Introduction to Coordination Chemistry

AvPaul V. Bernhardt,Geoffrey A. Lawrance

Häftad, Engelska, 2025

Del i serien Inorganic Chemistry: A Textbook Series

990 kr

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Beskrivning

INTRODUCTION TO COORDINATION CHEMISTRY An accessible introduction to one of the primary fields of study in Inorganic Chemistry, revised to incorporate contemporary topics and applications Written in a highly readable, descriptive, and accessible style, Introduction to Coordination Chemistry examines and explains the interaction between metals and molecules that bind as ligands and the consequences of this assembly process. The book describes the chemical and physical properties and behavior of these complex assemblies and their applications. The contents of this book tell a story, taking the reader from fundamentals, including metal ions, ligands, metal-ligand bonding, and structure, to key concepts, such as stability, synthesis and mechanisms, properties, and characterization. Subsequent chapters address applications involving metals in biology, medicine, and industrial chemistry. Written by two highly qualified academics, this newly revised Second Edition of Introduction to Coordination Chemistry has been thoroughly updated to include full-color images throughout, as well as now including: Information on instrument-based experimental methods to reflect the increasing use of sophisticated, commercially available instruments in laboratory teachingAn expansion of the chapter Metals in Biology showing key developments in the vast field of metalloproteins and metalloenzymesAn updated description of polymetallic compounds and new discussions of metal-containing nanomolecules pertinent to advancements in nanotechnologyAn expanded discussion of organometallic compounds and catalysts and updating of Concept Keys to summarize key topics and further reading at the end of each chapterIntroduction to Coordination Chemistry is an ideal textbook resource for undergraduate inorganic chemistry students in their second or third year or at the intermediate level who have completed a general introductory chemistry course and are moving to a first specialist course in coordination chemistry. INORGANIC CHEMISTRY ADVANCED TEXTBOOK This series reflects the pivotal role of modern inorganic and physical chemistry in a whole range of emerging areas, such as materials chemistry, green chemistry and bioinorganic chemistry, as well as providing a solid grounding in established areas such as solid state chemistry, coordination chemistry, main group chemistry and physical inorganic chemistry.

Produktinformation

Utgivningsdatum:2025-02-13
Mått:178 x 252 x 18 mm
Vikt:794 g
Format:Häftad
Språk:Engelska
Serie:Inorganic Chemistry: A Textbook Series
Antal sidor:400
Upplaga:2
Förlag:John Wiley & Sons Inc
ISBN:9781394190713

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Mer om författaren

PAUL V. BERNHARDT is a Professor of Chemistry in the School of Chemistry and Molecular Biosciences, University of Queensland, Australia. Professor Bernhardt is a former President of the Royal Australian Chemical Institute (2014-2016) and Chair of its Inorganic Chemistry Division (2007-2010). GEOFFREY A. LAWRANCE is an Emeritus Professor of Chemistry in the College of Engineering, Science, and Environment at the University of Newcastle, Australia. Professor Lawrance has held academic and visiting positions at several national and European universities.

Innehållsförteckning

Preface ixAcknowledgments xPreamble xiAbout the Companion Website xv1 The Central Atom 11.1 Key Concepts in Coordination Chemistry 11.2 A Who’s Who of Metal Ions 61.3 Metals in Molecules 121.4 The Road Ahead 162 Complexes 202.1 The Central Metal Ion 202.2 Metal--Ligand Assembly 222.3 The Nature of Bonding in Metal Complexes 282.4 Metal--Ligand Bonding in Organometallic Chemistry -- Beyond Classical Werner Complexes 522.5 Coupling -- Polymetallic Complexes 592.6 Complex Lifetimes and Complexation Consequences 603 Ligands 633.1 Membership: Being a Ligand 633.2 Ligand Basicity 763.3 Making Choices 813.4 Polydentate Ligands 843.5 Polynucleating Ligands 863.6 Nonclassical Ligands in Organometallic Chemistry 904 Shape 954.1 Getting in Shape 954.2 Coordination Number and Shape 984.3 Influencing Shape 1144.4 Isomerism -- Real 3D Effects 1184.5 Sophisticated Shapes 1284.6 Defining Shape 1405 Stability 1435.1 Making a Stable Assembly 1435.2 Complexation -- Will It Last? 1645.3 Reaction Mechanisms 1676 Synthesis 1966.1 Molecular Creation--Ways to Make Complexes 1966.2 Core Metal Chemistry--Periodic Table Influences 1966.3 Reactions Involving the Coordination Shell 2036.4 Reactions Involving the Metal Oxidation State 2166.5 Reactions Involving Coordinated Ligands 2206.6 Organometallic Synthesis 2296.7 Nanomolecular Synthesis 2336.8 Silicate and Aluminosilicate Synthesis 2387 Properties 2447.1 Investigative Methods 2447.2 Physical Methods and Outcomes 2457.3 Probing Complexes Using Physical Methods 2508 A Complex Life 2938.1 Metal Ions in the Natural World 2939 Complexes and Commerce 3299.1 Metals in Medicine 3299.2 Medical Imaging and Diagnostics 3389.3 Analysing with Complexes 3429.4 Profiting from Complexation 3459.5 Being Green 3559.6 Complex Futures 357Concept Keys 358Further Reading 358Appendix One: Nomenclature 360Appendix Two: Molecular Symmetry: The Point Group 369Index 375