NAROTTAM P. BANSAL, NASA Glenn Research CenterPRABHAKAR SINGH, University of Connecticut

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• Preface ix Introduction xiCELL/STACK DEVELOPMENTRecent Development of SOFC Cell and Stack at NTT 3Reiichi Chiba, Hiroaki Taguchi, Takeshi Komatsu, Himeko Orui, Kazuhiko Nozawa, Kimitaka Watanabe, Yoshiteru Yoshida, Masayuki Yokoo, Akihiro Miyasaka, Hajime Arai, and Katsuya HayashiInvestigation of the Effects of NiO-ScSZ-Layer Insertion on the Current Collection and Catalytic Properties of ScSZ-based Micro-Tubular SOFC 15Toshiaki Yamaguchi and Nigel SammesELECTROLYTESEffect of Dopants on Ce02 Based Solid State Electrolytes for Intermediate Temperature Electrochemical Devices 23E. Yu. Pikalova, A. K. Demin, V. G. Bamburov, V. I. Maragou, and P. E. TsiakarasELECTRODESElectrochemical Phenomena in MEA Electrodes 37Mihails Kusnezoff, Nikolai Trofimenko, and Alexander MichaelisThe Effect of A-Site Stoichiometry on LSCF Cathode Performance and Stability 61Jared Templeton, John Hardy, Zigui Lu, and Jeff StevensonInfluence of Operational Parameters on LSCF and LSF Stability 67Amaia Arregui, Lide M. Rodriguez-Martinez, Stefano Modena, Jan van Herle, Massimo Bertoldi, and Vincenzo M. SglavoAssessment of the Electrochemical Properties of BSCF and Samarium Doped BSCF Perovskites 77Keling Zhang, Alex Lassman, Atul Verma, and Prabhakar SinghRole of Sintering Atmosphere on the Stability of LSM-YSZ Composite 89Manoj Mahapatra and Prabhakar SinghINTERCONNECTSCrofer22 APU in Real SOFC Stacks 101Qingping Fang, Mario Heinrich, and Christian WunderlichAssessment of Chromium Evaporation from Chromia and Alumina Forming Alloys 115Sanjit Bhowmick, Gavin Le, Atul Verma, and Prabhakar SinghEffect of Chromium Doping on the Crystal Structure, Electrical Conductivity and Thermal Expansion of Manganese Cobalt Spinel Oxides 125Yingjia Liu, Kangli Wang, and Jeffrey W. FergusEffect of Metallic Interconnect Thickness on its Long-Term Performance in SOFCs 131Wenning Liu, Xin Sun, Liz Stephens, and Moe KhaleelCharacterization of the Conductive Protection Layers on Alloy Interconnect for SOFC 139Xiaojia Du, Minfang Han, and Ze LeiNOVEL CELL/STACK DESIGN AND PROCESSINGAdvanced Manufacturing Technology for Solid Oxide Fuel Cells 149Norbert H. Menzler, Wolfgang Schafbauer, Robert Mücke, Ralf Kauert, Oliver Büchler, Hans Peter Buchkremer, and Detlev StöverProduction of Current Collector-Supported Micro-Tubular Solid Oxide Fuel Cells with Sacrificial Inner Core 161Ricardo De la Torre, Michèle Casarin, and Vincenzo M. SglavoRELIABILITY/DEGRADATIONNumerical Modeling of Cathode Contact Material Densification 171Brian J. Koeppel, Wenning Liu, Elizabeth V. Stephens, and Moe A. KhaleelObservations on the Air Electrode-Electrolyte Interface Degradation in Solid Oxide Electrolysis Cells 183Michael Keane, Atul Verma, and Prabhakar SinghFUEL REFORMINGCarbon Dioxide Reforming of Methane for Solid Oxide Fuel Cells 195Mitsunobu Kawano, Hiroyuki Yoshida, Koji Hashino, and Toru InagakiAuthor Index 207

NAROTTAM P. BANSAL, NASA Glenn Research CenterPRABHAKAR SINGH, University of Connecticut

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• Preface ix Introduction xiCELL/STACK DEVELOPMENTRecent Development of SOFC Cell and Stack at NTT 3Reiichi Chiba, Hiroaki Taguchi, Takeshi Komatsu, Himeko Orui, Kazuhiko Nozawa, Kimitaka Watanabe, Yoshiteru Yoshida, Masayuki Yokoo, Akihiro Miyasaka, Hajime Arai, and Katsuya HayashiInvestigation of the Effects of NiO-ScSZ-Layer Insertion on the Current Collection and Catalytic Properties of ScSZ-based Micro-Tubular SOFC 15Toshiaki Yamaguchi and Nigel SammesELECTROLYTESEffect of Dopants on Ce02 Based Solid State Electrolytes for Intermediate Temperature Electrochemical Devices 23E. Yu. Pikalova, A. K. Demin, V. G. Bamburov, V. I. Maragou, and P. E. TsiakarasELECTRODESElectrochemical Phenomena in MEA Electrodes 37Mihails Kusnezoff, Nikolai Trofimenko, and Alexander MichaelisThe Effect of A-Site Stoichiometry on LSCF Cathode Performance and Stability 61Jared Templeton, John Hardy, Zigui Lu, and Jeff StevensonInfluence of Operational Parameters on LSCF and LSF Stability 67Amaia Arregui, Lide M. Rodriguez-Martinez, Stefano Modena, Jan van Herle, Massimo Bertoldi, and Vincenzo M. SglavoAssessment of the Electrochemical Properties of BSCF and Samarium Doped BSCF Perovskites 77Keling Zhang, Alex Lassman, Atul Verma, and Prabhakar SinghRole of Sintering Atmosphere on the Stability of LSM-YSZ Composite 89Manoj Mahapatra and Prabhakar SinghINTERCONNECTSCrofer22 APU in Real SOFC Stacks 101Qingping Fang, Mario Heinrich, and Christian WunderlichAssessment of Chromium Evaporation from Chromia and Alumina Forming Alloys 115Sanjit Bhowmick, Gavin Le, Atul Verma, and Prabhakar SinghEffect of Chromium Doping on the Crystal Structure, Electrical Conductivity and Thermal Expansion of Manganese Cobalt Spinel Oxides 125Yingjia Liu, Kangli Wang, and Jeffrey W. FergusEffect of Metallic Interconnect Thickness on its Long-Term Performance in SOFCs 131Wenning Liu, Xin Sun, Liz Stephens, and Moe KhaleelCharacterization of the Conductive Protection Layers on Alloy Interconnect for SOFC 139Xiaojia Du, Minfang Han, and Ze LeiNOVEL CELL/STACK DESIGN AND PROCESSINGAdvanced Manufacturing Technology for Solid Oxide Fuel Cells 149Norbert H. Menzler, Wolfgang Schafbauer, Robert Mücke, Ralf Kauert, Oliver Büchler, Hans Peter Buchkremer, and Detlev StöverProduction of Current Collector-Supported Micro-Tubular Solid Oxide Fuel Cells with Sacrificial Inner Core 161Ricardo De la Torre, Michèle Casarin, and Vincenzo M. SglavoRELIABILITY/DEGRADATIONNumerical Modeling of Cathode Contact Material Densification 171Brian J. Koeppel, Wenning Liu, Elizabeth V. Stephens, and Moe A. KhaleelObservations on the Air Electrode-Electrolyte Interface Degradation in Solid Oxide Electrolysis Cells 183Michael Keane, Atul Verma, and Prabhakar SinghFUEL REFORMINGCarbon Dioxide Reforming of Methane for Solid Oxide Fuel Cells 195Mitsunobu Kawano, Hiroyuki Yoshida, Koji Hashino, and Toru InagakiAuthor Index 207

NAROTTAM P. BANSAL, NASA Glenn Research CenterPRABHAKAR SINGH, University of Connecticut

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• Preface ix Introduction xiCELL/STACK DEVELOPMENTRecent Development of SOFC Cell and Stack at NTT 3Reiichi Chiba, Hiroaki Taguchi, Takeshi Komatsu, Himeko Orui, Kazuhiko Nozawa, Kimitaka Watanabe, Yoshiteru Yoshida, Masayuki Yokoo, Akihiro Miyasaka, Hajime Arai, and Katsuya HayashiInvestigation of the Effects of NiO-ScSZ-Layer Insertion on the Current Collection and Catalytic Properties of ScSZ-based Micro-Tubular SOFC 15Toshiaki Yamaguchi and Nigel SammesELECTROLYTESEffect of Dopants on Ce02 Based Solid State Electrolytes for Intermediate Temperature Electrochemical Devices 23E. Yu. Pikalova, A. K. Demin, V. G. Bamburov, V. I. Maragou, and P. E. TsiakarasELECTRODESElectrochemical Phenomena in MEA Electrodes 37Mihails Kusnezoff, Nikolai Trofimenko, and Alexander MichaelisThe Effect of A-Site Stoichiometry on LSCF Cathode Performance and Stability 61Jared Templeton, John Hardy, Zigui Lu, and Jeff StevensonInfluence of Operational Parameters on LSCF and LSF Stability 67Amaia Arregui, Lide M. Rodriguez-Martinez, Stefano Modena, Jan van Herle, Massimo Bertoldi, and Vincenzo M. SglavoAssessment of the Electrochemical Properties of BSCF and Samarium Doped BSCF Perovskites 77Keling Zhang, Alex Lassman, Atul Verma, and Prabhakar SinghRole of Sintering Atmosphere on the Stability of LSM-YSZ Composite 89Manoj Mahapatra and Prabhakar SinghINTERCONNECTSCrofer22 APU in Real SOFC Stacks 101Qingping Fang, Mario Heinrich, and Christian WunderlichAssessment of Chromium Evaporation from Chromia and Alumina Forming Alloys 115Sanjit Bhowmick, Gavin Le, Atul Verma, and Prabhakar SinghEffect of Chromium Doping on the Crystal Structure, Electrical Conductivity and Thermal Expansion of Manganese Cobalt Spinel Oxides 125Yingjia Liu, Kangli Wang, and Jeffrey W. FergusEffect of Metallic Interconnect Thickness on its Long-Term Performance in SOFCs 131Wenning Liu, Xin Sun, Liz Stephens, and Moe KhaleelCharacterization of the Conductive Protection Layers on Alloy Interconnect for SOFC 139Xiaojia Du, Minfang Han, and Ze LeiNOVEL CELL/STACK DESIGN AND PROCESSINGAdvanced Manufacturing Technology for Solid Oxide Fuel Cells 149Norbert H. Menzler, Wolfgang Schafbauer, Robert Mücke, Ralf Kauert, Oliver Büchler, Hans Peter Buchkremer, and Detlev StöverProduction of Current Collector-Supported Micro-Tubular Solid Oxide Fuel Cells with Sacrificial Inner Core 161Ricardo De la Torre, Michèle Casarin, and Vincenzo M. SglavoRELIABILITY/DEGRADATIONNumerical Modeling of Cathode Contact Material Densification 171Brian J. Koeppel, Wenning Liu, Elizabeth V. Stephens, and Moe A. KhaleelObservations on the Air Electrode-Electrolyte Interface Degradation in Solid Oxide Electrolysis Cells 183Michael Keane, Atul Verma, and Prabhakar SinghFUEL REFORMINGCarbon Dioxide Reforming of Methane for Solid Oxide Fuel Cells 195Mitsunobu Kawano, Hiroyuki Yoshida, Koji Hashino, and Toru InagakiAuthor Index 207