coated magnetic nanoparticles in an integrated manner. Featuring comprehensive descriptions of almost all approaches utilized for the synthesis of nanomaterials including some latest techniques such as flow and microwave-assisted synthesis that enable large-scale synthesis, it proves useful not only to academics but also industrialists. It also includes a systematic discussion on the vital characterization techniques employed for authenticating the structure of these.The title also offers an enormous amount of knowledge about the fusion of nanotechnology with green chemistry that strives to meet the scientific challenges of protecting human health and the environment.

The term "green chemistry" was coined by Anastas and Warner in the early 1990s and it is nowadays the mainstay of designing and implementing advanced chemical processes that decrease or eliminate the use and generation of hazardous substances whilst minimizing energy consumption.Solution Combustion Synthesis of Nanostructured Solid Catalysts for Sustainable Chemistry is an interdisciplinary collection of fundamental and applied cutting-edge studies which highlight general and specific aspects of the synthesis of nanostructured catalysts through Solution Combustion Synthesis (SCS), studying their applications from the perspective of green chemistry.This book intends to integrate the fundamental principles of the SCS process with its engineering aspects and covers the synthesis of a wide variety of catalytic materials. This reference book can be used as a permanent consulting material for students, researchers and the general readership for green chemistry, nanochemistry, materials science and chemical engineering.

First-generation ethanol plants did not have many operational challenges as the feedstocks (e.g., corn) used for fuel production are dense, stable, storable, and shippable commodity-type products with fewer conversion challenges. These feedstock properties led the first-generation large-scale biorefineries to grow exponentially. In the second-generation biofuels, the feedstocks used are agricultural and forest residues, dedicated energy crops, industrial wastes, and municipal solid waste. When the industry tested these feedstocks for biofuel production, they faced flowability, storage, transportation, and conversion issues. One way to overcome some of the feeding, handling, transportation, and variable moisture challenges is to densify the biomass. Pellet mills and briquette presses are commonly used to produce densified products. The densified products have uniform size, shape, higher bulk density, and better downstream conversion performance. Also, the densified products are aerobically stable and can be stored for longer durations without any loss in quality.This book's focus is on understanding how the densification process variables, biomass types and their blends, mechanical preprocessing, and thermal and chemical pretreatment methods impact the quality of the densified products produced for biofuel production. Finally, the book also explores the conversion performance of densified biomass for biofuel production.