Arup K. SenGupta - Böcker

This new book explains advanced and emerging technologies for removing heavy metals from wastestreams and contaminated sites. Separation processes of this type are critical for meeting stringent regulations of priority pollutants, especially arsenic, mercury, and lead, which the text treats in depth. After explaining the chemistry of heavy metals and their transport in various media, the work offers a comprehensive analysis of strategies for separating metals from groundwater, wastewater, contaminated soils, and industrial sludges.Both the basics and the applications of techniques such as ion-exchange, specialized sorbents, novel membranes, advanced precipitates, and electrokinetic processes are presented with a view to current use and potential for future applications such as resource reuse. Information in this volume enables engineers and other investigators to adapt and select the best means to remove and, in certain instances, recover heavy metals.

This text introduces a special class of polymeric ligand exchanger (PLE) with high affinities for anionic ligands. Volume 14 discusses the potential and advantages of micro- and nanofiltration membrane processes for removal of metals; details prevailing equilibrium relationships and supporting experimental data for systems where leaching and ion exchange take place simultaneously; covers cases of uranium cation and gold cyanide anion bisorption and modelling of engineered systems.

Alternating the focus of the series each year, the new volume in the Ion Exchange and Solvent Extraction series represents the vanguard of research in ion exchange. Ion Exchange and Solvent Extraction: A Series of Advances, Volume 18 reflects the remarkable breadth of applications inspiring the latest advances, featuring carefully selected contributors in areas including catalysis, molecular imprinting, drug delivery, nanotechnology, green processes, water treatment, and pollution control.The book explores the properties of resins, synthetic polymers, and naturally occurring materials that exhibit ion exchange properties. It explains their role in synthesis reactions with experimental evidence, examples of reactions, and models. The book also provides useful data, calculations, modeling approaches, process variables, and design aspects to consider for a variety of novel applications.Ion Exchange and Solvent Extraction: A Series of Advances, Volume 18 offers an updated perspective on the current and potential capabilities of ion exchange materials in today's most cutting-edge applications.

This text introduces a special class of polymeric ligand exchanger (PLE) with high affinities for anionic ligands. Volume 14 discusses the potential and advantages of micro- and nanofiltration membrane processes for removal of metals; details prevailing equilibrium relationships and supporting experimental data for systems where leaching and ion exchange take place simultaneously; covers cases of uranium cation and gold cyanide anion bisorption and modelling of engineered systems.

"Contains a complete manual with procedures for the implementation and scaling-up of industrial extraction processes. Discusses computer-aided molecular design. Includes examples of interactive, combinatorial, construct-and-test, and mathematical programming."

Volume 17 in the Ion Exchange and Solvent Extraction series represents the vanguard of research on solvent extraction. It covers the principles of electrolyte extraction and other subjects of increasing interest to the field. This volume begins with pharmaceutical applications of supercritical fluid solvents, particularly supercritical carbon dioxide. It also contains chapters on liquid ion exchangers and relevant experiment protocols, SCF applications in drug formulation and pollution reduction, exploiting SCF as reaction media, applications of metal bis(dicarbollide) in analytical chemistry and radioactive waste treatment, and synergistic extraction of metal ions.Volume 17 discusses the ion exchange isothermal supersaturation technique, metal separation via pH-induced parametric pumping, modeling of ion exchange kinetics for ultrapure water, and the engineering of activated carbons and carbonaceous materials for removal of metal ions and organic micropollutants in water. Volume 17 cover topics that include supercritical fluid applications, applications of metal bis(dicarbollide), and synergistic extraction of metal ions.

Alternating the focus of the series each year, the new volume in the Ion Exchange and Solvent Extraction series represents the vanguard of research in ion exchange. Ion Exchange and Solvent Extraction: A Series of Advances, Volume 18 reflects the remarkable breadth of applications inspiring the latest advances, featuring carefully selected contributors in areas including catalysis, molecular imprinting, drug delivery, nanotechnology, green processes, water treatment, and pollution control.The book explores the properties of resins, synthetic polymers, and naturally occurring materials that exhibit ion exchange properties. It explains their role in synthesis reactions with experimental evidence, examples of reactions, and models. The book also provides useful data, calculations, modeling approaches, process variables, and design aspects to consider for a variety of novel applications.Ion Exchange and Solvent Extraction: A Series of Advances, Volume 18 offers an updated perspective on the current and potential capabilities of ion exchange materials in today's most cutting-edge applications.

Since the Second World War, the field of ion exchange has taken a dominant role in offering solutions to many problems in the developed and developing world. It has evolved to a wide array of applications, including mining, microelectronics, drug delivery and detection, food, fertilizers, chemical cleaning, catalysis, bioseparation, water management, environmental research and practices, and energy.The six chapters in this book represent diverse contributions from researchers around the globe who are making noticeable strides in the field in currently important areas:Brackish water desalinationRemoving boron from waterSustainable approaches for synthesizing commercially important epoxide building blocksSolid-phase heavy-metal separationSeparating concentrated ion mixtures in sorption columnsSensing toxic metalsIon Exchange and Solvent Extraction: A Series of Advances, Volume 22 provides a focused review of new materials and new processes that have developed and are rapidly growing. It describes cutting-edge research and practices in the use of ion exchange for building a cleaner, sustainable world and provides thoughtful insights on what ion exchange may do for us in the future.

Provides a comprehensive introduction to ion exchange for beginners and in-depth coverage of the latest advances for those already in the fieldAs environmental and energy related regulations have grown, ion exchange has assumed a dominant role in offering solutions to many concurrent problems both in the developed and the developing world. Written by an internationally acknowledged leader in ion exchange research and innovation, Ion Exchange: in Environmental Processes is both a comprehensive introduction to the science behind ion exchange and an expert assessment of the latest ion exchange technologies. Its purpose is to provide a valuable reference and learning tool for virtually anyone working in ion exchange or interested in becoming involved in that incredibly fertile field.Written for beginners as well as those already working the in the field, Dr. SenGupta provides stepwise coverage, advancing from ion exchange fundamentals to trace ion exchange through the emerging area of hybrid ion exchange nanotechnology (or polymeric/inorganic ion exchangers). Other topics covered include ion exchange kinetics, sorption and desorption of metals and ligands, solid-phase and gas-phase ion exchange, and more. Connects state-of-the-art innovations in such a way as to help researchers and process scientists get a clear picture of how ion exchange fundamentals can lead to new applicationsCovers the design of selective or smart ion exchangers for targeted applications—an area of increasing importance—including solid and gas phase ion exchange processesProvides in-depth discussion on intraparticle diffusion controlled kinetics for selective ion exchangeFeatures a chapter devoted to exciting developments in the areas of hybrid ion exchange nanotechnology or polymeric/inorganic ion exchangersWritten for those just entering the field of ion exchange as well as those involved in developing the “next big thing” in ion exchange systems, Ion Exchange in Environmental Processes is a valuable resource for students, process engineers, and chemists working in an array of industries, including mining, microelectronics, pharmaceuticals, energy, and wastewater treatment, to name just a few.

Over the past four decades, notable advancements in the theory and application of ion exchange science uncovered a wealth of knowledge that fueled new scientific pursuits and created synergies with myriad scientific endeavors. Today, pioneers continue to break new ground by synthesizing novel materials and merging the interdisciplinary fields of science and engineering.Now in its 20th volume, Ion Exchange and Solvent Extraction: A Series of Advances chronicles the ongoing changes that drive innovation in this important field. Beginning with a review of research studies that show how functionalized ion exchange polymers serve as supports to stabilize metal nanoparticles (MNPs) without forming larger than nano aggregates, the book describes the sorption of different gases from the air by ion exchange resins and fibrous ion exchangers and discusses the selective ion exchange technology capable of removing and recovering perchlorate quantitatively through stable isotope ratio analysis of chlorine and oxygen atoms, allowing for the forensic analysis of perchlorate origin in contaminated water.Later chapters demonstrate how numerical simulations coupled with small-scale bench-top experiments can help tailor particle size distribution and enhance the efficiency of each application, review dual-temperature ion exchange processes in which sorption and desorption are carried out solely by varying temperature, and present the preparation and characterization of a new composite material in which microparticles of clinoptilolite are embedded in a matrix of cross-linked chitosan, opening new opportunities for the natural biopolymer. The book concludes with the preparation, characterization, and field-level experience of an emerging class of "hybrid ion exchangers" that enhance the application opportunities of ion exchange resins.Highlighting the latest and most pivotal discoveries, the 20th volume of a field standard codifies the current state-of-the-art and lays the groundwork for the next generation of growth and expansion in the field of ion exchange.

Over the past four decades, notable advancements in the theory and application of ion exchange science uncovered a wealth of knowledge that fueled new scientific pursuits and created synergies with myriad scientific endeavors. Today, pioneers continue to break new ground by synthesizing novel materials and merging the interdisciplinary fields of science and engineering.Now in its 20th volume, Ion Exchange and Solvent Extraction: A Series of Advances chronicles the ongoing changes that drive innovation in this important field. Beginning with a review of research studies that show how functionalized ion exchange polymers serve as supports to stabilize metal nanoparticles (MNPs) without forming larger than nano aggregates, the book describes the sorption of different gases from the air by ion exchange resins and fibrous ion exchangers and discusses the selective ion exchange technology capable of removing and recovering perchlorate quantitatively through stable isotope ratio analysis of chlorine and oxygen atoms, allowing for the forensic analysis of perchlorate origin in contaminated water.Later chapters demonstrate how numerical simulations coupled with small-scale bench-top experiments can help tailor particle size distribution and enhance the efficiency of each application, review dual-temperature ion exchange processes in which sorption and desorption are carried out solely by varying temperature, and present the preparation and characterization of a new composite material in which microparticles of clinoptilolite are embedded in a matrix of cross-linked chitosan, opening new opportunities for the natural biopolymer. The book concludes with the preparation, characterization, and field-level experience of an emerging class of "hybrid ion exchangers" that enhance the application opportunities of ion exchange resins.Highlighting the latest and most pivotal discoveries, the 20th volume of a field standard codifies the current state-of-the-art and lays the groundwork for the next generation of growth and expansion in the field of ion exchange.

Since the Second World War, the field of ion exchange has taken a dominant role in offering solutions to many problems in the developed and developing world. It has evolved to a wide array of applications, including mining, microelectronics, drug delivery and detection, food, fertilizers, chemical cleaning, catalysis, bioseparation, water management, environmental research and practices, and energy.The six chapters in this book represent diverse contributions from researchers around the globe who are making noticeable strides in the field in currently important areas:Brackish water desalinationRemoving boron from waterSustainable approaches for synthesizing commercially important epoxide building blocksSolid-phase heavy-metal separationSeparating concentrated ion mixtures in sorption columnsSensing toxic metalsIon Exchange and Solvent Extraction: A Series of Advances, Volume 22 provides a focused review of new materials and new processes that have developed and are rapidly growing. It describes cutting-edge research and practices in the use of ion exchange for building a cleaner, sustainable world and provides thoughtful insights on what ion exchange may do for us in the future.

This book provides comprehensive coverage of developments in ion exchange areas which would continue to have major impacts in the general pursuit of pollution control and pollution prevention. Its nine chapters can be split into four different theme areas: trace contaminants removals; new materials; desalination and finally controlling gaseous pollutants. This would have value for practicing engineers, scientists and researchers who are pertaining to ion exchange technology. It would also server the needs of those trying to explore and identify new technologies in the areas of pollution control and pollution prevention.